FSD100 MbP?h㈵> d c 0 $@ @@ d fffffr@ м@ Harry Kooijman and Ross TaylorPervaporation_iecr48p3484P&{ChemSepAdapted from Luyben et al., Ind. Eng. Chem. Res. (2009) 48 pp. 3484-3495
Separation of Ethanol and Water using pervaporization to break the azeotrope. Note that the reflux ratio is set instead of the overhead composition because the sensitivity to the binary interaction parameters of the UNIQUAC model and the vapor pressure models. Specification of an 85% overhead would lower the reflux ratio to 2.5, lowering the condenser duty requirement.
< x temperaturepressure compositionflow Water-nButanol-UNIQUACAUwNA\t ?# ;#
W a t e r - e t h a n o l W a t e r - e t h a n o l - U N I Q U A C :0yE>MbP?MbP?MbP? % c:\werk\CO\COCO\bin\data\ChemSep1.pcd Z Water HOH H2O 7732-18-5 OT 9@
uA z? @O? `fRw@ `fq@ `q@ @ 2@ ? ? = ^@ I9 @qU? A Ӭ `@ A VA 8 {J@ ` 8 8 8 $m@ `fq@ J{? x? `f:@ ? Qa @3o@ Q:@i X@ Y % @ó> @ `frp@ Q:@e FpA O? | :? : `fq@ =:@j )hp ࣐a@ Mо I = @33 @ `fq@d 0q@ @ a@ eп f'? q@ @3@ @/@ `0;@ @ `3c? I@ @@ 4? `6 l2 v G)@ `fq@ @@h `f` @@ Qx2@ `T @ q@ @
9@e @r> ? `f f@ 8 `q@ Đ@f } @ K ? R? s q@ @3Ƀ@ `1> P? /M@ > 8 `q@ Đ@f J @d@ l
v? ϧ p@ 8@ @ fA `? k ! @6l> I@ @@d 8 8 8 8 8 8 8 f7@ &@ B 8 8 tx@ @3@
Z Wt l> 8 8 q@ @
9@
:#J{#Q@\ yf8TBfm?w-! b= @ p? `ff? ? ? `X@ B? 8 8 A N? έ? `? ? Q8*@ ?@1(@ 8@y ? (? B? Ethanol CH3CH2OH C2H6O 64-17-5 CCON \@ sWA A`? Q? u@ c@ c@ =@? G@ N ? ? @& = @ #9 pZ? @bA ` !A nRA 8 &g 8@ $ 8 8 8 \O@ c@ ? ? G @ fI? 8 c@ @3 @i p^@ v- Գ> @ c@ "@e +xA s? Mb `@ @U c@ @3 @j `f@ | `Ε? `2 4@ c@d @ @ 1 ? x] c@ x@ @@ VN(@ {> P b@ p@ 9@? IA a1 pp@ @@h `; @ 6@ ¤2 @ i@ {@e ࠻> (? -S@ @3 8 i@ @@f `y;? ^ ߿ @^} p> c@ `fv@ ? ( 8 `fq@ @@f w* 3@ hF? `fq@ `fr@ @ @ ? #C w> I@ @@d 8 8 8 8 8 8 8 v6@ @ 3N 8 8 Hs@ @3|@
l@ F `w? 8 8 i@ {@
vO jS )%寿#~j|4@kD> @ G @ ? p? `I? @S@ #? 8 8 `I? `? :ё? 8 c]? `I@ N ?ެp=@ z@,(2? Q? #? a c t i v i t y C o e f f i c i e n t a c t i v i t y C o e f f i c i e n t B d e n s i t y d e n s i t y d e n s i t y / v o l u m e ( p u r e ) d e n s i t y / v o l u m e ( p u r e )
e n t h a l p y e n t h a l p y e n t h a l p y F e n t h a l p y F e n t r o p y e n t r o p y : ! e n t r o p y F e n t r o p y F : e x c e s s E n t h a l p y e x c e s s E n t h a l p y f u g a c i t y f u g a c i t y h e a t C a p a c i t y h e a t C a p a c i t y C p K K
h e a t O f V a p o r i z a t i o n h e a t O f V a p o r i z a t i o n O l o g F u g a c i t y C o e f f i c i e n t l o g F u g a c i t y C o e f f i c i e n t s u r f a c e T e n s i o n s u r f a c e T e n s i o n s u r f a c e T e n s i o n ( p u r e ) s u r f a c e T e n s i o n ( p u r e ) t h e r m a l C o n d u c t i v i t y t h e r m a l C o n d u c t i v i t y 0 4 t h e r m a l C o n d u c t i v i t y ( p u r e ) t h e r m a l C o n d u c t i v i t y ( p u r e ) R S
v a p o r P r e s s u r e
v a p o r P r e s s u r e N v i s c o s i t y v i s c o s i t y & v i s c o s i t y ( p u r e ) v i s c o s i t y ( p u r e ) " v o l u m e v o l u m e V a p o r V a p o r p h a s e L i q u i d L i q u i d p h a s e z s?
Ethanol/Water imported from NRTL.IPDs?
Ethanol/Water imported from NRTL.IPD 333333? Water/water imported from HAYDENO.IPD?
Water/ethanol imported from HAYDENO.IPD?
Water/ethanol imported from HAYDENO.IPDffffff? Ethanol/ethanol imported from HAYDENO.IPD _L?
Ethanol/Water imported from VANLAAR.IPD&S?
Ethanol/Water imported from VANLAAR.IPD W2? Ethanol/Wate imported from MARGULES.IPD'? Ethanol/Wate imported from MARGULES.IPD ~ :h"~@
Ethanol/Water imported from WILSON.IPD ^Kh@
Ethanol/Water imported from WILSON.IPD z ~|HG@
Ethanol/Water imported from NRTL.IPDb /=
Ethanol/Water imported from NRTL.IPD
ƅ7K@
Ethanol/Water imported from UNIQUAC.IPD&BG.U@
Ethanol/Water imported from UNIQUAC.IPD ƅ7K@
Ethanol/Water imported from UNIQUAC.IPD&BG.U@
Ethanol/Water imported from UNIQUAC.IPD
H2O CH2 OH H2O q=
ףp?ffffff?jt2@ CH3 ͪ?A`"? rh.@ CH2 M
O?HzG?Zd;O
,@ OH ?333333?5^I 1@ r@33333l @ Ԏ@ v@̌c@ H2O CH2 OH H2O q=
ףp?ffffff?jt2@ CH3 ͪ?A`"? rh.@ CH2 M
O?HzG?Zd;O
,@ OH ?333333?5^I 1@ffffffu@^ P@$@{G<@33333t@ V瞯<
Water-ethanol 7732-18-5Water 2@ `fRw@H2O
Water-ethanolWater64-17-5Ethanol G@ u@C2H6O
Water-ethanolEthanol
? ? ? ? ? ? ? ? ? ? ? ? excessEnthalpy.Dpressure ? ? thermalConductivity.Dmoles ? ? / molenthalpyF.DmolFraction ? ? viscosity.Dtemperature ? ? ? ? activityCoefficient enthalpyF.Dpressure ? ? thermalConductivity.Dpressure ? ? thermalConductivity.Dtemperature ? ? heatCapacity.DmolFraction ? ? entropyF.Dmoles ? ? heatOfVaporization ? ? density.Dpressure ? @ ? @ enthalpy.Dmoles ? ? #logFugacityCoefficient.DmolFraction entropy.Dtemperature ? ? viscosity.Dmoles ? ? ? ? / mol
volume.Dmoles @@ @@ vaporPressure.Dtemperature ? ? enthalpy ? ? enthalpyF ? ? fugacity.Dtemperature ? ? excessEnthalpy.Dtemperature ? ? volume.Dpressure @@ @@ surfaceTension.DmolFraction ? ? activityCoefficient.Dtemperature activityCoefficient.Dmoles / molenthalpy.DmolFraction ? ? enthalpy.Dpressure ? ? logFugacityCoefficient fugacity.Dpressure density ? @ ? @ volume.DmolFraction @@ @@ enthalpyF.Dtemperature ? ? entropyF.DmolFraction ? ? thermalConductivity ? ? surfaceTension.Dtemperature ? ? density.DmolFraction ? @ ? @ surfaceTension ? ? heatCapacity.Dtemperature ? ? #logFugacityCoefficient.Dtemperature excessEnthalpy ? ? viscosity.DmolFraction ? ? ? ? enthalpy.Dtemperature ? ? entropy.Dpressure ? ? surfaceTension.Dmoles ? ? / moldensity.Dmoles ? @ ? @ / mol thermalConductivity.DmolFraction ? ? logFugacityCoefficient.Dmoles / mol heatOfVaporization.Dtemperature ? ? enthalpyF.Dmoles ? ? surfaceTension.Dpressure ? ? entropy.DmolFraction ? ? entropyF.Dtemperature ? ? volume @@ @@ entropy ? ? entropyF ? ? heatCapacity.Dpressure ? ? logFugacityCoefficient.Dpressure viscosity.Dpressure ? ? entropy.Dmoles ? ? entropyF.Dpressure ? ? heatCapacity ? ? activityCoefficient.Dpressure activityCoefficient.DmolFraction viscosity ? ? ? ? excessEnthalpy.Dmoles ? ? volume.Dtemperature @@ @@ density.Dtemperature ? @ ? @ fugacity.Dmoles ? ? / molheatCapacity.Dmoles ? ? excessEnthalpy.DmolFraction ? ? @ &{71F5AC07-65A1-4357-8F1B-A8CD58148763} RelativePerturbationTemperature ? ? RelativePerturbationPressure ? ? PerturbationComposition ? ? Temperature profile ? ? Pressure profile ? ? Vapour Flow profile ? ? Liquid Flow profile ? ? Vapour Density profile @ ? @ ? Vapour Viscosity profile ? ? ? ? Vapour Heat capacity profile ? ? #Vapour Thermal conductivity profile ? ? Liquid Density profile @ ? @ ? Liquid Viscosity profile ? ? ? ? Liquid Heat capacity profile ? ? Liquid Thermal cond. profile ? ? Surface tension profile ? ? Duties profile ? ? TotalMassBalanceProperties Fraction ? ?
TotalFlowMass ? ?
TotalFlowMole ? ? &{3D330930-C48E-47D6-B9BB-424741D04275} Area @ @ Permeate pressure ? ? &{779B2C7A-F54B-4A1D-B345-7FA14B889642} Outlet temperature ? ? Heat duty ? ?
Pressure drop ? ? &{E813F646-A25E-4B14-8873-4853D1AA3252} Pressure increase ? ? Pressure ? ?
Energy demand ? ? Adiabatic efficiency ? ? &{5E216BDD-C82F-45FE-830C-61FDDD2D9BC7}
Pressure drop ? ? &{429DC999-9073-4549-8647-BA72D6BE7931} Pressure increase ? ? Pressure ? ?
Energy demand ? ? Isentropic efficiency ? ? N heatOfVaporization heatOfVaporization.Dtemperature
vaporPressure vaporPressure.Dtemperature activityCoefficient activityCoefficient.Dmoles activityCoefficient.DmolFraction activityCoefficient.Dpressure activityCoefficient.Dtemperature density density.Dpressure density.Dtemperature enthalpy enthalpy.Dmoles enthalpy.DmolFraction enthalpy.Dpressure enthalpy.Dtemperature excessEnthalpy excessEnthalpy.Dmoles excessEnthalpy.DmolFraction excessEnthalpy.Dpressure excessEnthalpy.Dtemperature logFugacityCoefficient logFugacityCoefficient.Dmoles #logFugacityCoefficient.DmolFraction logFugacityCoefficient.Dpressure #logFugacityCoefficient.Dtemperature volume
volume.Dmoles volume.DmolFraction volume.Dpressure volume.Dtemperature bubblePointTemperature bubblePointPressure dewPointTemperature dewPointPressure density.Dmoles density.DmolFraction enthalpyF enthalpyF.Dmoles enthalpyF.DmolFraction enthalpyF.Dpressure enthalpyF.Dtemperature entropy entropy.Dmoles entropy.DmolFraction entropy.Dpressure entropy.Dtemperature entropyF entropyF.Dmoles entropyF.DmolFraction entropyF.Dpressure entropyF.Dtemperature fugacity fugacity.Dmoles fugacity.DmolFraction fugacity.Dpressure fugacity.Dtemperature heatCapacity heatCapacity.Dmoles heatCapacity.DmolFraction heatCapacity.Dpressure heatCapacity.Dtemperature thermalConductivity thermalConductivity.Dmoles thermalConductivity.DmolFraction thermalConductivity.Dpressure thermalConductivity.Dtemperature viscosity viscosity.Dmoles viscosity.DmolFraction viscosity.Dpressure viscosity.Dtemperature surfaceTension surfaceTension.Dmoles surfaceTension.DmolFraction surfaceTension.Dpressure surfaceTension.Dtemperature Vapor Vapor phase
Water-ethanolVapor Liquid Liquid phase
Water-ethanolLiquid VaporLiquid defaultdefault material template
Water-ethanol Feed ' ' '
s+pv+ default 6@ t@88Nh@|s@ (\?
?Q ?g,? ? (\?
?Q ?g,? (\?
?Q ?g,? t@ 6@88Nh@|s@ 2 5
8
6
5
8
5
8
default 6@TBü v@:/@i8? u&?|70?"ZCv?Q?
?- ?VU?#m/? ? u&?|70?"ZCv?Q? 2 Water 5 . ? . ? . 5 . ? . 5 . ? .
, T,HW, default 6@ >xw@Ζf@!=
@ +?eBa?MbP?& d? R?-" C?G`[?IW? ? +?eBa?MbP?& d? d 4 <
C
?
<
C
<
C
default 6%A9&"v@:/@i8? u&?|70?"ZCv?Q? ? u&?|70?"ZCv?Q? 2 5 R
l \ R
l R
R l l
default Q @aݿv@8Tٓ?' ? v-W?o> L?b4?1>? ? v-W?o> L?b4?1>? 2 6 R S R R S R R S
2Invalid mass balance after equilibrium calculation default 6%Alv@/oP-@r ? i]?!y?RI4?e? ? i]?!y?RI4?e? 2 8 G
N
J
G
N
G
N
default 6%A pw@:/@i8? u&?|70?"ZCv?Q? ? u&?|70?"ZCv?Q? 2 11 a n h a n a a n n
default Q @.Av@ +A2D? ? GJ ?yf?D hv?,i/q? ? GJ ?yf?D hv?,i/q? 2 10 a b a a b a a b
default 6%AU)v@ K
E,@&%A? mΌn?mْ?( 3?<@0i? ? mΌn?mْ?( 3?<@0i? 2 9 W ] Z W ] W ]
default 6%A pw@/oP-@r ? i]?!y?RI4?e? ? i]?!y?RI4?e? 2 14 p p p p p p p
default Q @"%w@?;O?9? kȬ?F ?|@y3U?? ? kȬ?F ?|@y3U?? 2 13 p v q p v p p v
default 6%Aw@r
Ïz+@o ? ''CХ{?X7?}"\?VUM!? ? ''CХ{?X7?}"\?VUM!? 2 12 f l i f l f l
default 6%A pw@ K
E,@&%A? mΌn?mْ?( 3?<@0i? ? mΌn?mْ?( 3?<@0i? 2 18 z r z r z z z
r
r
default Q @Gv@& ?:ݹk? 6Y;?(?H6-{'?;J? ? 6Y;?(?H6-{'?;J? 2 15 z { z z z
default 6%AU`ov@3SO++@ȵQd? ?h5gp?9 ?.0? ? ?h5gp?9 ?.0? 2 17 t
t t t
default Q @v@, %h?W^? o?z:f?@4?3? ? o?z:f?@4?3? 2 Ethanol
default 6%A4`v@+@Mޥֈ? C-4Tv?WR̲a?W?3M8? ? C-4Tv?WR̲a?W?3M8? X 19 p p p p p p p
default Q @KTv@Z< @+c1?
tU?Eމ?1?
ʸ? ?
tU?Eމ?1?
ʸ? 2 21 p # p ( p % p # p ( p # p (
default Q @ q@Z< @+c1?
tU?Eމ?1?
ʸ? ?
tU?Eމ?1?
ʸ? 2 Total Permeate p , ' d 2 % p 2 p , p 2 U 2 % 2 % $ % ' U 2 % $
default 6@`?q@Z< @+c1?
tU?Eމ?1?
ʸ? ?
tU?Eމ?1?
ʸ?
C1ChemSep Unit Operation qeWCXc CSUOp [ChemSep]
Version=6.90
Compiled=2012-1-31 20:40 41769b34bc6e
Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_54_~1.sep
Title=ChemSep CO Unit Operation "C1" in COFE Flowsheet
User=Harry
Date=2012-02-02
Time=01:03:14
[Cape-Open]
unitname=C1
CO_ID=CS_54_111C_1CCE13E_E9528A0
2 components
Water
7732-18-5
18.0149993896 Mw
Ethanol
64-17-5
46.0690002441 Mw
1 thermo
exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe
mode=COFE
NoWarnings=FALSE
WilsonEstimate=TRUE
Status=
0 only K-values and ethalpies
0 use only perturbed derivative
0 use only perturbed mole derivative
0.001 relative T perturbation
0.001 relative P perturbation
0.001 X perturbation
0 write all values to log
1 use initial guess
0 inlet reflash
0 outlet reflash
0 expose energy ports
0 clear log
0 update icon
CO Thermo Version=Auto
2 number of run levels
normal
simplified
1 current run level
[Paths]
Device drivers path=c:\program files\chemsepl6v90\bin\
Help and Info path=c:\program files\chemsepl6v90\help\
Component data path=c:\program files\chemsepl6v90\pcd\
Property data path=c:\program files\chemsepl6v90\ipd\
Section data path=c:\program files\chemsepl6v90\ild\
Executables path=C:\Program Files\ChemSepL6v90\bin\
Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\
Scripts path=c:\program files\chemsepl6v90\bin\
[Units]
Temperature=K
Flow=kmol/h
Mass flow=kg/s
Pressure=atm
Heat=MW
Enthalpy=kJ/kmol
Entropy=J/kmol/K
Fraction=_
Length=m
1/Length=1/m
Area=m2
Volume=m3
Mass=kg
Angle=deg
Velocity=m/s
Surface tension=dyn/cm
Density=kg/m3
Molar density=kmol/m3
Viscosity=Pa.s
Molecular weight=kg/kmol
Heat capacity=J/kmol/K
Thermal conductivity=J/s/m/K
Diffusivity=1e-8 m2/s
Interaction parameter=cal/mol
Time=s
[Components]
2
14 1921 Library Offset, Index DT=2012-01-31,09:17:24 CHK=26350 CAS=7732-18-5 CID=Water
Name=Water
Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd
53 1102 Library Offset, Index DT=2012-01-31,09:17:24 CHK=50254 CAS=64-17-5 CID=Ethanol
Name=Ethanol
Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd
[Operation]
2 Operation Column
1 Operation kind Simple Distillation
1 Condenser Total (Liquid product)
1 Reboiler Partial (Liquid product)
21 Stages
2 Feed stages
0 Sidestream stages
F=14,14
S=
0 Pumparound stages
P=
[Properties]
350 BIP estimation temperature
[Thermodynamics]
4 K model DECHEMA
7 1 Activity coefficient UNIQUAC
* Wilson model *
1 UNIQUAC model Original
1 Equation of State Ideal gas law
* Cubic EOS *
* Virial EOS *
3 Vapour pressure T correlation
0 Henry's law
* Henry's default *
[Enthalpy]
3 Enthalpy Excess
1 Enthalpy reference state Vapour
298.15 Enthalpy reference temperature
1 Formation enthalpies Excluded
298.15 Exergy surroundings temperature
[Physical property models]
0 No Check T range
* Cubic EOS *
* Virial EOS *
* Vapour model *
* Liquid mixture density *
* Liquid component density *
* Vapour mixture viscosity *
* Vapour mixture viscosity pressure correction *
* Vapour component viscosity *
* Liquid mixture viscosity *
* Liquid component viscosity
* Vapour mixture Cp
* Vapour component Cp
* Liquid mixture Cp
* Liquid component Cp
* Vapour mixture conductivity *
* Vapour component conductivity *
* Liquid mixture conductivity *
* Liquid component conductivity
* Mixture surface tension *
* Component surface tension *
* Vignes MS D-model *
* D mixture model *
* Vapour Diffusion Coefficients *
[Property Data]
[UNIQUAC Data]
i j Aij Aji Component Component
1 2 109.8687 173.801 Water/Ethanol
[Reaction data]
0 Number of reactions
[Specifications]
Top
Bottom
[Heaters/Coolers]
0 Number
0 Column duty Qcolumn
2 First stage
20 Last stage
0 Qcolumn lost to surroundings
[Efficiencies]
1 Default efficiency
0 Number
[Pressures]
1 Column pressure Constant pressure
111456.5 Condenser pressure
111456.5 Top pressure
* Pressure Drop
* Bottom pressure
[Feeds]
2 Number
1 Feed state T & p
14 Stage Feed1{split}
320 Temperature
111457.5 Pressure
0 Vapour fraction
2 componentflows
0.180833333333 Component 1 flow
0.0136111111111 Component 2 flow
1 Feed state T & p
14 Stage Feed2{split}
273.005431536 Temperature
111457.5 Pressure
0 Vapour fraction
2 componentflows
0.00215956452 Component 1 flow
9.05500274934e-005 Component 2 flow
[Condenser]
1 Type Reflux ratio
3.17 Value Qcondenser
1 Type Reflux ratio
3.17 Initialization guess
[Reboiler]
7 Type Mole fraction of a component
0.999 Value Qreboiler
1 1st comp.
1 Type Boilup ratio
0.1 Initialization guess
[Monitored Variables]
1
RR
x7/x1
[Solve options]
3 Initialization Old Results
1 Method Newton's method
0.5 Flow Step limit
10 Temperature Step limit
1 Composition Step limit
1 Flux Step limit
0.000001 Accuracy
30 Maximum iterations
1 Iteration count & function vector
0 T/V/L profiles
0 X/Y profiles
0 Variable and function vectors
0 Jacobian
1 History Screen
History file=
1 Feeds type Stage below
1 Interactive
0 Log thermodynamics
0 Log enthalpy/entropy
0 Log physical properties
0 Log timing
0 CO numeric differencing
0 Log from iteration
0 CS K-value
0 CS enthalpy
0 CS entropy
0 CS flash
0 CS activity coefficient
0 CS vapor pressuure
0 CS density
0 CS viscosity
0 CS thermal conductivity
0 CS heat capacity
0 CS surface tension
0 CS diffusivity
[Programs]
Temporary file=SCRATCH.TMP
User program=
8 DOS extender NT
1 Show windows Hidden
[FlowSheet]
[CoCo]
[Settings]
ComboBox=ComboBox14
-1
ComboBox=ComboBox20
-1
ComboBox=ComboBox21
-1
CheckBox=CheckBox3
0 Show settings
CheckBox=CheckBox1
1 Auto colors
CheckBox=CheckBox2
1 Auto points
Edit=Edit9
0.2
StringGrid=StringGrid5
2
8
Title
Labels
Stages
Axis color
Commands
Box
Labels box
Import data
StringGrid=StringGrid4
5
9
Title
Start
End
Tic interval
Small tics
Grid
Logarithmic
Scientific notation
x1
y1
x2
y2
StringGrid=StringGrid3
1
14
Label
Plot X
Plot Y
X axis
Y axis
Units X
Units Y
Color
Points
Thickness
Style
1st stage
Last stage
CheckBox=CheckBox10
0 Show settings
ComboBox=ComboBox22
1
ComboBox=ComboBox23
0
StringGrid=StringGrid7
16
2
Title
McCabe-Thiele diagram Ethanol - Water
Xlabel
X Ethanol/(Ethanol+Water)
Ylabel
Y Ethanol/(Ethanol+Water)
X interval
0.2
Y interval
0.2
X min
0
X max
1
Y min
0
Y max
1
X tics
0
Y tics
0
Axis color
Black
Grid
Off
y Fractions
Vertical
Commands
set label "ChemSep" at 1,0.02 right
Stage numbers
On
StringGrid=StringGrid11
5
3
CheckBox=CheckBox45
0 Lumped
ComboBox=ComboBox75
-1
ComboBox=ComboBox76
-1
ComboBox=ComboBox77
-1
Edit=Edit55
0.95
Edit=Edit56
0.95
Edit=Edit57
1.2
Edit=Edit1
1
CheckBox=CheckBox2
0 Use old results
CheckBox=CheckBox3
1 Automatic
CheckBox=CheckBox1
0 Keep sep-files
CheckBox=CheckBox4
1 Restore original
StringGrid=StringGrid1
1
6
Name
Variable
Units
Value
Start/Valuelist
End
StringGrid=StringGrid2
4
1
Name
Variable
Units
Current Value
StringGrid=StringGrid3
1
1
None
ComboBox=ComboBox1
-1
ComboBox=ComboBox2
-1
ComboBox=ComboBox3
-1
Edit=Edit1
Edit=Edit2
21
Edit=Edit3
Title
ComboBox=ComboBox4
0
ComboBox=ComboBox15
0
Edit=Edit17
Plot font
CheckBox=CheckBox2
1
Color=Edit18
1241641
SpinEdit=SpinEdit1
1
CheckBox=CheckBox2
1
Color=Edit19
1241641
Edit=Edit5
StringGrid=StringGrid2
7
2
StringGrid=StringGrid3
7
2
StringGrid=StringGrid4
7
2
Color=BVLEbplineColor
1241641
SpinEdit=SpinEdit2
1
ComboBox=ComboBox13
0
Color=BVLEdplineColor
1241641
SpinEdit=SpinEdit3
1
ComboBox=ComboBox14
0
RadioButton=RadioButton3
TRUE
DrawSetColors=BVLEcolors
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ComboBox=ComboBox7
-1
ComboBox=ComboBox11
-1
ComboBox=ComboBox6
-1
Memo=Memo1
Memo1,
ComboBox=ComboBox1
-1
ComboBox=ComboBox2
-1
ComboBox=ComboBox2
-1
ComboBox=ComboBox4
0
Edit=Edit1
Edit=Edit2
21
Edit=Edit3
Ternary Phase Diagram
Edit=Edit4
14,14
Edit=Edit6
Edit=Edit7
chemsep1.pcd
Edit=Edit8
Edit=Edit5
StringGrid=StringGrid1
3
7
Identifier
L#
File
Loc.
CAS
SMILES
Name
Water
1921
c:\program files\chemsepl6v84\pcd\chemsep1.pcd
14
7732-18-5
O
Water
Ethanol
1102
c:\program files\chemsepl6v84\pcd\chemsep1.pcd
53
64-17-5
CCO
Ethanol
0
0
ComboBox=ComboBox1
-1
ComboBox=ComboBox2
-1
ComboBox=ComboBox3
-1
Edit=Edit1
Edit=Edit2
Edit=Edit3
21
Edit=Edit4
Binary Property Diagram
Memo=Memo1
StringGrid=StringGrid1
13
4
Axis
Left
Right
X/Y
Property
-click to select-
-click to select-
x
Title
x
Units
-
Minimum
0
Maximum
1
Interval
0.2
Grid
Off
Off
Off
Log
Off
Off
Off
Color
Blue
Red
Black
Line
Normal
Normal
Style
Solid
Solid
Point
None
None
Edit=Edit5
ComboBox=ComboBox7
-1
ComboBox=ComboBox6
-1
[End Settings]
[End of Input]
[Results]
1 Converged
1 Iterations
[Profiles]
Stage Temperature Pressure Vapour Flow Liquid Flow Duties
1 353.7990355 1.114565000E+05 1.575499005E-02 4.994331845E-02 -2.555268938E+06
2 353.8178995 1.114565000E+05 6.569830850E-02 4.991831717E-02 0.000000000E+00
3 353.8404686 1.114565000E+05 6.567330722E-02 4.989262051E-02 0.000000000E+00
4 353.8675783 1.114565000E+05 6.564761056E-02 4.986540352E-02 0.000000000E+00
5 353.9006175 1.114565000E+05 6.562039357E-02 4.983563852E-02 0.000000000E+00
6 353.9418167 1.114565000E+05 6.559062857E-02 4.980191641E-02 0.000000000E+00
7 353.9948169 1.114565000E+05 6.555690646E-02 4.976213147E-02 0.000000000E+00
8 354.0658260 1.114565000E+05 6.551712151E-02 4.971285780E-02 0.000000000E+00
9 354.1661444 1.114565000E+05 6.546784785E-02 4.964797111E-02 0.000000000E+00
10 354.3182880 1.114565000E+05 6.540296116E-02 4.955515556E-02 0.000000000E+00
11 354.5731278 1.114565000E+05 6.531014561E-02 4.940527554E-02 0.000000000E+00
12 355.0685729 1.114565000E+05 6.516026559E-02 4.911096808E-02 0.000000000E+00
13 356.2945723 1.114565000E+05 6.486595813E-02 4.837114323E-02 0.000000000E+00
14 360.1886759 1.114565000E+05 6.412613328E-02 2.627896820E-01 0.000000000E+00
15 360.3753127 1.114565000E+05 8.185011303E-02 2.626629174E-01 0.000000000E+00
16 361.0393616 1.114565000E+05 8.172334849E-02 2.623045845E-01 0.000000000E+00
17 363.1429437 1.114565000E+05 8.136501554E-02 2.618268605E-01 0.000000000E+00
18 367.7498951 1.114565000E+05 8.088729152E-02 2.623339479E-01 0.000000000E+00
19 372.7903912 1.114565000E+05 8.139437898E-02 2.637845147E-01 0.000000000E+00
20 375.4783394 1.114565000E+05 8.284494575E-02 2.647325979E-01 0.000000000E+00
21 376.4038671 1.114565000E+05 8.379302894E-02 1.809395689E-01 3.415697885E+06
[Enthalpies/Entropies]
Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy
1 -0.3530516E+08 -0.3530516E+08 -0.1020309E+06 -0.1020309E+06
2 0.3588820E+07 -0.3534535E+08 0.1362026E+05 -0.1019635E+06
3 0.3573080E+07 -0.3538607E+08 0.1369867E+05 -0.1019018E+06
4 0.3557370E+07 -0.3542851E+08 0.1377403E+05 -0.1018441E+06
5 0.3541272E+07 -0.3547408E+08 0.1384841E+05 -0.1017893E+06
6 0.3524328E+07 -0.3552464E+08 0.1392378E+05 -0.1017368E+06
7 0.3505984E+07 -0.3558278E+08 0.1400218E+05 -0.1016864E+06
8 0.3485522E+07 -0.3565255E+08 0.1408599E+05 -0.1016393E+06
9 0.3461948E+07 -0.3574071E+08 0.1417817E+05 -0.1015989E+06
10 0.3433833E+07 -0.3585983E+08 0.1428267E+05 -0.1015756E+06
11 0.3399120E+07 -0.3603661E+08 0.1440507E+05 -0.1015993E+06
12 0.3355386E+07 -0.3633963E+08 0.1455364E+05 -0.1017744E+06
13 0.3304689E+07 -0.3699153E+08 0.1474226E+05 -0.1025609E+06
14 0.3270336E+07 -0.3810227E+08 0.1491141E+05 -0.1046741E+06
15 0.3269235E+07 -0.3812361E+08 0.1490883E+05 -0.1047231E+06
16 0.3264821E+07 -0.3818670E+08 0.1489130E+05 -0.1048715E+06
17 0.3243688E+07 -0.3829325E+08 0.1474306E+05 -0.1051482E+06
18 0.3143494E+07 -0.3828150E+08 0.1381486E+05 -0.1052321E+06
19 0.2923202E+07 -0.3810978E+08 0.1138629E+05 -0.1050094E+06
20 0.2748514E+07 -0.3798576E+08 0.8972482E+04 -0.1048664E+06
21 0.2678025E+07 -0.3793958E+08 0.7700009E+04 -0.1048360E+06
[Vapour Properties]
Stage Moleweight Density Viscosity Heat capacity Thermal conductivity
1 0.4233637E+02 0.1604177E+01 0.1072914E-04 0.6845139E+05 0.2117033E-01
2 0.4209057E+02 0.1594778E+01 0.1074505E-04 0.6810482E+05 0.2119024E-01
3 0.4184778E+02 0.1585478E+01 0.1076085E-04 0.6776298E+05 0.2121031E-01
4 0.4160134E+02 0.1576021E+01 0.1077697E-04 0.6741649E+05 0.2123109E-01
5 0.4134415E+02 0.1566131E+01 0.1079389E-04 0.6705541E+05 0.2125325E-01
6 0.4106778E+02 0.1555481E+01 0.1081219E-04 0.6666802E+05 0.2127763E-01
7 0.4076130E+02 0.1543642E+01 0.1083264E-04 0.6623920E+05 0.2130538E-01
8 0.4040924E+02 0.1530002E+01 0.1085635E-04 0.6574766E+05 0.2133824E-01
9 0.3998803E+02 0.1513625E+01 0.1088507E-04 0.6516109E+05 0.2137906E-01
10 0.3945868E+02 0.1492947E+01 0.1092175E-04 0.6442636E+05 0.2143288E-01
11 0.3875048E+02 0.1465098E+01 0.1097204E-04 0.6344800E+05 0.2150980E-01
12 0.3771933E+02 0.1424122E+01 0.1104836E-04 0.6203376E+05 0.2163361E-01
13 0.3602063E+02 0.1355306E+01 0.1118490E-04 0.5973372E+05 0.2187604E-01
14 0.3268583E+02 0.1216536E+01 0.1149286E-04 0.5528077E+05 0.2248622E-01
15 0.3254407E+02 0.1210632E+01 0.1150638E-04 0.5509028E+05 0.2251382E-01
16 0.3204094E+02 0.1189723E+01 0.1155422E-04 0.5441219E+05 0.2261169E-01
17 0.3043600E+02 0.1123584E+01 0.1170380E-04 0.5222538E+05 0.2291976E-01
18 0.2669952E+02 0.9732989E+00 0.1202037E-04 0.4698563E+05 0.2359390E-01
19 0.2207496E+02 0.7938358E+00 0.1231592E-04 0.4023852E+05 0.2433812E-01
20 0.1933019E+02 0.6901551E+00 0.1241675E-04 0.3611720E+05 0.2473820E-01
21 0.1833579E+02 0.6530416E+00 0.1243495E-04 0.3460508E+05 0.2487636E-01
[Liquid Properties]
Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension
1 0.4209057E+02 0.7660054E+03 0.4113822E-03 0.1307573E+06 0.2288626E+00 0.2365771E-01
2 0.4177115E+02 0.7664478E+03 0.4103235E-03 0.1300370E+06 0.2347171E+00 0.2417343E-01
3 0.4144686E+02 0.7669249E+03 0.4092317E-03 0.1293071E+06 0.2406612E+00 0.2469662E-01
4 0.4110832E+02 0.7674536E+03 0.4080746E-03 0.1285466E+06 0.2468668E+00 0.2524236E-01
5 0.4074444E+02 0.7680576E+03 0.4068125E-03 0.1277307E+06 0.2535374E+00 0.2582845E-01
6 0.4034078E+02 0.7687719E+03 0.4053915E-03 0.1268272E+06 0.2609380E+00 0.2647801E-01
7 0.3987693E+02 0.7696518E+03 0.4037336E-03 0.1257909E+06 0.2694433E+00 0.2722366E-01
8 0.3932170E+02 0.7707909E+03 0.4017169E-03 0.1245525E+06 0.2796263E+00 0.2811512E-01
9 0.3862349E+02 0.7723609E+03 0.3991369E-03 0.1229979E+06 0.2924355E+00 0.2923452E-01
10 0.3768857E+02 0.7747151E+03 0.3956170E-03 0.1209192E+06 0.3095950E+00 0.3073057E-01
11 0.3632538E+02 0.7787014E+03 0.3903790E-03 0.1178908E+06 0.3346343E+00 0.3290623E-01
12 0.3407337E+02 0.7868939E+03 0.3815437E-03 0.1128820E+06 0.3760588E+00 0.3648583E-01
13 0.2962261E+02 0.8104328E+03 0.3637184E-03 0.1029075E+06 0.4581993E+00 0.4350346E-01
14 0.2255963E+02 0.8771701E+03 0.3299898E-03 0.8681463E+05 0.5901321E+00 0.5423709E-01
15 0.2239827E+02 0.8792525E+03 0.3288960E-03 0.8644371E+05 0.5932090E+00 0.5446348E-01
16 0.2188726E+02 0.8860368E+03 0.3251936E-03 0.8526761E+05 0.6029969E+00 0.5516647E-01
17 0.2071733E+02 0.9026494E+03 0.3148736E-03 0.8256248E+05 0.6257424E+00 0.5666329E-01
18 0.1929403E+02 0.9246151E+03 0.2963912E-03 0.7921673E+05 0.6545005E+00 0.5808260E-01
19 0.1844730E+02 0.9379756E+03 0.2796296E-03 0.7715249E+05 0.6726455E+00 0.5846527E-01
20 0.1813571E+02 0.9426916E+03 0.2716645E-03 0.7636416E+05 0.6796246E+00 0.5843517E-01
21 0.1804305E+02 0.9440451E+03 0.2690501E-03 0.7612534E+05 0.6817379E+00 0.5839997E-01
[Vapour phase compositions]
Component Mole fractions on stages: 1 to 5
1 0.133051462E+00 0.141813386E+00 0.150467683E+00 0.159252047E+00 0.168419903E+00
2 0.866948538E+00 0.858186614E+00 0.849532317E+00 0.840747953E+00 0.831580097E+00
Component Mole fractions on stages: 6 to 10
1 0.178271227E+00 0.189196002E+00 0.201745102E+00 0.216759322E+00 0.235628610E+00
2 0.821728773E+00 0.810803998E+00 0.798254898E+00 0.783240678E+00 0.764371390E+00
Component Mole fractions on stages: 11 to 15
1 0.260872592E+00 0.297628377E+00 0.358179643E+00 0.477050161E+00 0.482103551E+00
2 0.739127408E+00 0.702371623E+00 0.641820357E+00 0.522949839E+00 0.517896449E+00
Component Mole fractions on stages: 16 to 20
1 0.500037893E+00 0.557246589E+00 0.690435700E+00 0.855280366E+00 0.953119205E+00
2 0.499962107E+00 0.442753411E+00 0.309564300E+00 0.144719634E+00 0.468807951E-01
Component Mole fractions on stages: 21 to 21
1 0.988565399E+00
2 0.114346014E-01
[Liquid phase compositions]
Component Mole fractions on stages: 1 to 5
1 0.141813386E+00 0.153199112E+00 0.164758792E+00 0.176826240E+00 0.189796973E+00
2 0.858186614E+00 0.846800888E+00 0.835241208E+00 0.823173760E+00 0.810203027E+00
Component Mole fractions on stages: 6 to 10
1 0.204185640E+00 0.220719844E+00 0.240511175E+00 0.265399372E+00 0.298724892E+00
2 0.795814360E+00 0.779280156E+00 0.759488825E+00 0.734600628E+00 0.701275108E+00
Component Mole fractions on stages: 11 to 15
1 0.347316666E+00 0.427590782E+00 0.586240304E+00 0.838004209E+00 0.843755954E+00
2 0.652683334E+00 0.572409218E+00 0.413759696E+00 0.161995791E+00 0.156244046E+00
Component Mole fractions on stages: 16 to 20
1 0.861971235E+00 0.903673911E+00 0.954408095E+00 0.984590542E+00 0.995697245E+00
2 0.138028765E+00 0.963260887E-01 0.455919046E-01 0.154094584E-01 0.430275478E-02
Component Mole fractions on stages: 21 to 21
1 0.999000000E+00
2 0.100000000E-02
[Reaction rates]
Component reaction rates on stages: 1 to 5
1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
Component reaction rates on stages: 6 to 10
1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
Component reaction rates on stages: 11 to 15
1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
Component reaction rates on stages: 16 to 20
1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00
Component reaction rates on stages: 21 to 21
1 0.000000000E+00
2 0.000000000E+00
[Condenser Heat Duty]
-2.555268938E+06
[Reboiler Heat Duty]
3.415697885E+06
[UA Column]
0.000000000E+00
[K-values]
Component K-values on stages: 1 to 5
1 0.938215115E+00 0.925680206E+00 0.913260414E+00 0.900613206E+00 0.887368748E+00
2 0.101020981E+01 0.101344558E+01 0.101711016E+01 0.102134931E+01 0.102638483E+01
Component K-values on stages: 6 to 10
1 0.873084060E+00 0.857177130E+00 0.838818000E+00 0.816728842E+00 0.788781304E+00
2 0.103256339E+01 0.104045251E+01 0.105104232E+01 0.106621292E+01 0.108997365E+01
Component K-values on stages: 11 to 15
1 0.751108766E+00 0.696058917E+00 0.610977513E+00 0.569269409E+00 0.571377955E+00
2 0.113244413E+01 0.122704457E+01 0.155119110E+01 0.322816930E+01 0.331466357E+01
Component K-values on stages: 16 to 20
1 0.580109721E+00 0.616645653E+00 0.723417690E+00 0.868666039E+00 0.957237966E+00
2 0.362215882E+01 0.459640184E+01 0.678989622E+01 0.939161071E+01 0.108955303E+02
Component K-values on stages: 21 to 21
1 0.989554953E+00
2 0.114346014E+02
[Molecular weights]
1 18.015
2 46.069
[Feed stream 1]
14 Stage Number
1.9444444444410E-01 Flow rate
3.2000000000000E+02 Temperature [K]
1.1145750000000E+05 Pressure [Pa]
-4.2026019771604E+07 Enthalpy [J/kmol]
-1.1728738485861E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
9.2999999999993E-01 Mole fraction of component 1
7.0000000000067E-02 Mole fraction of component 2
1.9444444444410E-01 Flow rate
9.2999999999993E-01 Mole fraction of component 1
7.0000000000067E-02 Mole fraction of component 2
1.9978779449465E+01 Molar mass
9.5254635039630E+02 Density
5.8359298722209E-04 Viscosity
6.0590384577533E-01 Thermal conductivity
7.8776400731269E+04 Heat capacity
6.5152913295198E-02 Surface tension
[Feed stream 2]
14 Stage Number
2.2501145474934E-03 Flow rate
2.7300543153600E+02 Temperature [K]
1.1145750000000E+05 Pressure [Pa]
-4.8756348715556E+07 Enthalpy [J/kmol]
-1.3351878937755E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
9.5975759207714E-01 Mole fraction of component 1
4.0242407922864E-02 Mole fraction of component 2
2.2501145474934E-03 Flow rate
9.5975759207714E-01 Mole fraction of component 1
4.0242407922864E-02 Mole fraction of component 2
1.9143959935903E+01 Molar mass
1.0041656349401E+03 Density
1.7732187762586E-03 Viscosity
5.5162251938971E-01 Thermal conductivity
7.6665448891568E+04 Heat capacity
7.3939729845735E-02 Surface tension
[Reflashed Feed stream 1]
14 Stage Number
1.9444444444410E-01 Flow rate
3.2000000000000E+02 Temperature [K]
1.1145650000000E+05 Pressure [Pa]
-4.2026019771604E+07 Enthalpy [J/kmol]
-1.1728738485861E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
9.2999999999993E-01 Mole fraction of component 1
7.0000000000067E-02 Mole fraction of component 2
1.9444444444410E-01 Flow rate
9.2999999999993E-01 Mole fraction of component 1
7.0000000000067E-02 Mole fraction of component 2
1.9978779449465E+01 Molar mass
9.5254635031292E+02 Density
5.8359298722209E-04 Viscosity
6.0590384577533E-01 Thermal conductivity
7.8776400731269E+04 Heat capacity
6.5152913295198E-02 Surface tension
[Reflashed Feed stream 2]
14 Stage Number
2.2501145474934E-03 Flow rate
2.7300543153600E+02 Temperature [K]
1.1145650000000E+05 Pressure [Pa]
-4.8756348715556E+07 Enthalpy [J/kmol]
-1.3351878937755E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
9.5975759207714E-01 Mole fraction of component 1
4.0242407922864E-02 Mole fraction of component 2
2.2501145474934E-03 Flow rate
9.5975759207714E-01 Mole fraction of component 1
4.0242407922864E-02 Mole fraction of component 2
1.9143959935903E+01 Molar mass
1.0041656348843E+03 Density
1.7732187762586E-03 Viscosity
5.5162251938971E-01 Thermal conductivity
7.6665448891568E+04 Heat capacity
7.3939729845735E-02 Surface tension
[Top product]
1 Stage Number
1.5754990048087E-02 Flow rate
3.5379903549130E+02 Temperature [K]
1.1145650000000E+05 Pressure [Pa]
-3.5305163637085E+07 Enthalpy [J/kmol]
-1.0203092915372E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
1.4181338557584E-01 Mole fraction of component 1
8.5818661442414E-01 Mole fraction of component 2
1.5754990048087E-02 Flow rate
1.4181338557584E-01 Mole fraction of component 1
8.5818661442414E-01 Mole fraction of component 2
4.2090567404017E+01 Molar mass
7.6600539209199E+02 Density
4.1138224724860E-04 Viscosity
2.2886256997047E-01 Thermal conductivity
1.3075731022091E+05 Heat capacity
2.3657705115063E-02 Surface tension
[Bottom product]
21 Stage Number
1.8093956894351E-01 Flow rate
3.7640386707452E+02 Temperature [K]
1.1145650000000E+05 Pressure [Pa]
-3.7939584060347E+07 Enthalpy [J/kmol]
-1.0483597059242E+05 Entropy [J/kmol/K]
0.0000000000000E+00 Vapour fraction [-]
1.0000000000000E+00 Liquid phase split ratio [-]
9.9900000000000E-01 Mole fraction of component 1
1.0000000000000E-03 Mole fraction of component 2
1.8093956894351E-01 Flow rate
9.9900000000000E-01 Mole fraction of component 1
1.0000000000000E-03 Mole fraction of component 2
1.8043053390503E+01 Molar mass
9.4404514590756E+02 Density
2.6905010102860E-04 Viscosity
6.8173791825580E-01 Thermal conductivity
7.6125344346800E+04 Heat capacity
5.8399967373317E-02 Surface tension
[Equilibrium Data at 1.11457E+05 Pa]
Temperature X(1) Y(1)
353.895 0.0000000 0.0000000
353.827 0.0250000 0.0271754
353.784 0.0500000 0.0525850
353.762 0.0750000 0.0763814
353.760 0.1000000 0.0987001
353.778 0.1250000 0.1196621
353.812 0.1500000 0.1393757
353.863 0.1750000 0.1579387
353.929 0.2000000 0.1754392
354.009 0.2250000 0.1919576
354.103 0.2500000 0.2075671
354.208 0.2750000 0.2223352
354.324 0.3000000 0.2363242
354.451 0.3250000 0.2495925
354.588 0.3500000 0.2621950
354.734 0.3750000 0.2741842
354.889 0.4000000 0.2856108
355.051 0.4250000 0.2965247
355.222 0.4500000 0.3069757
355.400 0.4750000 0.3170148
355.586 0.5000000 0.3266951
355.780 0.5250000 0.3360735
355.983 0.5500000 0.3452122
356.195 0.5750000 0.3541813
356.419 0.6000000 0.3630614
356.656 0.6250000 0.3719473
356.910 0.6500000 0.3809539
357.184 0.6750000 0.3902225
357.485 0.7000000 0.3999315
357.821 0.7250000 0.4103108
358.202 0.7500000 0.4216632
358.643 0.7750000 0.4343973
359.167 0.8000000 0.4490793
359.801 0.8250000 0.4665163
360.590 0.8500000 0.4878999
361.596 0.8750000 0.5150624
362.915 0.9000000 0.5509666
364.699 0.9250000 0.6007180
367.204 0.9500000 0.6738765
370.891 0.9750000 0.7904850
376.697 1.0000000 1.0000000
[End of Results]
G U I A r g u m e n t s / k p l d U s e C O S E T h e r m o : U s e C O S E D i f f u s i o n C o e f f i c i e n t s 8 U s e P e r t u r b e d D e r i v a t i v e s O n l y " U s e P e r t u r b e d _ d d X " S u p p r e s s W a r n i n g s @ R e l a t i v e P e r t u r b a t i o n T e m p e r a t u r e MbP?: R e l a t i v e P e r t u r b a t i o n P r e s s u r e MbP?0 P e r t u r b a t i o n C o m p o s i t i o n MbP? I n l e t R e f l a s h < n o n e > O u t l e t F l a s h
A u t o D U s e O n l y K V a l u e s A n d E n t h a l p y F r o m C O S E * R e s t a r t D a t a A v a i l a b l e , O m i t S t a g e F r o m P o r t N a m e W i l s o n E s t i m a t e " L o g P r o p e r t y C a l l s E n e r g y P o r t s U s e I n i t i a l G u e s s ( T e m p e r a t u r e p r o f i l e 4 T e m p e r a t u r e a t e a c h s t a g e }r v@> v@
3r v@ș v@IKh v@:Uc v@!0 v@S
!v@"v@Yk(%v@V+)v@E1v@qDv@@v@`Gv@~ 9v@JUIv@ v@0>qLw@66Gww@&Y=vw@" P r e s s u r e p r o f i l e . P r e s s u r e a t e a c h s t a g e 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@ 6@( V a p o u r F l o w p r o f i l e 4 V a p o u r F l o w a t e a c h s t a g e ^ K/@4"lP@*wkP@sriP@ s;gP@eP@d(ZcP@`фaP@@8]P@ YP@lSP@YAJP@k7P@a"RP@9p{@hvT@N
wWKnT@<#j\WT@_b8T@ UU=YT@:VT@8tT@( L i q u i d F l o w p r o f i l e 4 L i q u i d F l o w a t e a c h s t a g e Q;H@@jH@,cAH@# H@V3H@i2H@s%H@i٤>H@H@@2_VH@H@?34H@}/H@×lp@0FOjp@%dp@]:]p@Wep@;I_|p@Yp@:f@ D u t i e s p r o f i l e * D u t i e s a t e a c h s t a g e Nbx~C GHJA4 V a p o u r M o l e w e i g h t p r o f i l e @ V a p o u r M o l e w e i g h t a t e a c h s t a g e ,+E@9̗ E@D@i㈵D@uq
D@TD@8EGraD@a4D@û\wC@&C@&`C@dB@ B@NGW@@ ^E@@=@@V-o>@":@ 06@\wTT3@R\UU2@. V a p o u r D e n s i t y p r o f i l e : V a p o u r D e n s i t y a t e a c h s t a g e ?5?p- ^?a7?F$a?>ʈ @?g+?`z?+7?d ?
q?9x&4?E)!XU?sv?n^? ?d73?rC%?Ug?]%?1]?2 V a p o u r V i s c o s i t y p r o f i l e > V a p o u r V i s c o s i t y a t e a c h s t a g e )>'Pm>.ad/>]xzי> >6 >v>5au>>w>>5 6 +>?Z`t>ך.>DPp!> ;>;
n>c5> s'>"N" 1
>ӽ>: V a p o u r H e a t c a p a c i t y p r o f i l e F V a p o u r H e a t c a p a c i t y a t e a c h s t a g e t Q@^Q@"P@ GŧP@wbP@DP@M
OP@!ToP@mnLOJP@t{IP@MbXO@g?RO@5vM@UwEK@ϽKK@T4K@x@ J@n )~G@҇ D@h B@ZBsMA@H V a p o u r T h e r m a l c o n d u c t i v i t y p r o f i l e T V a p o u r T h e r m a l c o n d u c t i v i t y a t e a c h s t a g e kˬ?t-䲕?-&'?^oT? viÕ?ɕ?Pѕ? ٕ?ޮnd?$:?y,>? '?v1f?
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?K:Ԅ'?MWGx?0V(?ȕ?3T?B0y?4 L i q u i d M o l e w e i g h t p r o f i l e @ L i q u i d M o l e w e i g h t a t e a c h s t a g e 9̗ E@' D@^2D@YnݍD@VI_D@խ+D@p>?C@ŏ1w-C@3OC@܀#B@bE
)B@@+0d A@)t^c=@HcC6@Ye6@ x#5@pZ4@
ҌEK3@4@r2@{"2@&S 2@. L i q u i d D e n s i t y p r o f i l e : L i q u i d D e n s i t y a t e a c h s t a g e 0' @1*@1f@k @!u @B>,@C 6
@@aS@ "@JY5@QkwU@( &@_vS@fc]\i@Q z@c]K@.15@(~@o_O@Oeu@fc]\@2 L i q u i d V i s c o s i t y p r o f i l e > L i q u i d V i s c o s i t y a t e a c h s t a g e -\:?Uf:? Ú:?5[:?b.:?2
łl3?,gS2?$1?ga1?: L i q u i d H e a t c a p a c i t y p r o f i l e F L i q u i d H e a t c a p a c i t y a t e a c h s t a g e Y5;X`@w/A`@Aa)`@H}`@_@D_@r_@(\#_@k+ݿ^@<,:^@ y]@ r8\@GzY@"U@ eU@I QU@) T@S@jeIS@eNS@\8S@: L i q u i d T h e r m a l c o n d . p r o f i l e F L i q u i d T h e r m a l c o n d . a t e a c h s t a g e #^K?\'5 ?CCw?;T?T9?J'L5?h >?~fe?C ,cC?S g?j?PX?4#(#S?;\?+p?8ܢ'K??V?r O?|?2 ?0 S u r f a c e t e n s i o n p r o f i l e < S u r f a c e t e n s i o n a t e a c h s t a g e 5
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< C h e m S e p ( T M ) - C O L 2 6 . 9 0
C o p y r i g h t ( c ) 1 9 8 8 - 2 0 1 2 H a r r y K o o i j m a n a n d R o s s T a y l o r
L i c e n s e : 2 1 0 0 - 6 L I T E f r e e l i c e n s e
B u i l d : 6 4 9 4 e 2 b 6 9 d 2 3
C h e c k i n g d a t a f i l e C : \ D O C U M E ~ 1 \ H a r r y \ L O C A L S ~ 1 \ T e m p \ C S _ 5 4 _ ~ 1 . S E P
C a p e O p e n u n i t n a m e : C 1
C a p e - O p e n u n i t i d : C S _ 5 4 _ 1 1 1 C _ 1 C C E 1 3 E _ E 9 5 2 8 A 0
C a p e - O p e n r u n l e v e l : n o r m a l
C a p e o p e n I n i t i a l i z e d
C a p e O p e n T h e r m o d y n a m i c - p r o p e r t i e s d i s a b l e d
R e a d i n g c o n f i g u r a t i o n
R e a d i n g c o m p o n e n t p r o p e r t y l i b r a r i e s
R e a d i n g t h e r m o d y n a m i c p r o p e r t y o p t i o n s
R e a d i n g p h y s i c a l p r o p e r t y o p t i o n s
R e a d i n g t h e r m o d y n a m i c p r o p e r t y d a t a
R e a d i n g s p e c i f i c a t i o n s
R e a d i n g r e a c t i o n d a t a
C h e c k i n g C o m p o n e n t D a t a
7 7 3 2 - 1 8 - 5 W a t e r
* N o c l a s s
6 4 - 1 7 - 5 E t h a n o l
D e t e r m i n i n g f e e d c o n d i t i o n s
S o l v i n g T P f l a s h
P o s s i b l e t r i v i a l s o l u t i o n
S o l v i n g T P f l a s h
P o s s i b l e t r i v i a l s o l u t i o n
R u n l e v e l : I n i t i a l i z a t i o n
R e a d i n g i n i t i a l t e m p e r a t u r e p r o f i l e s
R e a d i n g i n i t i a l c o m p o s i t i o n p r o f i l e s
I n i t 4 7 m i l l i s e c o n d s
R u n l e v e l : C o m p l e t e m o d e l
I t e r a t i o n l o g ( E r r / T o l )
0 0 . 6 9 6 5 R R = 3 . 1 7 0 0
1 - 2 . 8 5 5 6 R R = 3 . 1 7 0 0
R u n l e v e l : R e p o r t
C o n v e r g e n c e o b t a i n e d i n 1 i t e r a t i o n s
G e n e r a t i n g e q u i l i b r i u m d a t a
T i m e 1 5 m i l l i s e c o n d s
F i x M e m d r i v e r d o n e
r u n t i m e : 0 . 1 7 s e c o n d s
U s i n g : C : \ P r o g r a m F i l e s \ C h e m S e p L 6 v 9 0 \ b i n \ c o - c o l 2 . e x e
C A P E - O P E N t h e r m o - p r o p e r t i e s w e r e d i s a b l e d .
A l l c a l c u l a t i o n m e t h o d s h a v e b e e n d e t e r m i n e d b y C h e m S e p .
S e e o u t p u t r e p o r t o r g r a p h i c a l u s e r i n t e r f a c e f o r m o r e i n f o r m a t i o n .
' 5 0
not all ports are connected Feed1{split}_stage14 Feed2{split}_stage14
TopProduct
BottomProduct
@ @ 0@ @ @ @ @ (@ @ (@ $@ ,@ @ @ @ @ @ @ @ $@ @ (@ @ (@ @ (@ @ @ @ ,@ $@ @ @ $@ @ (@ @ ,@ @ @ ,@ @ $@ 0@ ,@ 4@ @ 0@ @ 2@ @ 2@ $@ 2@ (@ 0@ (@ (@ (@ (@ @ (@ $@ 4@ ,@ 0@ @
4@ ,@ 0@ 4@ ,@ 0@ 4@ ,@ 0@ 4@ ,@ 0@ 4@ ,@ 0@ ,@ 0@
,@ 0@ @ /@
membrane 13Unit operation using SciLab script for calculations 0 3=GBGABu ?
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4ؕwy隄6mYw^|spp4e*ش j*"ʥ`㉥ᛃ "9#9:cY4P 36e|`>H)6J#A0u5 $anɹItOS$FOL;R0M*!F!.i"/9? 5 :V"4qjSe; 1;59kpgx%[!ݖưš
1.=b!^.ډh.|Bױ^;3壌 QQV~*e Hk m0YRLn]!~*TM|ŦسW8
&lC}+pJ²<*E:s&7-Um]
8a+ `&v}7l\`!/7/o &$ 9㐸K ^Awq)f\ᬼf>(h祖:pj:pf.\M"y?}-mWxE 9FU[|G'א7}~y >K;H#i;No5pno\nC4*-൞3x q;Q2FNV}lr~TT,
H?M >7Д xP,v&A{&и)mWoʖ {(Yr @#z~e "6.lPK sB@fkP Y calcWmo6<RH/KӀ`h'x0
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i!M 9N)77 W̎X)[4IcU4+A Ъե;pxV!_oak0 Qj! G #A0 l8ksJ^:lxg'iK+$^ZI}MuZg[L^\=,NO"SU~ %T_edPOV*XPŶ{?" DO2}b3a U?0C|ZYKވ DDoa[B '
$TS0T ="bգLj #Z#)hZHy@x!aDɁ"#
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)Product port "Retentate" is not connected Feed Permeate Retentate @ @ @ @ @ @ @ @ @ @ @ @ @ @ HeaterCooler_3MHeaterCooler - heat or cool stream specifying heat duty or outlet temperature z,wK JEKB COUSCOUS0002 T y p e T y p e o f h e a t d u t y s p e c i f i c a t i o n T e m p e r a t u r e H e a t d u t y H e a t d u t y T e m p e r a t u r e E n e r g y i n l e t O u t l e t t e m p e r a t u r e ! T e m p e r a t u r e o f t h e p r o d u c t s t r e a m ? pw@ r@ _B H e a t d u t y H e a t d u t y @ ? @ O)@ @x @x D
P r e s s u r e d r o p P r e s s u r e d r o p a l o n g t h e u n i t ? ? _B T h e r m o V e r s i o n * T h e r m o d y n a m i c s C A P E - O P E N I n t e r f a c e v e r s i o n 1 . 1 1 . 0 1 . 0 1 . 1 L a s t r u n + + + s p e c i f i c a t i o n s + + +
H e a t d u t y : 4 9 0 6 4 . 7 1 7 4 9 3 5 4 2 4 W
P r e s s u r e d r o p : 0 P a
+ + + o p t i o n a l p a r a m e t e r s + + +
O u t l e t t e m p e r a t u r e : 3 7 5 K
C G
$not all material ports are connected Inlet Outlet
sb h1h1 sb h1h1 sb h1h1 sb h1h1 @ @ ɿ@ ? ? ? ?@ @ @ @@ɿ @ @ @ Pump_4>Pump - unit increasing the pressure due to the work performed. F^KsHSѪ2R j COUSCOUS0002 P r e s s u r e s p e c . $ P r e s s u r e i n c r e a s e s p e c i f i c a t i o n t y p e P r e s s u r e P r e s s u r e i n c r e a s e P r e s s u r e i n c r e a s e P r e s s u r e E n e r g y s p e c . E n e r g y d e m a n d s p e c i f i c a t i o n t y p e
E f f i c i e n c y
E f f i c i e n c y
E n e r g y d e m a n d
E f f i c i e n c y E n e r g y s p e c i f i c a t i o n s t r e a m P r e s s u r e i n c r e a s e P r e s s u r e i n c r e a s e ? ? u>"A _B P r e s s u r e O u t l e t p r e s s u r e ? 6%A j@ _B
E n e r g y d e m a n d E n e r g y c o n s u m e d b y t h e p u m p @ ? @ 4n܇@ @x D A d i a b a t i c e f f i c i e n c y P u m p a d i a b a t i c e f f i c i e n c y ? ? ? T h e r m o V e r s i o n * T h e r m o d y n a m i c s C A P E - O P E N I n t e r f a c e v e r s i o n 1 . 1 1 . 0 1 . 0 1 . 1 L a s t r u n + + + s p e c i f i c a t i o n s + + +
P r e s s u r e : 7 0 9 2 7 5 P a
A d i a b a t i c e f f i c i e n c y : 0 . 7 5
+ + + o p t i o n a l p a r a m e t e r s + + +
P r e s s u r e i n c r e a s e : 5 9 7 8 1 8 . 5 P a
E n e r g y d e m a n d : 7 6 3 . 5 9 9 4 6 3 3 3 4 0 5 1 W
A d i a b a t i c e f f i c i e n c y : 0 . 7 5
8 <
$not all material ports are connected Inlet Outlet @ @ ?K(^&? @ @ @ @ ?:t=
@ @ ?:t=
@ @ ?:t=
@ @ ?:t=
@ @ ?:t=
@ @ @ HeaterCooler_3MHeaterCooler - heat or cool stream specifying heat duty or outlet temperature z,wK JEKB COUSCOUS0002 T y p e T y p e o f h e a t d u t y s p e c i f i c a t i o n T e m p e r a t u r e H e a t d u t y H e a t d u t y T e m p e r a t u r e E n e r g y i n l e t O u t l e t t e m p e r a t u r e ! T e m p e r a t u r e o f t h e p r o d u c t s t r e a m ? pw@ r@ _B H e a t d u t y H e a t d u t y @ ? @ xN7+@ @x @x D
P r e s s u r e d r o p P r e s s u r e d r o p a l o n g t h e u n i t ? ? _B T h e r m o V e r s i o n * T h e r m o d y n a m i c s C A P E - O P E N I n t e r f a c e v e r s i o n 1 . 1 1 . 0 1 . 0 1 . 1 L a s t r u n + + + s p e c i f i c a t i o n s + + +
H e a t d u t y : 3 7 2 1 4 . 5 4 8 8 3 3 7 4 4 1 W
P r e s s u r e d r o p : 0 P a
+ + + o p t i o n a l p a r a m e t e r s + + +
O u t l e t t e m p e r a t u r e : 3 7 5 K
S W
$not all material ports are connected Inlet Outlet
sb h1h1 sb h1h1 sb h1h1 sb h1h1 @ @ ɿ@ ? ? ? ?@ @ @ @@ɿ @ @ @
membrane 13Unit operation using SciLab script for calculations 0 3=GBGABu @
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i!M 9N)77 W̎X)[4IcU4+A Ъե;pxV!_oak0 Qj! G #A0 l8ksJ^:lxg'iK+$^ZI}MuZg[L^\=,NO"SU~ %T_edPOV*XPŶ{?" DO2}b3a U?0C|ZYKވ DDoa[B '
$TS0T ="bգLj #Z#)hZHy@x!aDɁ"#
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*[^R1c? !a_^|$I&W[W.w?ѽ?33ъ(܄hMsJy3g ѡ~GB?k??ql-%5xDု;Y4T6bf"oh|1y`gyu1NW055H/Ff16KG%ڛ7H=2 uN &-r?PK sB@t*N unit.xmlPK sB@fkP Y 2 calcPK h SciLab Unit Operation File ] f
)Product port "Retentate" is not connected Feed Permeate Retentate @ @ @ @ @ @ @ @ @ @ @ @ @ @ HeaterCooler_3MHeaterCooler - heat or cool stream specifying heat duty or outlet temperature z,wK JEKB COUSCOUS0002 T y p e T y p e o f h e a t d u t y s p e c i f i c a t i o n T e m p e r a t u r e H e a t d u t y H e a t d u t y T e m p e r a t u r e E n e r g y i n l e t O u t l e t t e m p e r a t u r e ! T e m p e r a t u r e o f t h e p r o d u c t s t r e a m ? pw@ r@ _B H e a t d u t y H e a t d u t y @ ? @ e@@ @x @x D
P r e s s u r e d r o p P r e s s u r e d r o p a l o n g t h e u n i t ? ? _B T h e r m o V e r s i o n * T h e r m o d y n a m i c s C A P E - O P E N I n t e r f a c e v e r s i o n 1 . 1 1 . 0 1 . 0 1 . 1 L a s t r u n + + + s p e c i f i c a t i o n s + + +
H e a t d u t y : 2 5 8 5 8 . 1 8 0 6 7 2 5 4 5 5 W
P r e s s u r e d r o p : 0 P a
+ + + o p t i o n a l p a r a m e t e r s + + +
O u t l e t t e m p e r a t u r e : 3 7 5 K
b f
$not all material ports are connected Inlet Outlet
sb h1h1 sb h1h1 sb h1h1 sb h1h1 @ @ ɿ@ ? ? ? ?@ @ @ @@ɿ @ @ @
membrane 13Unit operation using SciLab script for calculations 0 3=GBGABu ?
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i!M 9N)77 W̎X)[4IcU4+A Ъե;pxV!_oak0 Qj! G #A0 l8ksJ^:lxg'iK+$^ZI}MuZg[L^\=,NO"SU~ %T_edPOV*XPŶ{?" DO2}b3a U?0C|ZYKވ DDoa[B '
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P r e s s u r e d r o p P r e s s u r e d r o p a l o n g t h e m i x e r ? ? _B T h e r m o V e r s i o n * T h e r m o d y n a m i c s C A P E - O P E N I n t e r f a c e v e r s i o n 1 . 1 1 . 0 1 . 0 1 . 1 L a s t r u n D + + + s p e c i f i c a t i o n s + + +
N u m b e r o f i n l e t s : 5
P r e s s u r e d r o p : 0 P a
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Compressor_12@Compressor - unit increasing the pressure due to the work input. ɝBsIEGr־y1 p COUSCOUS0002 P r e s s u r e s p e c . T y p e o f p r e s s u r e s p e c i f i c a t i o n P r e s s u r e P r e s s u r e i n c r e a s e P r e s s u r e i n c r e a s e P r e s s u r e E n e r g y s p e c . T y p e o f e n e r g y s p e c i f i c a t i o n
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message: Warning: temperature out of range for heat of vaporization for compound Water (T = 273.00 K, range = [273.15 - 647.28] K)
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message: Warning: temperature out of range for heat of vaporization for compound Water (T = 273.01 K, range = [273.15 - 647.28] K)
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