FSD100MbP?h㈵>dk 1dgffffr@ϼ@Harry KooijmanMethylal purification using DMFiVY%ChemSepfInd.Eng.Chem.Res. (2012) Vol.51 pp. 1281-1292. Read NRTL from library, estimated unknown from UNIFAC.Saved Methylal_DMF.fsd Saved Methylal_DMF.fsd  (last message repeated 1 time) $Saved Methylal_DMF_iecr51p1281.fsd f9x temperaturepressure compositionflowMethylalAUwNA\tYAUAMethylalư>MbP?MbP?MbP?K/C:\Program Files\ChemSepL6v90\pcd\Methylal2.pcd{Methylal CH3OCH2OCH3C3H8O2109-87-5COCOC> ~@"NAC?@ ?s@e@@3 e@ ? S@`Ѷ?`F?=@| 9N?[@@3 e@ ~@eA*? ?@?@3 e@ ~@j6@S& ?Ȕ9@e@deA)@ ~?`Eb?`@3 e@s@@I-@5hTʹ>`fr@@3A@?@ e1@5NL̪ n@@3@h @ᒆ@g׿ ߧ>@@3 e@w@e &G>sF? o@ 8@3 e@@@fҌ?@3E+@?@3 e@s@\X??=j}@3 A 8s@@@f `Tb`7@3 e@ ~@@3y@Ͽ`0 ? 8`fr@@3A@ 8 8 8 8 8 8 85@`f̣@@7G 8 8`fRr@z@ ` 8 8 8@3 e@w@@@@^@@^@`F?@`Ѷ?wK?`F?? ?ۼ?@ܒ?V@`Ѷ?wm@@\@M6cg?@ ?`Ѷ?wMethanolCH3OHCH4O67-56-1COM@:^A?5?@?@ u@@ e@@ e@ {?@`@@ڤ?z?`T=@9`%;?VA3Y@H ALHA 8`•>@W 8 8 8dd@̔e@6??@? 8@ e@q@i`f^@@3.`U>@@ e@@e(A?-??@ e@@3 @j@3Ɍ@o2w?>9@@3c@d@̘@_?@@ e@y@ @3s-@ 1&@@qO?@הY@p@L0hC@?W@R`fq@p@h|@@ @vо@@ e@u@e Q> bJ?כi@M8@ 8n@@@f @O*@ڊ2`_b@z@K> C? [@@ 8q@b@f2@@@@qP?¾q@`fr@@#@@ M]h?58`U!>I@@@d 8 8 8 8 8 8 8Z7@ƫ@ ݔB 8 8`f>s@|@ @*? 8 8@ e@u@ 㥛 u@ X4?#~jL|sj1@G?G?Q?@?@֤?@?ۿ`?6?!S? k??@?@ڤ?D @z@)Տ?@?֤?bWaterHOHH2O 7732-18-5OT9@ uAz?@O?`fRw@`fq@`q@@2@ ??=^@ I9@qU?AӬ`@ AVA 8{J@` 8 8 8$m@`fq@ J{?x?`f:@?Qa@3o@Q:@iX@Y%@ó>@`frp@Q:@eFpAO?| :? :`fq@=:@j)hp࣐a@MоI =@33 @`fq@d0q@@a@eпf'?q@@3@@/@`0;@@`3c?I@@@4?`6l2vG)@`fq@@@h`f`@@Qx2@`T@q@@ 9@e@r>?`ff@ 8`q@Đ@f}@ K? R?sq@@3Ƀ@`1>P? /M@> 8`q@Đ@fJ@d@l v?ϧp@8@@fA`? k !@6l>I@@@d|?`h@ yY.?m@؃@yf7@&@B 8 8tx@@3@ ZWt l> 8 8q@@ 9@ :#J{#Q@\yf8TBfm?w-! b=@p?`ff???`X@B?`i?8? AN?έ?`? ?Q8*@ ?@1(@8@y ?(?B?qN,n-dimethylformamide HCON(CH3)2C3H7NO68-12-2CN(C)C=OTDL@hPAq? Zd?`fz@@ j@@ j@h?FR@ϳ?`\U?'=f@b9{?bA@8ڦAnA 8 cµ1@C 8 8 8EU@@ j@~??L@@JA? 8@ j@L@i `@Ѿ@@ j@L@ejA? ? ?@ j@L@j@@5T@@i?`W?־T@j@dDA]d@@EG@ؓ?%eq@@ '}@@`p+G*@@l2EA>i@p@ ? z@0Azr@p@h#@3@>Ϳ>@n@`fz@e >rP?@`@ 8@ j@@@f ?v>4@@4@s ?@o@`fz@#? ? \@Ȟ&A 8`fz@@@f`DZ`$MQ 5@ j@L@<@u@ǿ`;? 8i@p@ 8 8 8 8 8 8 8 5@`fi@I 8 8`x@$@ a?``˷? 8 8n@`fz@ O@T@T@@t?9g@`γ? 8 8`4?@?'?@6??GR@ϳ?9`@൚d@ P>[? Zd?`γ?activityactivityAactivityCoefficientactivityCoefficientAdensitydensity enthalpyenthalpy enthalpyF enthalpyFentropyentropy!entropyFentropyF excessEnthalpyexcessEnthalpyfugacityfugacityfugacityCoefficientfugacityCoefficientgibbsFreeEnergy gibbsEnergyGG heatCapacityheatCapacityCpKK heatOfVaporizationheatOfVaporizationOidealGasEnthalpyidealGasEnthalpy logFugacityCoefficientlogFugacityCoefficientmolecularWeightmolecularWeightHHHsurfaceTensionsurfaceTensionsurfaceTension (pure)surfaceTension (pure)thermalConductivitythermalConductivity04thermalConductivity (pure)thermalConductivity (pure)RS vaporPressure vaporPressureND viscosity viscosity& viscosity (pure)viscosity (pure)" volumevolumeVapor Vapor phaseLiquid Liquid phase 8 &S:?Dimethoxymethane - Methanolimported from NRTL.IPD+eX?Dimethoxymethane - Waterimported from NRTL.IPD?(Dimethoxymethane - N,n-dimethylformamideimported from NRTL.IPD&S:?Dimethoxymethane - Methanolimported from NRTL.IPDoŏ1?Methanol - Waterimported from NRTL.IPD߾S"@ Methanol - N,n-dimethylformamideimported from NRTL.IPD+eX?Dimethoxymethane - Waterimported from NRTL.IPDoŏ1?Methanol - Waterimported from NRTL.IPD?Water - N,n-dimethylformamideimported from NRTL.IPD?(Dimethoxymethane - N,n-dimethylformamideimported from NRTL.IPD߾S"@ Methanol - N,n-dimethylformamideimported from NRTL.IPD?Water - N,n-dimethylformamideimported from NRTL.IPD?ܵ?Methanol/Waterimported from VANLAAR.IPDc]F'Methanol/n,n-Dimethylformamide p88 1/2cimported from VANLAAR.IPDH}8?Methanol/Waterimported from VANLAAR.IPDn?%Water/N,n-dimethylformamide p232 1/1aimported from VANLAAR.IPD_vǿ'Methanol/n,n-Dimethylformamide p88 1/2cimported from VANLAAR.IPD/n?%Water/N,n-dimethylformamide p232 1/1aimported from VANLAAR.IPDH?Methanol/Waterimported from MARGULES.IPDףp= &Methanol/n,n-Dimethylformamide p88 1/2imported from MARGULES.IPD:M?Methanol/Waterimported from MARGULES.IPDv?$Water/N,n-dimethylformamide p232 1/1imported from MARGULES.IPDj+ݣ&Methanol/n,n-Dimethylformamide p88 1/2imported from MARGULES.IPDZӼ?$Water/N,n-dimethylformamide p232 1/1imported from MARGULES.IPD-QY@Methanol/Waterimported from WILSON.IPDBW1q@'Methanol/n,n-Dimethylformamide p88 1/2cimported from WILSON.IPDPgkYn@Methanol/Waterimported from WILSON.IPD!p&@%Water/N,n-dimethylformamide p234 1/1aimported from WILSON.IPDN߀(y'Methanol/n,n-Dimethylformamide p88 1/2cimported from WILSON.IPD7-UF}%Water/N,n-dimethylformamide p234 1/1aimported from WILSON.IPD8VD&s@Dimethoxymethane - Methanolimported from NRTL.IPD!II@Dimethoxymethane - Waterimported from NRTL.IPD#]\Z@(Dimethoxymethane - N,n-dimethylformamideimported from NRTL.IPDmylN@Dimethoxymethane - Methanolimported from NRTL.IPD:7qWMethanol - Waterimported from NRTL.IPD?8O Methanol - N,n-dimethylformamideimported from NRTL.IPD*6̀@Dimethoxymethane - Waterimported from NRTL.IPD=x@Methanol - Waterimported from NRTL.IPDwRḦ́@Water - N,n-dimethylformamideimported from NRTL.IPD/w(Dimethoxymethane - N,n-dimethylformamideimported from NRTL.IPD椒? Methanol - N,n-dimethylformamideimported from NRTL.IPD\{Water - N,n-dimethylformamideimported from NRTL.IPD G} o8eMethanol/Water (Kojima+Kato)imported from UNIQUAC.IPDvޯS'Methanol/n,n-Dimethylformamide p88 1/2cimported from UNIQUAC.IPDu`Iq@Methanol/Water (Kojima+Kato)imported from UNIQUAC.IPDKnJ t@%Water/N,n-dimethylformamide p234 1/1aimported from UNIQUAC.IPDIϏ+J@'Methanol/n,n-Dimethylformamide p88 1/2cimported from UNIQUAC.IPD}q%Water/N,n-dimethylformamide p234 1/1aimported from UNIQUAC.IPD Gz?Methanol/methanolimported from HAYDENO.IPD?Water/methanolimported from HAYDENO.IPD?Water/methanolimported from HAYDENO.IPD333333? Water/waterimported from HAYDENO.IPD g곿Methanol/Water p730imported from PR.IPD g곿Methanol/Water p730imported from PR.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPD†W2Methanol/Water p730imported from SRK.IPD fffffIMethanol/Waterimported from UNIQUACP.IPDGzX@Methanol/Waterimported from UNIQUACP.IPDCH2CH2OCH3OHH2ODMFCH2N O?HzG?Zd;O ,@CH3ORQ? rh?cX9?@CH3OH?x?L7A`@@H2Oq= ףp?ffffff?kt2@DMF-1M O@S@(\ER@po@Ʌ@@T~@ףp= T@m@33333so@(\0@33333`f̌er@@r@s@33333?fffffcfffffe@qCH2OHH2OCH2N O?HzG?Zd;O ,@CH3ͪ?A`"? rh.@OH?333333?5^I 1@H2Oq= ףp?ffffff?kt2@$@P@33333t@{G<@ffffffu@^;CH2OHH2OCH2??Zd;O ,@CH3?? rh.@OH??5^I 1@H2O??kt2@@ h"?+ DӚ?gsѿ_vOVfffff@33333qTq@V瞯<Methylal109-87-5Dimethoxymethane S@̴s@C3H8O2MethylalMethylal67-56-1Methanol@`@@@ u@CH4OMethylalMethanol 7732-18-5Water2@`fRw@H2OMethylalWater68-12-2N,n-dimethylformamideFR@`fz@C3H7NOMethylalN,n-dimethylformamide ????????????excessEnthalpy.Dpressure??thermalConductivity.Dmoles?? / molenthalpyF.DmolFraction??gibbsFreeEnergy.Dpressure??viscosity.Dtemperature????activityCoefficiententhalpyF.Dpressure??thermalConductivity.Dpressure?? thermalConductivity.Dtemperature??heatCapacity.DmolFraction??entropyF.Dmoles??heatOfVaporization??density.Dpressure?@?@enthalpy.Dmoles??molecularWeight#logFugacityCoefficient.DmolFractionentropy.Dtemperature??viscosity.Dmoles???? / mol volume.Dmoles@@@@vaporPressure.Dtemperature??enthalpy?? enthalpyF??activity.DmolFractionfugacity.Dtemperature??excessEnthalpy.Dtemperature??volume.Dpressure@@@@surfaceTension.DmolFraction?? activityCoefficient.DtemperaturefugacityCoefficient.Dmoles / molgibbsFreeEnergy??activity.Dmoles / molactivityCoefficient.Dmoles / molgibbsFreeEnergy.DmolFraction??enthalpy.DmolFraction??enthalpy.Dpressure??logFugacityCoefficientactivitymolecularWeight.Dtemperaturefugacity.Dpressure fugacityCoefficient.DmolFractiondensity?@?@volume.DmolFraction@@@@activity.DtemperatureenthalpyF.Dtemperature??entropyF.DmolFraction??thermalConductivity??surfaceTension.Dtemperature??density.DmolFraction?@?@surfaceTension??heatCapacity.Dtemperature??#logFugacityCoefficient.DtemperatureexcessEnthalpy??fugacityCoefficient.Dpressureviscosity.DmolFraction????enthalpy.Dtemperature??entropy.Dpressure??surfaceTension.Dmoles?? / molgibbsFreeEnergy.Dmoles??density.Dmoles?@?@ / mol thermalConductivity.DmolFraction??idealGasEnthalpy.Dtemperature??logFugacityCoefficient.Dmoles / molheatOfVaporization.Dtemperature??enthalpyF.Dmoles??surfaceTension.Dpressure??entropy.DmolFraction??entropyF.Dtemperature??entropy??entropyF??volume@@@@heatCapacity.Dpressure??molecularWeight.DpressuregibbsFreeEnergy.Dtemperature??fugacityCoefficientidealGasEnthalpy?? logFugacityCoefficient.Dpressureviscosity.Dpressure??entropy.Dmoles??entropyF.Dpressure?? fugacityCoefficient.Dtemperature heatCapacity??activityCoefficient.Dpressure activityCoefficient.DmolFraction viscosity????excessEnthalpy.Dmoles??volume.Dtemperature@@@@density.Dtemperature?@?@fugacity.Dmoles?? / molheatCapacity.Dmoles??activity.DpressuremolecularWeight.DmolFractionexcessEnthalpy.DmolFraction??molecularWeight.Dmoles / mol@&{71F5AC07-65A1-4357-8F1B-A8CD58148763}RelativePerturbationTemperature?RelativePerturbationPressure?PerturbationComposition?Temperature profile??Pressure profile??Vapour Flow profile??Liquid Flow profile??Duties profile??Vapour Density profile@?@?Vapour Viscosity profile????Vapour Heat capacity profile??#Vapour Thermal conductivity profile??Liquid Density profile@?@?Liquid Viscosity profile????Liquid Heat capacity profile??Liquid Thermal cond. profile??Surface tension profile??TotalMassBalancePropertiesFraction? TotalFlowMass??&{81212F14-4C54-43C0-BFA8-B9C163C9148C} Outlet flow??Net flow??&{779B2C7A-F54B-4A1D-B345-7FA14B889642}Outlet temperature?? Heat duty?? Pressure drop??dheatOfVaporizationheatOfVaporization.DtemperatureidealGasEnthalpyidealGasEnthalpy.Dtemperature vaporPressurevaporPressure.Dtemperatureactivityactivity.Dmolesactivity.DmolFractionactivity.Dpressureactivity.DtemperatureactivityCoefficientactivityCoefficient.Dmoles activityCoefficient.DmolFractionactivityCoefficient.Dpressure activityCoefficient.Dtemperaturedensitydensity.Dmolesdensity.DmolFractiondensity.Dpressuredensity.Dtemperatureenthalpyenthalpy.Dmolesenthalpy.DmolFractionenthalpy.Dpressureenthalpy.Dtemperature enthalpyFenthalpyF.DmolesenthalpyF.DmolFractionenthalpyF.DpressureenthalpyF.Dtemperatureentropyentropy.Dmolesentropy.DmolFractionentropy.Dpressureentropy.DtemperatureentropyFentropyF.DmolesentropyF.DmolFractionentropyF.DpressureentropyF.DtemperatureexcessEnthalpyexcessEnthalpy.DmolesexcessEnthalpy.DmolFractionexcessEnthalpy.DpressureexcessEnthalpy.Dtemperaturefugacityfugacity.Dmolesfugacity.DmolFractionfugacity.Dpressurefugacity.DtemperaturefugacityCoefficientfugacityCoefficient.Dmoles fugacityCoefficient.DmolFractionfugacityCoefficient.Dpressure fugacityCoefficient.DtemperaturegibbsFreeEnergygibbsFreeEnergy.DmolesgibbsFreeEnergy.DmolFractiongibbsFreeEnergy.DpressuregibbsFreeEnergy.Dtemperature heatCapacityheatCapacity.DmolesheatCapacity.DmolFractionheatCapacity.DpressureheatCapacity.DtemperaturelogFugacityCoefficientlogFugacityCoefficient.Dmoles#logFugacityCoefficient.DmolFraction logFugacityCoefficient.Dpressure#logFugacityCoefficient.DtemperaturemolecularWeightmolecularWeight.DmolesmolecularWeight.DmolFractionmolecularWeight.DpressuremolecularWeight.DtemperaturethermalConductivitythermalConductivity.Dmoles thermalConductivity.DmolFractionthermalConductivity.Dpressure thermalConductivity.Dtemperature viscosityviscosity.Dmolesviscosity.DmolFractionviscosity.Dpressureviscosity.Dtemperaturevolume volume.Dmolesvolume.DmolFractionvolume.Dpressurevolume.DtemperaturesurfaceTensionsurfaceTension.DmolessurfaceTension.DmolFractionsurfaceTension.DpressuresurfaceTension.DtemperaturebubblePointTemperaturebubblePointPressuredewPointTemperaturedewPointPressureVapor Vapor phaseMethylalVaporLiquid Liquid phaseMethylalLiquid VaporLiquiddefaultdefault material templateMethylal 2  defaultϼ@MAr@=S &@d?s3GLWu>X\>M>*B?S"??t3GMWu>X\>M>,B?S"???r@K@ U &@rq?2 Pure Methylal)33)3)3 defaultм@7 s@9K"@v?-?z?ADb<`?Y!zaK?1j>sU>SyAn>6}t:>\.QT? !?nʥb?u.}lBsO?eF>[EG>TWW(>OB>?-?z?ADb<`?Y!zaK?1j>sU>SyAn>6}t:>d4)+@4")@+)+4+4@ "defaultм@'؄w@2<3-@5?$?MH)?5T(1?E&Ӄ?pE?ܦm1f?=y#P?[e?GI?1d-FY?˛? ]?U?RZ ~n?4Dz?.y??$?MH)?5T(1?E&Ӄ?pE?ܦm1f?=y#P?[e?2MethanolNUUNUNUU mSepdefaultм@s7%u@1! @3$/?NL³D?CDX?bq?9cE?~7?uL?z∵>̑K>f٥e?:y?44@ t?:?e%)?.d? 9)>}~߬>?NL³D?CDX?bq?9cE?~7?uL?z∵>̑K>XDMF     Gat least one compound needs to be present for materials of type default.rtdefaultK@r@[f@rq?@p@???????r@K@[f@rq?8N*&\&\*N*\*\\.&\.  defaultм@my z@F &@d?4#Wu>~fˆ>׳"Ѭ>??.D$=Gn%=r`G>誒>'D ?hqh>%ۈ?xR ??4#Wu>~fˆ>׳"Ѭ>?? U &@rq?29 defaultK@r@̉f@^o??????d Raw Methylal"" """""  Makdefault@r@yXL*@?v ^?~jt?~?n?0-4؜?~jth??v ^?~jt?~?n?0-4؜?~jth?v ^?~jt?~?n?0-4؜?~jth?r@@yXL*@?11""" defaultм@r@F &@d?4#Wu>~fˆ>׳"Ѭ>???4#Wu>~fˆ>׳"Ѭ>??2C1ChemSep Unit OperationqeWCXcICSUOs[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_3_6~3.sep Title=ChemSep CO Unit Operation "C1" in COFE Flowsheet User=Harry Date=2012-02-06 Time=02:16:20 [Cape-Open] unitname=C1 CO_ID=CS_3_68C_1CCE46C_EE515410 4 components Dimethoxymethane 109-87-5 76.0943984985 Mw Methanol 67-56-1 32.0419998169 Mw Water 7732-18-5 18.0149993896 Mw N,n-dimethylformamide 68-12-2 73.0938034058 Mw 0 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=FALSE WilsonEstimate=TRUE Status= 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=C Flow=mol/s Mass flow=kg/s Pressure=bar Heat=MW Enthalpy=kJ/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=deg Velocity=m/s Surface tension=dyn/cm Density=kg/m3 Molar density=kmol/m3 Viscosity=Pa.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=1e-8 m2/s Interaction parameter=J/mol Time=s [Components] 4 1 1431 Library Offset, Index DT=2012-02-05,19:42:00 CHK=42323 CAS=109-87-5 CID=Dimethoxymethane Name=Dimethoxymethane Lib=c:\program files\chemsepl6v90\pcd\methylal.pcd 32 1101 Library Offset, Index DT=2012-01-31,09:17:24 CHK=37880 CAS=67-56-1 CID=Methanol Name=Methanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 14 1921 Library Offset, Index DT=2012-01-31,09:17:24 CHK=26350 CAS=7732-18-5 CID=Water Name=Water Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 66 1876 Library Offset, Index DT=2012-01-31,09:17:24 CHK=35635 CAS=68-12-2 CID=N,n-dimethylformamide Name=N,n-dimethylformamide Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd [Operation] 2 Operation Column 2 Operation kind Extractive Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 52 Stages 2 Feed stages 0 Sidestream stages F=4,42 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 4 K model DECHEMA 6 1 Activity coefficient NRTL * Wilson model * * UNIQUAC model * * Equation of State * * Cubic EOS * * Virial EOS * 3 Vapour pressure T correlation 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 1 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [NRTL Data] i j Aij Aji aij Component Component 1 2 2547.69 500 0.7259 Dimethoxymethane/Methanol 1 3 6728.16 7607.74 0.4898 Dimethoxymethane/Water 1 4 5299.43 -3188.63 0.2 Dimethoxymethane/N,n-dimethylformamid 2 3 -790.972 3317.08 0.2999 Methanol/Water 2 4 -519.194 1.43427 9.1633 Methanol/N,n-dimethylformamid 3 4 5534.99 -3666.87 0.2 Water/N,n-dimethylformamid [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 51 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 1 Column pressure Constant pressure 101325 Condenser pressure 101325 Top pressure * Pressure Drop * Bottom pressure [Feeds] 2 Number 1 Feed state T & p 4 Stage Feed1{split} 300.000000242 Temperature 101325 Pressure 0 Vapour fraction 4 componentflows 2.19037437742e-017 Component 1 flow 1.99877686907e-009 Component 2 flow 1.10206521555e-007 Component 3 flow 0.0110207337947 Component 4 flow 1 Feed state T & p 42 Stage Feed2{split} 300 Temperature 110000 Pressure 0 Vapour fraction 4 componentflows 0.00939622382341 Component 1 flow 0.00361504693825 Component 2 flow 0.00013877324922 Component 3 flow 0 Component 4 flow [Condenser] 7 Type Mole fraction of a component 0.998 Value Qcondenser 1 1st comp. * Type * * Initialization guess [Reboiler] 7 Type Mole fraction of a component 0.00016 Value Qreboiler 1 1st comp. * Type * * Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data Temperature profile On Vertical Black set label "ChemSep" at 110.6739,2.02 right On Off StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 Temperature (C) 31.88843 110.6739 20 0 Off Off Off y1 Stage 52 1 10 0 Off Off Off x2 0 Off Off Off y2 0 Off Off Off StringGrid=StringGrid3 2 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage 1 T T S x1 y1 C Red Diamond Normal Solid 1 52 CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 0 ComboBox=ComboBox23 1 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Dimethoxymethane - Methanol Xlabel X Dimethoxymethane/(Dimethoxymethane+Methanol) Ylabel Y Dimethoxymethane/(Dimethoxymethane+Methanol) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 -1 ComboBox=ComboBox76 -1 ComboBox=ComboBox77 -1 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 0 Edit=Edit1 1 Edit=Edit2 21 Edit=Edit3 Dimethoxymethane + Methanol @ p=1 (bar) ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 4,42 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 5 7 Identifier L# File Loc. CAS SMILES Name Dimethoxymethane 1431 c:\program files\chemsepl6v90\pcd\methylal.pcd 1 109-87-5 COCOC Dimethoxymethane Methanol 1101 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 67-56-1 CO Methanol Water 1921 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 14 7732-18-5 O Water N,n-dimethylformamide 1876 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 66 68-12-2 CN(C)C=O N,n-dimethylformamide 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 0 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 315.0365297 1.013250000E+05 9.412687887E-03 2.581273285E-02 -9.888025832E+05 2 315.0518675 1.013250000E+05 3.522542074E-02 2.576693650E-02 0.000000000E+00 3 315.3916588 1.013250000E+05 3.517962439E-02 2.462098676E-02 0.000000000E+00 4 323.8622985 1.013250000E+05 3.403367464E-02 3.731670082E-02 0.000000000E+00 5 325.5331743 1.013250000E+05 3.570854271E-02 3.635400478E-02 0.000000000E+00 6 327.7520750 1.013250000E+05 3.474584666E-02 3.577088435E-02 0.000000000E+00 7 329.6676096 1.013250000E+05 3.416272623E-02 3.536254010E-02 0.000000000E+00 8 331.2725089 1.013250000E+05 3.375438199E-02 3.505032662E-02 0.000000000E+00 9 332.6072004 1.013250000E+05 3.344216851E-02 3.481458833E-02 0.000000000E+00 10 333.6817521 1.013250000E+05 3.320643021E-02 3.464169301E-02 0.000000000E+00 11 334.5122293 1.013250000E+05 3.303353489E-02 3.451822352E-02 0.000000000E+00 12 335.1301610 1.013250000E+05 3.291006540E-02 3.443186497E-02 0.000000000E+00 13 335.5759356 1.013250000E+05 3.282370686E-02 3.437236765E-02 0.000000000E+00 14 335.8900554 1.013250000E+05 3.276420954E-02 3.433180568E-02 0.000000000E+00 15 336.1076630 1.013250000E+05 3.272364757E-02 3.430435063E-02 0.000000000E+00 16 336.2566094 1.013250000E+05 3.269619251E-02 3.428585698E-02 0.000000000E+00 17 336.3577137 1.013250000E+05 3.267769886E-02 3.427344007E-02 0.000000000E+00 18 336.4259530 1.013250000E+05 3.266528196E-02 3.426512127E-02 0.000000000E+00 19 336.4718328 1.013250000E+05 3.265696315E-02 3.425955608E-02 0.000000000E+00 20 336.5025993 1.013250000E+05 3.265139796E-02 3.425583663E-02 0.000000000E+00 21 336.5231948 1.013250000E+05 3.264767852E-02 3.425335237E-02 0.000000000E+00 22 336.5369655 1.013250000E+05 3.264519426E-02 3.425169382E-02 0.000000000E+00 23 336.5461658 1.013250000E+05 3.264353571E-02 3.425058685E-02 0.000000000E+00 24 336.5523093 1.013250000E+05 3.264242874E-02 3.424984816E-02 0.000000000E+00 25 336.5564102 1.013250000E+05 3.264169005E-02 3.424935530E-02 0.000000000E+00 26 336.5591470 1.013250000E+05 3.264119719E-02 3.424902648E-02 0.000000000E+00 27 336.5609731 1.013250000E+05 3.264086836E-02 3.424880711E-02 0.000000000E+00 28 336.5621915 1.013250000E+05 3.264064900E-02 3.424866078E-02 0.000000000E+00 29 336.5630043 1.013250000E+05 3.264050266E-02 3.424856316E-02 0.000000000E+00 30 336.5635466 1.013250000E+05 3.264040504E-02 3.424849803E-02 0.000000000E+00 31 336.5639083 1.013250000E+05 3.264033992E-02 3.424845458E-02 0.000000000E+00 32 336.5641497 1.013250000E+05 3.264029647E-02 3.424842556E-02 0.000000000E+00 33 336.5643110 1.013250000E+05 3.264026745E-02 3.424840606E-02 0.000000000E+00 34 336.5644196 1.013250000E+05 3.264024795E-02 3.424839251E-02 0.000000000E+00 35 336.5644955 1.013250000E+05 3.264023440E-02 3.424838162E-02 0.000000000E+00 36 336.5645561 1.013250000E+05 3.264022351E-02 3.424836989E-02 0.000000000E+00 37 336.5645993 1.013250000E+05 3.264021177E-02 3.424837001E-02 0.000000000E+00 38 336.5643189 1.013250000E+05 3.264021190E-02 3.424862676E-02 0.000000000E+00 39 336.5601173 1.013250000E+05 3.264046864E-02 3.425177235E-02 0.000000000E+00 40 336.5172479 1.013250000E+05 3.264361423E-02 3.428288963E-02 0.000000000E+00 41 336.1171058 1.013250000E+05 3.267473152E-02 3.459787637E-02 0.000000000E+00 42 332.1290195 1.013250000E+05 3.298971825E-02 4.721349621E-02 0.000000000E+00 43 336.1351697 1.013250000E+05 3.245529409E-02 4.660066790E-02 0.000000000E+00 44 339.6733871 1.013250000E+05 3.184246578E-02 4.625006655E-02 0.000000000E+00 45 342.1130457 1.013250000E+05 3.149186443E-02 4.608076532E-02 0.000000000E+00 46 343.5259460 1.013250000E+05 3.132256320E-02 4.600396632E-02 0.000000000E+00 47 344.2641432 1.013250000E+05 3.124576419E-02 4.596908102E-02 0.000000000E+00 48 344.6311407 1.013250000E+05 3.121087890E-02 4.595164318E-02 0.000000000E+00 49 344.8289590 1.013250000E+05 3.119344106E-02 4.592696912E-02 0.000000000E+00 50 345.2016416 1.013250000E+05 3.116876700E-02 4.570324154E-02 0.000000000E+00 51 349.0575522 1.013250000E+05 3.094503942E-02 4.380731424E-02 0.000000000E+00 52 376.3029477 1.013250000E+05 2.904911211E-02 1.475820212E-02 1.166868931E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.2630345E+08 -0.2630345E+08 -0.8385138E+05 -0.8385138E+05 2 0.1767256E+07 -0.2630882E+08 0.5251111E+04 -0.8382944E+05 3 0.1799868E+07 -0.2648539E+08 0.5372903E+04 -0.8347293E+05 4 0.2618580E+07 -0.3102515E+08 0.8361694E+04 -0.8320384E+05 5 0.2754513E+07 -0.3179273E+08 0.9467757E+04 -0.8328284E+05 6 0.2887336E+07 -0.3229317E+08 0.1119338E+05 -0.8293211E+05 7 0.2955286E+07 -0.3266906E+08 0.1261388E+05 -0.8279855E+05 8 0.2987904E+07 -0.3297152E+08 0.1358687E+05 -0.8287443E+05 9 0.3003793E+07 -0.3320863E+08 0.1422100E+05 -0.8304575E+05 10 0.3010594E+07 -0.3338773E+08 0.1462216E+05 -0.8323791E+05 11 0.3012347E+07 -0.3351862E+08 0.1486953E+05 -0.8341266E+05 12 0.3011627E+07 -0.3361179E+08 0.1501953E+05 -0.8355524E+05 13 0.3009998E+07 -0.3367683E+08 0.1511003E+05 -0.8366403E+05 14 0.3008275E+07 -0.3372158E+08 0.1516496E+05 -0.8374347E+05 15 0.3006796E+07 -0.3375207E+08 0.1519873E+05 -0.8379979E+05 16 0.3005647E+07 -0.3377270E+08 0.1521983E+05 -0.8383892E+05 17 0.3004803E+07 -0.3378659E+08 0.1523322E+05 -0.8386575E+05 18 0.3004203E+07 -0.3379592E+08 0.1524182E+05 -0.8388398E+05 19 0.3003787E+07 -0.3380217E+08 0.1524742E+05 -0.8389629E+05 20 0.3003502E+07 -0.3380635E+08 0.1525108E+05 -0.8390457E+05 21 0.3003308E+07 -0.3380915E+08 0.1525349E+05 -0.8391012E+05 22 0.3003177E+07 -0.3381101E+08 0.1525509E+05 -0.8391384E+05 23 0.3003089E+07 -0.3381226E+08 0.1525615E+05 -0.8391633E+05 24 0.3003030E+07 -0.3381309E+08 0.1525685E+05 -0.8391799E+05 25 0.3002991E+07 -0.3381365E+08 0.1525732E+05 -0.8391910E+05 26 0.3002965E+07 -0.3381402E+08 0.1525763E+05 -0.8391984E+05 27 0.3002947E+07 -0.3381426E+08 0.1525784E+05 -0.8392033E+05 28 0.3002935E+07 -0.3381443E+08 0.1525797E+05 -0.8392066E+05 29 0.3002927E+07 -0.3381454E+08 0.1525807E+05 -0.8392088E+05 30 0.3002922E+07 -0.3381461E+08 0.1525813E+05 -0.8392103E+05 31 0.3002919E+07 -0.3381466E+08 0.1525817E+05 -0.8392112E+05 32 0.3002916E+07 -0.3381469E+08 0.1525820E+05 -0.8392119E+05 33 0.3002915E+07 -0.3381472E+08 0.1525821E+05 -0.8392123E+05 34 0.3002914E+07 -0.3381473E+08 0.1525823E+05 -0.8392126E+05 35 0.3002913E+07 -0.3381474E+08 0.1525824E+05 -0.8392127E+05 36 0.3002914E+07 -0.3381475E+08 0.1525826E+05 -0.8392124E+05 37 0.3002914E+07 -0.3381478E+08 0.1525833E+05 -0.8392109E+05 38 0.3002885E+07 -0.3381485E+08 0.1525847E+05 -0.8392064E+05 39 0.3002522E+07 -0.3381490E+08 0.1525807E+05 -0.8392018E+05 40 0.2998921E+07 -0.3381317E+08 0.1524858E+05 -0.8392887E+05 41 0.2965683E+07 -0.3378844E+08 0.1514316E+05 -0.8405051E+05 42 0.2640446E+07 -0.3342571E+08 0.1404477E+05 -0.8558327E+05 43 0.2628958E+07 -0.3396486E+08 0.1411195E+05 -0.8700832E+05 44 0.2533809E+07 -0.3432463E+08 0.1310939E+05 -0.8838155E+05 45 0.2411781E+07 -0.3452392E+08 0.1154085E+05 -0.8944793E+05 46 0.2317163E+07 -0.3462410E+08 0.1009138E+05 -0.9016212E+05 47 0.2260224E+07 -0.3467248E+08 0.9054575E+04 -0.9059669E+05 48 0.2230180E+07 -0.3469586E+08 0.8409024E+04 -0.9084347E+05 49 0.2216368E+07 -0.3470987E+08 0.8043994E+04 -0.9095994E+05 50 0.2224947E+07 -0.3474687E+08 0.7922961E+04 -0.9080428E+05 51 0.2437342E+07 -0.3503349E+08 0.8824252E+04 -0.8829281E+05 52 0.4431983E+07 -0.3364903E+08 0.1720959E+05 -0.7541029E+05 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.7599399E+02 0.2939681E+01 0.8738186E-05 0.9536859E+05 0.1436225E-01 2 0.7600696E+02 0.2940040E+01 0.8738008E-05 0.9538755E+05 0.1436274E-01 3 0.7601360E+02 0.2937129E+01 0.8746604E-05 0.9549060E+05 0.1439045E-01 4 0.7597777E+02 0.2858960E+01 0.8970000E-05 0.9781134E+05 0.1509931E-01 5 0.7518177E+02 0.2814487E+01 0.9055257E-05 0.9731961E+05 0.1529588E-01 6 0.7295171E+02 0.2712514E+01 0.9222505E-05 0.9525534E+05 0.1562835E-01 7 0.7006472E+02 0.2590032E+01 0.9412005E-05 0.9228611E+05 0.1597515E-01 8 0.6729026E+02 0.2475419E+01 0.9587307E-05 0.8933198E+05 0.1628847E-01 9 0.6490094E+02 0.2377942E+01 0.9736441E-05 0.8674571E+05 0.1655486E-01 10 0.6296189E+02 0.2299467E+01 0.9856603E-05 0.8462408E+05 0.1677086E-01 11 0.6145858E+02 0.2238991E+01 0.9949131E-05 0.8296589E+05 0.1693848E-01 12 0.6033681E+02 0.2194071E+01 0.1001772E-04 0.8172095E+05 0.1706362E-01 13 0.5952525E+02 0.2161685E+01 0.1006705E-04 0.8081618E+05 0.1715417E-01 14 0.5895192E+02 0.2138862E+01 0.1010173E-04 0.8017491E+05 0.1721813E-01 15 0.5855393E+02 0.2123047E+01 0.1012571E-04 0.7972873E+05 0.1726253E-01 16 0.5828110E+02 0.2112218E+01 0.1014211E-04 0.7942238E+05 0.1729295E-01 17 0.5809569E+02 0.2104866E+01 0.1015323E-04 0.7921396E+05 0.1731362E-01 18 0.5797046E+02 0.2099903E+01 0.1016074E-04 0.7907308E+05 0.1732759E-01 19 0.5788621E+02 0.2096565E+01 0.1016578E-04 0.7897826E+05 0.1733698E-01 20 0.5782970E+02 0.2094327E+01 0.1016916E-04 0.7891464E+05 0.1734328E-01 21 0.5779186E+02 0.2092828E+01 0.1017142E-04 0.7887202E+05 0.1734750E-01 22 0.5776655E+02 0.2091826E+01 0.1017293E-04 0.7884352E+05 0.1735032E-01 23 0.5774964E+02 0.2091157E+01 0.1017395E-04 0.7882447E+05 0.1735220E-01 24 0.5773835E+02 0.2090710E+01 0.1017462E-04 0.7881175E+05 0.1735346E-01 25 0.5773081E+02 0.2090411E+01 0.1017507E-04 0.7880326E+05 0.1735430E-01 26 0.5772578E+02 0.2090212E+01 0.1017537E-04 0.7879759E+05 0.1735486E-01 27 0.5772242E+02 0.2090079E+01 0.1017557E-04 0.7879381E+05 0.1735524E-01 28 0.5772018E+02 0.2089990E+01 0.1017571E-04 0.7879129E+05 0.1735549E-01 29 0.5771869E+02 0.2089931E+01 0.1017579E-04 0.7878961E+05 0.1735565E-01 30 0.5771769E+02 0.2089892E+01 0.1017585E-04 0.7878848E+05 0.1735576E-01 31 0.5771703E+02 0.2089866E+01 0.1017589E-04 0.7878773E+05 0.1735584E-01 32 0.5771658E+02 0.2089848E+01 0.1017592E-04 0.7878723E+05 0.1735589E-01 33 0.5771629E+02 0.2089836E+01 0.1017594E-04 0.7878690E+05 0.1735592E-01 34 0.5771609E+02 0.2089828E+01 0.1017595E-04 0.7878668E+05 0.1735594E-01 35 0.5771596E+02 0.2089823E+01 0.1017596E-04 0.7878653E+05 0.1735596E-01 36 0.5771587E+02 0.2089819E+01 0.1017596E-04 0.7878643E+05 0.1735597E-01 37 0.5771579E+02 0.2089816E+01 0.1017597E-04 0.7878634E+05 0.1735598E-01 38 0.5771564E+02 0.2089813E+01 0.1017597E-04 0.7878612E+05 0.1735597E-01 39 0.5771497E+02 0.2089814E+01 0.1017590E-04 0.7878451E+05 0.1735566E-01 40 0.5771047E+02 0.2089918E+01 0.1017501E-04 0.7877084E+05 0.1735229E-01 41 0.5767630E+02 0.2091167E+01 0.1016610E-04 0.7865231E+05 0.1731993E-01 42 0.5739343E+02 0.2105898E+01 0.1007087E-04 0.7754753E+05 0.1699049E-01 43 0.5059589E+02 0.1834354E+01 0.1047329E-04 0.6995207E+05 0.1777683E-01 44 0.4398270E+02 0.1577983E+01 0.1081364E-04 0.6228437E+05 0.1851803E-01 45 0.3899353E+02 0.1389008E+01 0.1101839E-04 0.5633919E+05 0.1906155E-01 46 0.3592208E+02 0.1274336E+01 0.1111345E-04 0.5261817E+05 0.1939011E-01 47 0.3426111E+02 0.1212807E+01 0.1115261E-04 0.5058804E+05 0.1956605E-01 48 0.3342489E+02 0.1181945E+01 0.1116869E-04 0.4956164E+05 0.1965440E-01 49 0.3301988E+02 0.1166954E+01 0.1117609E-04 0.4906557E+05 0.1969912E-01 50 0.3285013E+02 0.1159701E+01 0.1118566E-04 0.4888384E+05 0.1974426E-01 51 0.3316006E+02 0.1157711E+01 0.1126426E-04 0.4963114E+05 0.2006882E-01 52 0.3860291E+02 0.1250157E+01 0.1144363E-04 0.6011340E+05 0.2191680E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.7600696E+02 0.8466495E+03 0.2770904E-03 0.1620957E+06 0.1383434E+00 0.1826298E-01 2 0.7601602E+02 0.8466816E+03 0.2771524E-03 0.1621153E+06 0.1383475E+00 0.1826778E-01 3 0.7596661E+02 0.8477284E+03 0.2794950E-03 0.1622429E+06 0.1388181E+00 0.1840331E-01 4 0.7435682E+02 0.8690659E+03 0.3382495E-03 0.1656937E+06 0.1499839E+00 0.2158247E-01 5 0.7220356E+02 0.8697475E+03 0.3427027E-03 0.1645371E+06 0.1527370E+00 0.2163755E-01 6 0.6943417E+02 0.8696927E+03 0.3467247E-03 0.1608124E+06 0.1560707E+00 0.2164359E-01 7 0.6677859E+02 0.8693445E+03 0.3507996E-03 0.1571386E+06 0.1592665E+00 0.2167251E-01 8 0.6449434E+02 0.8686789E+03 0.3542913E-03 0.1541295E+06 0.1620073E+00 0.2170877E-01 9 0.6264211E+02 0.8677915E+03 0.3569362E-03 0.1517891E+06 0.1642104E+00 0.2173955E-01 10 0.6120699E+02 0.8668497E+03 0.3588040E-03 0.1500264E+06 0.1659003E+00 0.2176212E-01 11 0.6013658E+02 0.8659874E+03 0.3600716E-03 0.1487360E+06 0.1671489E+00 0.2177759E-01 12 0.5936242E+02 0.8652731E+03 0.3609141E-03 0.1478140E+06 0.1680452E+00 0.2178788E-01 13 0.5881564E+02 0.8647206E+03 0.3614692E-03 0.1471679E+06 0.1686744E+00 0.2179463E-01 14 0.5843613E+02 0.8643131E+03 0.3618343E-03 0.1467219E+06 0.1691093E+00 0.2179904E-01 15 0.5817599E+02 0.8640222E+03 0.3620747E-03 0.1464173E+06 0.1694065E+00 0.2180194E-01 16 0.5799923E+02 0.8638190E+03 0.3622335E-03 0.1462108E+06 0.1696080E+00 0.2180384E-01 17 0.5787983E+02 0.8636793E+03 0.3623385E-03 0.1460715E+06 0.1697439E+00 0.2180510E-01 18 0.5779952E+02 0.8635842E+03 0.3624082E-03 0.1459779E+06 0.1698353E+00 0.2180593E-01 19 0.5774564E+02 0.8635199E+03 0.3624546E-03 0.1459152E+06 0.1698965E+00 0.2180648E-01 20 0.5770957E+02 0.8634765E+03 0.3624854E-03 0.1458732E+06 0.1699375E+00 0.2180685E-01 21 0.5768544E+02 0.8634475E+03 0.3625059E-03 0.1458451E+06 0.1699649E+00 0.2180709E-01 22 0.5766933E+02 0.8634280E+03 0.3625196E-03 0.1458263E+06 0.1699832E+00 0.2180725E-01 23 0.5765856E+02 0.8634150E+03 0.3625287E-03 0.1458138E+06 0.1699954E+00 0.2180736E-01 24 0.5765138E+02 0.8634063E+03 0.3625347E-03 0.1458055E+06 0.1700036E+00 0.2180743E-01 25 0.5764658E+02 0.8634005E+03 0.3625388E-03 0.1457999E+06 0.1700090E+00 0.2180748E-01 26 0.5764338E+02 0.8633966E+03 0.3625415E-03 0.1457962E+06 0.1700126E+00 0.2180751E-01 27 0.5764124E+02 0.8633940E+03 0.3625433E-03 0.1457937E+06 0.1700151E+00 0.2180753E-01 28 0.5763982E+02 0.8633923E+03 0.3625445E-03 0.1457920E+06 0.1700167E+00 0.2180755E-01 29 0.5763887E+02 0.8633911E+03 0.3625453E-03 0.1457909E+06 0.1700177E+00 0.2180756E-01 30 0.5763824E+02 0.8633903E+03 0.3625458E-03 0.1457902E+06 0.1700185E+00 0.2180757E-01 31 0.5763781E+02 0.8633898E+03 0.3625462E-03 0.1457897E+06 0.1700189E+00 0.2180757E-01 32 0.5763753E+02 0.8633895E+03 0.3625464E-03 0.1457894E+06 0.1700193E+00 0.2180757E-01 33 0.5763734E+02 0.8633893E+03 0.3625466E-03 0.1457891E+06 0.1700195E+00 0.2180757E-01 34 0.5763722E+02 0.8633891E+03 0.3625467E-03 0.1457890E+06 0.1700196E+00 0.2180758E-01 35 0.5763713E+02 0.8633890E+03 0.3625468E-03 0.1457889E+06 0.1700198E+00 0.2180758E-01 36 0.5763705E+02 0.8633889E+03 0.3625469E-03 0.1457888E+06 0.1700202E+00 0.2180761E-01 37 0.5763691E+02 0.8633889E+03 0.3625471E-03 0.1457886E+06 0.1700213E+00 0.2180771E-01 38 0.5763627E+02 0.8633884E+03 0.3625476E-03 0.1457876E+06 0.1700261E+00 0.2180808E-01 39 0.5763200E+02 0.8633837E+03 0.3625486E-03 0.1457805E+06 0.1700465E+00 0.2180922E-01 40 0.5759950E+02 0.8633396E+03 0.3625431E-03 0.1457253E+06 0.1701384E+00 0.2181062E-01 41 0.5733047E+02 0.8629273E+03 0.3624322E-03 0.1452633E+06 0.1705978E+00 0.2178784E-01 42 0.5433949E+02 0.8570379E+03 0.3605149E-03 0.1403824E+06 0.1737308E+00 0.2132110E-01 43 0.4986990E+02 0.8479249E+03 0.3630102E-03 0.1354067E+06 0.1788023E+00 0.2133450E-01 44 0.4651738E+02 0.8383928E+03 0.3626064E-03 0.1317805E+06 0.1824007E+00 0.2130755E-01 45 0.4445726E+02 0.8312031E+03 0.3612624E-03 0.1296063E+06 0.1845071E+00 0.2127242E-01 46 0.4334338E+02 0.8268489E+03 0.3601617E-03 0.1284511E+06 0.1856094E+00 0.2124688E-01 47 0.4278252E+02 0.8245260E+03 0.3595045E-03 0.1278753E+06 0.1861587E+00 0.2123263E-01 48 0.4251114E+02 0.8233741E+03 0.3591625E-03 0.1275982E+06 0.1864433E+00 0.2122758E-01 49 0.4240104E+02 0.8229259E+03 0.3590218E-03 0.1274920E+06 0.1866527E+00 0.2123778E-01 50 0.4265764E+02 0.8242163E+03 0.3593323E-03 0.1278715E+06 0.1868990E+00 0.2133894E-01 51 0.4667790E+02 0.8404150E+03 0.3631899E-03 0.1336996E+06 0.1856024E+00 0.2223455E-01 52 0.6257219E+02 0.8588809E+03 0.3495158E-03 0.1624523E+06 0.1719722E+00 0.2375065E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.997720870E+00 0.998000000E+00 0.997794740E+00 0.988544932E+00 0.970889316E+00 2 0.227632115E-02 0.198211779E-02 0.180600153E-02 0.200278572E-02 0.201022989E-01 3 0.229791235E-05 0.125901171E-05 0.845293938E-06 0.763622895E-06 0.788079328E-06 4 0.511335934E-06 0.166231981E-04 0.398412747E-03 0.945151900E-02 0.900759683E-02 Component Mole fractions on stages: 6 to 10 1 0.920350123E+00 0.854579497E+00 0.791165504E+00 0.736416584E+00 0.691900254E+00 2 0.707313857E-01 0.136249363E+00 0.199198697E+00 0.253399374E+00 0.297379715E+00 3 0.812803042E-06 0.833578037E-06 0.856719232E-06 0.881727166E-06 0.905716846E-06 4 0.891767814E-02 0.917030602E-02 0.963494249E-02 0.101831608E-01 0.107191251E-01 Component Mole fractions on stages: 11 to 15 1 0.657339462E+00 0.631525058E+00 0.612836582E+00 0.599627893E+00 0.590455889E+00 2 0.331473539E+00 0.356912345E+00 0.375315461E+00 0.388315961E+00 0.397340337E+00 3 0.926478992E-06 0.943110752E-06 0.955707346E-06 0.964875244E-06 0.971364560E-06 4 0.111860719E-01 0.115616537E-01 0.118470019E-01 0.120551818E-01 0.122028029E-01 Component Mole fractions on stages: 16 to 20 1 0.584166870E+00 0.579892534E+00 0.577005072E+00 0.575062546E+00 0.573759374E+00 2 0.403526714E+00 0.407730642E+00 0.410570248E+00 0.412480448E+00 0.413761873E+00 3 0.975870568E-06 0.978958683E-06 0.981056350E-06 0.982472722E-06 0.983425233E-06 4 0.123054400E-01 0.123758447E-01 0.124236987E-01 0.124560243E-01 0.124777696E-01 Component Mole fractions on stages: 21 to 25 1 0.572886768E+00 0.572303209E+00 0.571913282E+00 0.571652886E+00 0.571479056E+00 2 0.414619891E+00 0.415193683E+00 0.415577078E+00 0.415833110E+00 0.416004025E+00 3 0.984064071E-06 0.984491758E-06 0.984777740E-06 0.984968820E-06 0.985096442E-06 4 0.124923568E-01 0.125021239E-01 0.125086554E-01 0.125130195E-01 0.125159339E-01 Component Mole fractions on stages: 26 to 30 1 0.571363045E+00 0.571285633E+00 0.571233984E+00 0.571199527E+00 0.571176540E+00 2 0.416118091E+00 0.416194204E+00 0.416244986E+00 0.416278866E+00 0.416301467E+00 3 0.985181736E-06 0.985239072E-06 0.985279011E-06 0.985312477E-06 0.985362480E-06 4 0.125178794E-01 0.125191778E-01 0.125200441E-01 0.125206222E-01 0.125210078E-01 Component Mole fractions on stages: 31 to 35 1 0.571161205E+00 0.571150975E+00 0.571144151E+00 0.571139596E+00 0.571136548E+00 2 0.416316544E+00 0.416326602E+00 0.416333309E+00 0.416337778E+00 0.416340737E+00 3 0.985508153E-06 0.986061125E-06 0.988279689E-06 0.997265914E-06 0.103372178E-05 4 0.125212651E-01 0.125214368E-01 0.125215514E-01 0.125216285E-01 0.125216816E-01 Component Mole fractions on stages: 36 to 40 1 0.571134472E+00 0.571132907E+00 0.571131056E+00 0.571125918E+00 0.571101178E+00 2 0.416342629E+00 0.416343627E+00 0.416343773E+00 0.416346549E+00 0.416400421E+00 3 0.118165640E-05 0.178198723E-05 0.421819656E-05 0.141046827E-04 0.542289964E-04 4 0.125217170E-01 0.125216847E-01 0.125209528E-01 0.125134287E-01 0.124441716E-01 Component Mole fractions on stages: 41 to 45 1 0.570948278E+00 0.569603792E+00 0.413372296E+00 0.261109789E+00 0.146114546E+00 2 0.417002849E+00 0.422899264E+00 0.576882691E+00 0.726652662E+00 0.839628722E+00 3 0.217224707E-03 0.885109796E-03 0.102041791E-02 0.116527924E-02 0.127867855E-02 4 0.118316491E-01 0.661183410E-02 0.872459529E-02 0.110722700E-01 0.129780533E-01 Component Mole fractions on stages: 46 to 50 1 0.752784791E-01 0.369611534E-01 0.176697849E-01 0.830598054E-02 0.384240470E-02 2 0.909173951E+00 0.946776171E+00 0.965685214E+00 0.974751075E+00 0.978130572E+00 3 0.135029664E-02 0.139308824E-02 0.143096405E-02 0.151707286E-02 0.183695339E-02 4 0.141972730E-01 0.148695871E-01 0.152140372E-01 0.154258716E-01 0.161900700E-01 Component Mole fractions on stages: 51 to 52 1 0.174146651E-02 0.782612297E-03 2 0.968705170E+00 0.829535471E+00 3 0.312048689E-02 0.797604092E-02 4 0.264328771E-01 0.161705876E+00 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.998000000E+00 0.997719759E+00 0.984930227E+00 0.677315506E+00 0.621237795E+00 2 0.198211779E-02 0.174166608E-02 0.201068715E-02 0.187360813E-01 0.670893575E-01 3 0.125901171E-05 0.694162420E-06 0.574234050E-06 0.338982276E-05 0.348234996E-05 4 0.166231981E-04 0.537880854E-03 0.130585121E-01 0.303945023E+00 0.311669366E+00 Component Mole fractions on stages: 6 to 10 1 0.553548040E+00 0.489541760E+00 0.434618060E+00 0.390114479E+00 0.355651889E+00 2 0.129602461E+00 0.189612336E+00 0.241240819E+00 0.283107289E+00 0.315547155E+00 3 0.354570869E-05 0.359911548E-05 0.364740412E-05 0.368901276E-05 0.372270239E-05 4 0.316845954E+00 0.320842304E+00 0.324137473E+00 0.326774543E+00 0.328797233E+00 Component Mole fractions on stages: 11 to 15 1 0.329961026E+00 0.311389052E+00 0.298276555E+00 0.289178146E+00 0.282942827E+00 2 0.339743833E+00 0.357244361E+00 0.369605335E+00 0.378184888E+00 0.384065922E+00 3 0.374856121E-05 0.376760583E-05 0.378121209E-05 0.379072485E-05 0.379727606E-05 4 0.330291392E+00 0.331362819E+00 0.332114329E+00 0.332633176E+00 0.332987454E+00 Component Mole fractions on stages: 16 to 20 1 0.278706497E+00 0.275845402E+00 0.273920929E+00 0.272630010E+00 0.271765674E+00 2 0.388062170E+00 0.390761413E+00 0.392577152E+00 0.393795194E+00 0.394610764E+00 3 0.380174118E-05 0.380476309E-05 0.380679852E-05 0.380816511E-05 0.380908066E-05 4 0.333227531E+00 0.333389380E+00 0.333498112E+00 0.333570987E+00 0.333619754E+00 Component Mole fractions on stages: 21 to 25 1 0.271187673E+00 0.270801473E+00 0.270543571E+00 0.270371409E+00 0.270256512E+00 2 0.395156165E+00 0.395520589E+00 0.395763952E+00 0.395926409E+00 0.396034830E+00 3 0.380969315E-05 0.381010251E-05 0.381037593E-05 0.381055850E-05 0.381068045E-05 4 0.333652352E+00 0.333674128E+00 0.333688667E+00 0.333698372E+00 0.333704848E+00 Component Mole fractions on stages: 26 to 30 1 0.270179844E+00 0.270128692E+00 0.270094566E+00 0.270071800E+00 0.270056613E+00 2 0.396107176E+00 0.396155445E+00 0.396187648E+00 0.396209131E+00 0.396223462E+00 3 0.381076222E-05 0.381081838E-05 0.381086235E-05 0.381091806E-05 0.381106226E-05 4 0.333709169E+00 0.333712052E+00 0.333713975E+00 0.333715258E+00 0.333716114E+00 Component Mole fractions on stages: 31 to 35 1 0.270046482E+00 0.270039722E+00 0.270035210E+00 0.270032186E+00 0.270030111E+00 2 0.396233022E+00 0.396239397E+00 0.396243645E+00 0.396246457E+00 0.396248254E+00 3 0.381159286E-05 0.381370964E-05 0.382227552E-05 0.385702069E-05 0.399800983E-05 4 0.333716685E+00 0.333717067E+00 0.333717323E+00 0.333717501E+00 0.333717636E+00 Component Mole fractions on stages: 36 to 40 1 0.270028516E+00 0.270026754E+00 0.270024114E+00 0.270028189E+00 0.270155733E+00 2 0.396249198E+00 0.396249337E+00 0.396252133E+00 0.396305322E+00 0.396897730E+00 3 0.457015264E-05 0.689196790E-05 0.163142101E-04 0.545544405E-04 0.209903975E-03 4 0.333717716E+00 0.333717017E+00 0.333707438E+00 0.333611935E+00 0.332736634E+00 Component Mole fractions on stages: 41 to 45 1 0.271612223E+00 0.284208581E+00 0.178468275E+00 0.995410629E-01 0.512204217E-01 2 0.402703113E+00 0.472731127E+00 0.573700026E+00 0.649466434E+00 0.696039881E+00 3 0.846811473E-03 0.364280518E-02 0.377627569E-02 0.387328257E-02 0.393149627E-02 4 0.324837853E+00 0.239417487E+00 0.244055423E+00 0.247119221E+00 0.248808201E+00 Component Mole fractions on stages: 46 to 50 1 0.251552396E-01 0.120483337E-01 0.568975141E-02 0.265909838E-02 0.123078933E-02 2 0.721223397E+00 0.733890593E+00 0.739956827E+00 0.742124212E+00 0.734587097E+00 3 0.396486926E-02 0.399253686E-02 0.405196235E-02 0.427041412E-02 0.515138942E-02 4 0.249656494E+00 0.250068536E+00 0.250301459E+00 0.250946276E+00 0.259030724E+00 Component Mole fractions on stages: 51 to 52 1 0.572861065E-03 0.160000000E-03 2 0.632169793E+00 0.243687669E+00 3 0.845905572E-02 0.940979151E-02 4 0.358798290E+00 0.746742539E+00 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 21 to 25 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 26 to 30 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 31 to 35 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 36 to 40 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 41 to 45 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 46 to 50 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 51 to 52 1 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -9.888025832E+05 [Reboiler Heat Duty] 1.166868931E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.999720312E+00 0.100028088E+01 0.101306135E+01 0.145950436E+01 0.156283041E+01 2 0.114842880E+01 0.113805845E+01 0.898201161E+00 0.106894590E+00 0.299634690E+00 3 0.182517156E+01 0.181371344E+01 0.147203730E+01 0.225269269E+00 0.226306757E+00 4 0.307603826E-01 0.309049821E-01 0.305098119E-01 0.310961467E-01 0.289011299E-01 Component K-values on stages: 6 to 10 1 0.166263822E+01 0.174567232E+01 0.182036960E+01 0.188769354E+01 0.194544237E+01 2 0.545756505E+00 0.718568031E+00 0.825725503E+00 0.895064818E+00 0.942425597E+00 3 0.229235709E+00 0.231606361E+00 0.234884647E+00 0.239014398E+00 0.243295529E+00 4 0.281451539E-01 0.285819729E-01 0.297248646E-01 0.311626502E-01 0.326010199E-01 Component K-values on stages: 11 to 15 1 0.199217304E+01 0.202809011E+01 0.205459186E+01 0.207355881E+01 0.208683816E+01 2 0.975657267E+00 0.999070617E+00 0.101544925E+01 0.102678868E+01 0.103456285E+01 3 0.247155892E+00 0.250320971E+00 0.252751585E+00 0.254535816E+00 0.255805621E+00 4 0.338672825E-01 0.348912221E-01 0.356714567E-01 0.362416699E-01 0.366464344E-01 Component K-values on stages: 16 to 20 1 0.209599301E+01 0.210223745E+01 0.210646581E+01 0.210931491E+01 0.211122828E+01 2 0.103985068E+01 0.104342606E+01 0.104583328E+01 0.104744917E+01 0.104853165E+01 3 0.256690426E+00 0.257298198E+00 0.257711656E+00 0.257991105E+00 0.258179157E+00 4 0.369280412E-01 0.371212926E-01 0.372526809E-01 0.373414500E-01 0.374011716E-01 Component K-values on stages: 21 to 25 1 0.211251036E+01 0.211336815E+01 0.211394150E+01 0.211432447E+01 0.211458015E+01 2 0.104925578E+01 0.104973975E+01 0.105006299E+01 0.105027879E+01 0.105042283E+01 3 0.258305337E+00 0.258389835E+00 0.258446347E+00 0.258484109E+00 0.258509328E+00 4 0.374412371E-01 0.374680649E-01 0.374860061E-01 0.374979941E-01 0.375059997E-01 Component K-values on stages: 26 to 30 1 0.211475081E+01 0.211486469E+01 0.211494068E+01 0.211499137E+01 0.211502519E+01 2 0.105051894E+01 0.105058307E+01 0.105062585E+01 0.105065440E+01 0.105067344E+01 3 0.258526163E+00 0.258537398E+00 0.258544896E+00 0.258549898E+00 0.258553236E+00 4 0.375113439E-01 0.375149105E-01 0.375172904E-01 0.375188783E-01 0.375199377E-01 Component K-values on stages: 31 to 35 1 0.211504775E+01 0.211506281E+01 0.211507289E+01 0.211507971E+01 0.211508467E+01 2 0.105068614E+01 0.105069462E+01 0.105070028E+01 0.105070410E+01 0.105070681E+01 3 0.258555462E+00 0.258556948E+00 0.258557941E+00 0.258558612E+00 0.258559088E+00 4 0.375206444E-01 0.375211160E-01 0.375214308E-01 0.375216419E-01 0.375217855E-01 Component K-values on stages: 36 to 40 1 0.211508947E+01 0.211509748E+01 0.211511130E+01 0.211506036E+01 0.211397024E+01 2 0.105070908E+01 0.105071123E+01 0.105070418E+01 0.105057017E+01 0.104913783E+01 3 0.258559505E+00 0.258560001E+00 0.258559657E+00 0.258543257E+00 0.258351451E+00 4 0.375218829E-01 0.375218645E-01 0.375207483E-01 0.375089360E-01 0.373994635E-01 Component K-values on stages: 41 to 45 1 0.210207137E+01 0.200417521E+01 0.231622284E+01 0.262313643E+01 0.285266190E+01 2 0.103550937E+01 0.894587302E+00 0.100554761E+01 0.111884560E+01 0.120629398E+01 3 0.256520741E+00 0.242974782E+00 0.270218065E+00 0.300850561E+00 0.325239669E+00 4 0.364232463E-01 0.276163373E-01 0.357484181E-01 0.448053776E-01 0.521608742E-01 Component K-values on stages: 46 to 50 1 0.299255663E+01 0.306773984E+01 0.310554603E+01 0.312360783E+01 0.312190282E+01 2 0.126059964E+01 0.129007808E+01 0.130505616E+01 0.131346082E+01 0.133153791E+01 3 0.340565239E+00 0.348923076E+00 0.353153342E+00 0.355251932E+00 0.356593772E+00 4 0.568672291E-01 0.594620474E-01 0.607828544E-01 0.614708132E-01 0.625025084E-01 Component K-values on stages: 51 to 52 1 0.303994567E+01 0.489132685E+01 2 0.153234966E+01 0.340409292E+01 3 0.368893053E+00 0.847632054E+00 4 0.736705771E-01 0.216548365E+00 [Molecular weights] 1 76.094 2 32.042 3 18.015 4 73.094 [Feed stream 1] 4 Stage Number 1.1020845999998E-02 Flow rate 3.0000000024200E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -4.6720513665178E+07 Enthalpy [J/kmol] -1.1748328433789E+05 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.9874829731042E-15 Mole fraction of component 1 1.8136328817863E-07 Mole fraction of component 2 9.9998241110542E-06 Mole fraction of component 3 9.9998981881260E-01 Mole fraction of component 4 1.1020845999998E-02 Flow rate 1.9874829731042E-15 Mole fraction of component 1 1.8136328817863E-07 Mole fraction of component 2 9.9998241110542E-06 Mole fraction of component 3 9.9998981881260E-01 Mole fraction of component 4 7.3093245182119E+01 Molar mass 9.4221553570179E+02 Density 7.9929556408023E-04 Viscosity 1.8552730477420E-01 Thermal conductivity 1.4497732387500E+05 Heat capacity 3.4297224431565E-02 Surface tension [Feed stream 2] 42 Stage Number 1.3150044010880E-02 Flow rate 3.0000000000000E+02 Temperature [K] 1.1000000000000E+05 Pressure [Pa] -3.0977247543780E+07 Enthalpy [J/kmol] -9.2406592987855E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 7.1453934417526E-01 Mole fraction of component 1 2.7490759234410E-01 Mole fraction of component 2 1.0553063480638E-02 Mole fraction of component 3 0.0000000000000E+00 Mole fraction of component 4 1.3150044010880E-02 Flow rate 7.1453934417526E-01 Mole fraction of component 1 2.7490759234410E-01 Mole fraction of component 2 1.0553063480638E-02 Mole fraction of component 3 0.0000000000000E+00 Mole fraction of component 4 6.3371144054269E+01 Molar mass 8.7491817923900E+02 Density 3.6771154851007E-04 Viscosity 1.6314378847443E-01 Thermal conductivity 1.4124322573169E+05 Heat capacity 2.1332962516154E-02 Surface tension [Reflashed Feed stream 1] 4 Stage Number 1.1020845999998E-02 Flow rate 3.0000000048447E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -4.6720513665178E+07 Enthalpy [J/kmol] -1.1748328419787E+05 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.9874829731042E-15 Mole fraction of component 1 1.8136328817863E-07 Mole fraction of component 2 9.9998241110542E-06 Mole fraction of component 3 9.9998981881260E-01 Mole fraction of component 4 1.1020845999998E-02 Flow rate 1.9874829731042E-15 Mole fraction of component 1 1.8136328817863E-07 Mole fraction of component 2 9.9998241110542E-06 Mole fraction of component 3 9.9998981881260E-01 Mole fraction of component 4 7.3093245182119E+01 Molar mass 9.4221553548566E+02 Density 7.9929556172851E-04 Viscosity 1.8552730469222E-01 Thermal conductivity 1.4497732396254E+05 Heat capacity 3.4297224405176E-02 Surface tension [Reflashed Feed stream 2] 42 Stage Number 1.3150044010880E-02 Flow rate 2.9999999999722E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -3.0977247543780E+07 Enthalpy [J/kmol] -9.2406592989119E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 7.1453934417526E-01 Mole fraction of component 1 2.7490759234410E-01 Mole fraction of component 2 1.0553063480638E-02 Mole fraction of component 3 0.0000000000000E+00 Mole fraction of component 4 1.3150044010880E-02 Flow rate 7.1453934417526E-01 Mole fraction of component 1 2.7490759234410E-01 Mole fraction of component 2 1.0553063480638E-02 Mole fraction of component 3 0.0000000000000E+00 Mole fraction of component 4 6.3371144054269E+01 Molar mass 8.7491817924283E+02 Density 3.6771154852063E-04 Viscosity 1.6314378847510E-01 Thermal conductivity 1.4124322573066E+05 Heat capacity 2.1332962516495E-02 Surface tension [Top product] 1 Stage Number 9.4126878870000E-03 Flow rate 3.1503652970000E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -2.6303454018615E+07 Enthalpy [J/kmol] -8.3851381596725E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 9.9800000000000E-01 Mole fraction of component 1 1.9821177900000E-03 Mole fraction of component 2 1.2590117100000E-06 Mole fraction of component 3 1.6623198100000E-05 Mole fraction of component 4 9.4126878870000E-03 Flow rate 9.9800000000000E-01 Mole fraction of component 1 1.9821177900000E-03 Mole fraction of component 2 1.2590117100000E-06 Mole fraction of component 3 1.6623198100000E-05 Mole fraction of component 4 7.6006958453271E+01 Molar mass 8.4664951589975E+02 Density 2.7709037578694E-04 Viscosity 1.3834338258250E-01 Thermal conductivity 1.6209571848138E+05 Heat capacity 1.8262977436676E-02 Surface tension [Bottom product] 52 Stage Number 1.4758202120000E-02 Flow rate 3.7630294770000E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -3.3649031205515E+07 Enthalpy [J/kmol] -7.5410289740918E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.6000000000000E-04 Mole fraction of component 1 2.4368766900000E-01 Mole fraction of component 2 9.4097915100000E-03 Mole fraction of component 3 7.4674253900000E-01 Mole fraction of component 4 1.4758202120000E-02 Flow rate 1.6000000000000E-04 Mole fraction of component 1 2.4368766900000E-01 Mole fraction of component 2 9.4097915100000E-03 Mole fraction of component 3 7.4674253900000E-01 Mole fraction of component 4 6.2572185077932E+01 Molar mass 8.5888091671854E+02 Density 3.4951583724799E-04 Viscosity 1.7197218500704E-01 Thermal conductivity 1.6245225726660E+05 Heat capacity 2.3750651347360E-02 Surface tension [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stage4S*s@s԰s@ ?@(5?@QgrZ1?@ߤiP4+?@Tz>@Iz =@(Liquid Flow profile4Liquid Flow at each stage4"B9@ԛQU9@r8@BB@$]TP-B@VA@~ȶgA@UIqA@ц.nDhA@"RA@5%UBA@8YG7A@Pk?/A@țx*A@.!&A@w7&$A@q#A@h~!A@5"9!A@|3A A@m A@ʀ7 A@a: A@8FA@JA@A@,;PA@A@`A@7A@\A@aأhA@A@eSA@i A@9nA@ A@#mA@: A@ 65$A@6LA@SG@ LG@k C. G@V G@WG@ F@ǗqF@fF@F@2VE@Pz3-@Duties profile*Duties at each stage40*-.V1A4Vapour Moleweight profile@Vapour Moleweight at each stage4D;R@U[rS@pΈS@@ȓR@6YR@Q9P@,&6{O@LۿN@{+N@Zd;M@D4yM@"-FM@s#M@F? M@ 8L@KToL@3L@Z![L@_vOL@4L@4@L@}˜.L@ [L@0BxL@ܝ.L@+L@GUDL@ L@{L@9dL@M֨L@AȓL@ϠL@fL@mL@#L@eSL@t$L@ [L@FLI@E@%̴+C@%A@LTo l!A@2b@@m@@Ql@@겘|@@77',MC@.Vapour Density profile:Vapour Density at each stage4paxw@it3@9}=@ɓk&@!#@?:@n|b@-z@VGt@YNe@Nt@аu@Z!K@A%c@@#.@ݲC@-@@ .@9A@FaE@jin@}\*ƹ@ٖg)@n@ysV{@WL@0,-@R`L@-X @Xl:@@@m@y@Bus@ @g@撪&@˛õ@ȱ @tY?M*k??.s`9?A%c? Pg?E )??n׫?H7¢"?3?]?2Vapour Viscosity profile>Vapour Viscosity at each stage4#GS>Uɬ.S>PW>i>^ >W؂oKW>U>_p%>B6k>{3>@'f>548>p Ѵ>@3S/>1M2<>LE>69NJ>xO>c*Q>WES>ZQT>CZڌU>i V>EuV>V>84V>V>u W>fW>+[,W>S#W>M'W>IP*W>H(+W>.FK-W>.FK-W>FDت.W>FDت.W>Q %W>nعV>V%Q>V>Z> e]>rs>|N>j c>n%l>p>?gAu>r5%t>>:Vapour Heat capacity profileFVapour Heat capacity at each stage4}W@&䃞W@ڊeW@{sX@_^}tTX@W}WW@CQOW@E )?UV@6oU@='U@$bJ$ѽT@Gx $nT@ K<4T@o1 T@Mg'S@FS@HS@xWS@ ϛS@C5vS@O],ϷS@haO;S@ĴS@ˡES@֋hS@wg S@7OuͲS@~S@ aS@4ctvS@+jS@aS@?^?/WyR?or?o‘?k`Ñ?CHđ? nđ?4ő?[Ső?Ȳxő?b_pő?7ő?0qő?cVő?}GǴő?Ԛő? +ő?,jő?O\ő?`S)nő?rő?`S)nő?Afő?2*>xđ?P?r{e?*4?c?qބ?;lCAۓ? rc ?tH ?ѣ,?T7?dF댔?l[q?4Liquid Moleweight profile@Liquid Moleweight at each stage4U[rS@>xS@$0R@£#֖R@  R@p[Q@&kԱP@F=DP@70RO@L~N@Ӥt{N@JOcM@:fhM@f7M@&6׆M@NL@DL@?ޫVL@sK!qL@0L@dwL@L@:KL@^zk`L@)"L@CsFZL@q&L@ҩ+L@2}L@+ٱL@£L@BL@a7l[L@-lL@vyL@ZڊL@h?RDL@KqL@7A`L@~jL@'ILL@֨ht+K@,eXH@`9BG@m~:F@ 7E@;)dE@ mAE@1ZGU3E@NE*-TE@\mVG@=IO@.Liquid Density profile:Liquid Density at each stage4V-2u@gsu@@a}@tF(@G-@/L-@K7*@ cn%@FT@J{/@1@M O/ @@:@ŏ1w-@d;O@b4o@ q@T(@Zd;@Gz@Cl@Q@6@@bX94@<,@x&@ı.n#@k @=U@_vO@V-@QI@u@'1@Qkw@Qkw@"uq@;N@m4@,Ck@&䃞MȊ@1f@St$3@@L։@|?5ĉ@x $(@ZB>h@~@QC@_L ׊@2Liquid Viscosity profile>Liquid Viscosity at each stage44(2?kMw~)2?g%Q2?V*6?-u6?ZI?6?8p6?I87?0FNed7?r7?,+7? A"7?{dr7?ԝ-|7?7?Q8 E7?7?2]37?=7?2~7?/7?(7?q 87?MR7?Jd7?s%o7?w7?V|7?47?ЋZ7?n7?=h7? Oʅ7?sC87?څ67?A*7?7?7?{Ua7?v7?1.r7?0Xo7?L7?"7?oz17?7?C|7?K17?(b7?z7? $P7?16?:Liquid Heat capacity profileFLiquid Heat capacity at each stage4FGrCd@R'Cd@Y8Gd@W2d@V/d@H.d@8gDioc@/$Dc@¨N@b@Db@d;Ob@5^I zb@o_eb@p_Wb@ݓZMb@?߾Fb@@5^IBb@EJ?b@QI=b@[ A;b@0' ;b@ꕲ q:b@/L :b@9b@Aǘ9b@i"lxz9b@ڊe9b@MbX9b@M O9b@QI9b@48E9b@B9b@¨N@9b@i|?9b@z6>9b@b=9b@46<9b@J49b@"8b@>yX57b@-!l(b@ Outlet flash: Auto Flash used for TopProduct: PVF Flash used for BottomProduct: PVF CAPE-OPEN supplied d H / d T have been used CAPE-OPEN supplied d H / d x have been used CAPE-OPEN supplied d K / d T have been used CAPE-OPEN supplied d K / d x and d K / d y have been used Relative perturbation of pressure: 0.001 Relative perturbation of temperature: 0.001 Perturbation of composition: 0.001 )- not all ports are connectedFeed2{split}_stage42Feed1{split}_stage4 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@@1@message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 315.04 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 315.05 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 315.39 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 323.86 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 325.53 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 327.75 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 329.67 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 331.27 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 332.61 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 333.68 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 334.51 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 335.13 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 335.58 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 335.89 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.11 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.26 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.36 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.43 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.47 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.50 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.52 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.54 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.55 K, range = [425.15 - 1000.00] K)  (last message repeated 1 time) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.56 K, range = [425.15 - 1000.00] K) "(last message repeated 14 times) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.52 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.12 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 332.13 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 336.14 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 339.67 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 342.11 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 343.53 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 344.26 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 344.63 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 344.83 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 345.20 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 349.06 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 376.30 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 315.04 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 315.05 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 315.39 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 323.86 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 325.53 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 327.75 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 329.67 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 331.27 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 332.61 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 333.68 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 334.51 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 335.13 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 335.58 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 335.89 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.11 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.26 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.36 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.43 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.47 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.50 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.52 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.54 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.55 K, range = [168.35 - 315.00] K)  (last message repeated 1 time) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.56 K, range = [168.35 - 315.00] K) "(last message repeated 14 times) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.52 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.12 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 332.13 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 336.14 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 339.67 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 339.67 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 342.11 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 342.11 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 343.53 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 343.53 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 344.26 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 344.26 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 344.63 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 344.63 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 344.83 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 344.83 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 345.20 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 345.20 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 349.06 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 349.06 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 376.30 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 376.30 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 315.04 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 315.04 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 376.30 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 376.30 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 376.30 K, range = [168.35 - 315.00] K) C2ChemSep Unit OperationqeWCXcECSUO}[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_4_6~1.sep Title=ChemSep CO Unit Operation "C2" in COFE Flowsheet User=Harry Date=2012-02-06 Time=02:16:22 [Cape-Open] unitname=C2 CO_ID=CS_4_68C_1CCE46C_EE515410 4 components Dimethoxymethane 109-87-5 76.0943984985 Mw Methanol 67-56-1 32.0419998169 Mw Water 7732-18-5 18.0149993896 Mw N,n-dimethylformamide 68-12-2 73.0938034058 Mw 0 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=FALSE WilsonEstimate=TRUE Status= 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=C Flow=mol/s Mass flow=kg/s Pressure=bar Heat=MW Enthalpy=kJ/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=deg Velocity=m/s Surface tension=dyn/cm Density=kg/m3 Molar density=kmol/m3 Viscosity=Pa.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=1e-8 m2/s Interaction parameter=J/mol Time=s [Components] 4 1 1431 Library Offset, Index DT=2012-02-05,19:42:00 CHK=42323 CAS=109-87-5 CID=Dimethoxymethane Name=Dimethoxymethane Lib=c:\program files\chemsepl6v90\pcd\methylal.pcd 32 1101 Library Offset, Index DT=2012-01-31,09:17:24 CHK=37880 CAS=67-56-1 CID=Methanol Name=Methanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 14 1921 Library Offset, Index DT=2012-01-31,09:17:24 CHK=26350 CAS=7732-18-5 CID=Water Name=Water Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 66 1876 Library Offset, Index DT=2012-01-31,09:17:24 CHK=35635 CAS=68-12-2 CID=N,n-dimethylformamide Name=N,n-dimethylformamide Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd [Operation] 2 Operation Column 1 Operation kind Simple Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 22 Stages 1 Feed stages 0 Sidestream stages F=9 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 4 K model DECHEMA 6 1 Activity coefficient NRTL * Wilson model * * UNIQUAC model * * Equation of State * * Cubic EOS * * Virial EOS * 3 Vapour pressure T correlation 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 1 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [NRTL Data] i j Aij Aji aij Component Component 1 2 2547.69 500 0.7259 Dimethoxymethane/Methanol 1 3 6728.16 7607.74 0.4898 Dimethoxymethane/Water 1 4 5299.43 -3188.63 0.2 Dimethoxymethane/N,n-dimethylformamid 2 3 -790.972 3317.08 0.2999 Methanol/Water 2 4 -519.194 1.43427 9.1633 Methanol/N,n-dimethylformamid 3 4 5534.99 -3666.87 0.2 Water/N,n-dimethylformamid [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 21 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 1 Column pressure Constant pressure 101325 Condenser pressure 101325 Top pressure * Pressure Drop * Bottom pressure [Feeds] 1 Number 1 Feed state T & p 9 Stage Feed1{split} 376.302947786 Temperature 101325 Pressure 0 Vapour fraction 4 componentflows 2.3613123392e-006 Component 1 flow 0.00359639187325 Component 2 flow 0.000138871605012 Component 3 flow 0.0110205773222 Component 4 flow [Condenser] 7 Type Mole fraction of a component 0.00001 Value Qcondenser 4 1st comp. * Type * * Initialization guess [Reboiler] 7 Type Mole fraction of a component 0.00001 Value Qreboiler 3 1st comp. * Type * * Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 y1 x2 y2 StringGrid=StringGrid3 1 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 1 ComboBox=ComboBox23 3 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Methanol - N,n-dimethylformamide Xlabel X Methanol/(Methanol+N,n-dimethylformamide) Ylabel Y Methanol/(Methanol+N,n-dimethylformamide) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 1 ComboBox=ComboBox76 3 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 0 Edit=Edit1 1.01325 Edit=Edit2 21 Edit=Edit3 Dimethoxymethane + Methanol @ p=1.01325 (bar) ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 9 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 5 7 Identifier L# File Loc. CAS SMILES Name Dimethoxymethane 1431 c:\program files\chemsepl6v90\pcd\methylal.pcd 1 109-87-5 COCOC Dimethoxymethane Methanol 1101 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 67-56-1 CO Methanol Water 1921 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 14 7732-18-5 O Water N,n-dimethylformamide 1876 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 66 68-12-2 CN(C)C=O N,n-dimethylformamide 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 0 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 338.3260603 1.013250000E+05 3.737549969E-03 2.133014351E-03 -2.093261902E+05 2 339.2782266 1.013250000E+05 5.870564320E-03 2.110749869E-03 0.000000000E+00 3 340.1859152 1.013250000E+05 5.848299838E-03 2.086276151E-03 0.000000000E+00 4 341.4723827 1.013250000E+05 5.823826120E-03 2.028038619E-03 0.000000000E+00 5 346.2536100 1.013250000E+05 5.765588587E-03 1.842473966E-03 0.000000000E+00 6 361.3940989 1.013250000E+05 5.580023934E-03 1.667763361E-03 0.000000000E+00 7 376.1062580 1.013250000E+05 5.405313329E-03 1.640954028E-03 0.000000000E+00 8 382.7064302 1.013250000E+05 5.378503997E-03 1.646187905E-03 0.000000000E+00 9 385.0569326 1.013250000E+05 5.383737662E-03 1.655638797E-02 0.000000000E+00 10 397.1407466 1.013250000E+05 5.535735819E-03 1.695873540E-02 0.000000000E+00 11 408.1045593 1.013250000E+05 5.938083242E-03 1.744327988E-02 0.000000000E+00 12 415.8851023 1.013250000E+05 6.422627727E-03 1.785766262E-02 0.000000000E+00 13 420.7983417 1.013250000E+05 6.837010463E-03 1.816059082E-02 0.000000000E+00 14 423.4332748 1.013250000E+05 7.139938669E-03 1.833930263E-02 0.000000000E+00 15 424.6557667 1.013250000E+05 7.318650478E-03 1.842668096E-02 0.000000000E+00 16 425.1820619 1.013250000E+05 7.406028805E-03 1.846534881E-02 0.000000000E+00 17 425.4036220 1.013250000E+05 7.444696656E-03 1.848187610E-02 0.000000000E+00 18 425.4971075 1.013250000E+05 7.461223946E-03 1.848891319E-02 0.000000000E+00 19 425.5369667 1.013250000E+05 7.468261035E-03 1.849193107E-02 0.000000000E+00 20 425.5541553 1.013250000E+05 7.471278912E-03 1.849323754E-02 0.000000000E+00 21 425.5616399 1.013250000E+05 7.472585381E-03 1.849380794E-02 0.000000000E+00 22 425.5649237 1.013250000E+05 7.473155781E-03 1.102065216E-02 2.973464890E+05 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.3378347E+08 -0.3378347E+08 -0.9803149E+05 -0.9803149E+05 2 0.1873445E+07 -0.3407182E+08 0.7246552E+04 -0.9714560E+05 3 0.1905121E+07 -0.3434876E+08 0.7855892E+04 -0.9647675E+05 4 0.1957098E+07 -0.3472839E+08 0.8469141E+04 -0.9523349E+05 5 0.2190286E+07 -0.3577974E+08 0.9799530E+04 -0.9105398E+05 6 0.3070877E+07 -0.3596775E+08 0.1380131E+05 -0.8308016E+05 7 0.4268596E+07 -0.3423802E+08 0.1836325E+05 -0.7591477E+05 8 0.4996887E+07 -0.3314420E+08 0.2053897E+05 -0.7272518E+05 9 0.5293204E+07 -0.3272510E+08 0.2130178E+05 -0.7163098E+05 10 0.6837124E+07 -0.3109199E+08 0.2735604E+05 -0.6661675E+05 11 0.8820556E+07 -0.2926047E+08 0.3287792E+05 -0.6196879E+05 12 0.1078367E+08 -0.2773223E+08 0.3644737E+05 -0.5858054E+05 13 0.1234827E+08 -0.2668531E+08 0.3832775E+05 -0.5646896E+05 14 0.1331062E+08 -0.2610351E+08 0.3900680E+05 -0.5538231E+05 15 0.1379187E+08 -0.2582756E+08 0.3911669E+05 -0.5490583E+05 16 0.1400774E+08 -0.2570661E+08 0.3906500E+05 -0.5471461E+05 17 0.1410083E+08 -0.2565492E+08 0.3900020E+05 -0.5464066E+05 18 0.1414071E+08 -0.2563283E+08 0.3895452E+05 -0.5461247E+05 19 0.1415789E+08 -0.2562332E+08 0.3892712E+05 -0.5460183E+05 20 0.1416535E+08 -0.2561919E+08 0.3891179E+05 -0.5459787E+05 21 0.1416862E+08 -0.2561738E+08 0.3890350E+05 -0.5459643E+05 22 0.1417005E+08 -0.2561659E+08 0.3889907E+05 -0.5459595E+05 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.3195584E+02 0.1151057E+01 0.1104400E-04 0.4722790E+05 0.1920418E-01 2 0.3154947E+02 0.1133230E+01 0.1109438E-04 0.4687916E+05 0.1935154E-01 3 0.3125192E+02 0.1119547E+01 0.1114114E-04 0.4665307E+05 0.1948477E-01 4 0.3101802E+02 0.1106982E+01 0.1119578E-04 0.4652495E+05 0.1964521E-01 5 0.3107937E+02 0.1093855E+01 0.1133686E-04 0.4702221E+05 0.2009963E-01 6 0.3282717E+02 0.1106966E+01 0.1161551E-04 0.5066989E+05 0.2131412E-01 7 0.3689348E+02 0.1195421E+01 0.1158440E-04 0.5789853E+05 0.2212569E-01 8 0.3983910E+02 0.1268603E+01 0.1143980E-04 0.6294272E+05 0.2230792E-01 9 0.4107467E+02 0.1299963E+01 0.1136812E-04 0.6505199E+05 0.2234163E-01 10 0.4595691E+02 0.1410225E+01 0.1106814E-04 0.7459199E+05 0.2258167E-01 11 0.5283543E+02 0.1577741E+01 0.1054176E-04 0.8762008E+05 0.2224893E-01 12 0.6012029E+02 0.1761690E+01 0.9999062E-05 0.1009854E+06 0.2154991E-01 13 0.6607459E+02 0.1913561E+01 0.9593452E-05 0.1117382E+06 0.2087827E-01 14 0.6976082E+02 0.2007745E+01 0.9359690E-05 0.1183527E+06 0.2044119E-01 15 0.7161462E+02 0.2055164E+01 0.9247219E-05 0.1216638E+06 0.2021871E-01 16 0.7245254E+02 0.2076637E+01 0.9197665E-05 0.1231536E+06 0.2011843E-01 17 0.7281684E+02 0.2085992E+01 0.9176446E-05 0.1237985E+06 0.2007516E-01 18 0.7297405E+02 0.2090036E+01 0.9167378E-05 0.1240758E+06 0.2005663E-01 19 0.7304217E+02 0.2091791E+01 0.9163473E-05 0.1241957E+06 0.2004866E-01 20 0.7307189E+02 0.2092558E+01 0.9161777E-05 0.1242478E+06 0.2004520E-01 21 0.7308494E+02 0.2092895E+01 0.9161035E-05 0.1242707E+06 0.2004368E-01 22 0.7309069E+02 0.2093043E+01 0.9160708E-05 0.1242808E+06 0.2004302E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.3154947E+02 0.7561039E+03 0.3444131E-03 0.1125959E+06 0.2085236E+00 0.2055033E-01 2 0.3072505E+02 0.7584927E+03 0.3455086E-03 0.1109458E+06 0.2354316E+00 0.2316174E-01 3 0.3006592E+02 0.7622413E+03 0.3465186E-03 0.1095040E+06 0.2602193E+00 0.2557174E-01 4 0.3021301E+02 0.7729251E+03 0.3485597E-03 0.1090958E+06 0.2829140E+00 0.2795674E-01 5 0.3541904E+02 0.8170911E+03 0.3560875E-03 0.1155028E+06 0.2993438E+00 0.3088234E-01 6 0.4886971E+02 0.8563504E+03 0.3523881E-03 0.1371047E+06 0.2657547E+00 0.3004095E-01 7 0.5872014E+02 0.8574186E+03 0.3418662E-03 0.1561220E+06 0.2140892E+00 0.2658213E-01 8 0.6270094E+02 0.8549248E+03 0.3379507E-03 0.1642883E+06 0.1895727E+00 0.2488161E-01 9 0.6402003E+02 0.8537855E+03 0.3365999E-03 0.1670655E+06 0.1812907E+00 0.2430403E-01 10 0.6599999E+02 0.8454994E+03 0.3202573E-03 0.1734876E+06 0.1868099E+00 0.2428253E-01 11 0.6831659E+02 0.8373076E+03 0.3088479E-03 0.1798493E+06 0.1828018E+00 0.2357327E-01 12 0.7040607E+02 0.8310469E+03 0.3029865E-03 0.1849623E+06 0.1730321E+00 0.2261404E-01 13 0.7178308E+02 0.8268093E+03 0.2997636E-03 0.1884370E+06 0.1644318E+00 0.2183510E-01 14 0.7250317E+02 0.8244319E+03 0.2980587E-03 0.1903876E+06 0.1592209E+00 0.2136866E-01 15 0.7283573E+02 0.8232999E+03 0.2972712E-03 0.1913352E+06 0.1565734E+00 0.2113463E-01 16 0.7298181E+02 0.8228047E+03 0.2969373E-03 0.1917630E+06 0.1553293E+00 0.2102656E-01 17 0.7304513E+02 0.8225939E+03 0.2967996E-03 0.1919511E+06 0.1547631E+00 0.2097820E-01 18 0.7307262E+02 0.8225042E+03 0.2967426E-03 0.1920333E+06 0.1545085E+00 0.2095676E-01 19 0.7308462E+02 0.8224658E+03 0.2967188E-03 0.1920694E+06 0.1543946E+00 0.2094726E-01 20 0.7308989E+02 0.8224491E+03 0.2967086E-03 0.1920853E+06 0.1543437E+00 0.2094305E-01 21 0.7309221E+02 0.8224418E+03 0.2967042E-03 0.1920923E+06 0.1543210E+00 0.2094118E-01 22 0.7309325E+02 0.8224386E+03 0.2967023E-03 0.1920954E+06 0.1543108E+00 0.2094035E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.264256050E-02 0.631780808E-03 0.454252456E-03 0.439021716E-03 0.440121650E-03 2 0.982914567E+00 0.962231920E+00 0.941422381E+00 0.921734761E+00 0.897925507E+00 3 0.144424376E-01 0.371262992E-01 0.580287905E-01 0.769484603E-01 0.935802615E-01 4 0.434533354E-06 0.100000000E-04 0.945760806E-04 0.877757242E-03 0.805410994E-02 Component Mole fractions on stages: 6 to 10 1 0.455191758E-03 0.468857207E-03 0.465646100E-03 0.462046173E-03 0.216902174E-03 2 0.841984468E+00 0.771677134E+00 0.738259642E+00 0.725879160E+00 0.528114339E+00 3 0.103542914E+00 0.821185137E-01 0.535452140E-01 0.403398787E-01 0.990853293E-01 4 0.540174262E-01 0.145735495E+00 0.207729498E+00 0.233318915E+00 0.372583430E+00 Component Mole fractions on stages: 11 to 15 1 0.684209479E-04 0.151546126E-04 0.263469888E-05 0.396207453E-06 0.553574035E-07 2 0.301338607E+00 0.142790416E+00 0.581960756E-01 0.208994947E-01 0.691522338E-02 3 0.143214530E+00 0.129119706E+00 0.840643306E-01 0.449359956E-01 0.217017252E-01 4 0.555378442E+00 0.728074724E+00 0.857736959E+00 0.934164113E+00 0.971382996E+00 Component Mole fractions on stages: 16 to 20 1 0.748679357E-08 0.998987049E-09 0.132564424E-09 0.175488506E-10 0.231837401E-11 2 0.219263946E-02 0.681408487E-03 0.209710848E-03 0.641035537E-04 0.193753029E-04 3 0.100083747E-01 0.452068345E-02 0.201786972E-02 0.889592927E-03 0.383392644E-03 4 0.987798978E+00 0.994797907E+00 0.997772419E+00 0.999046304E+00 0.999597232E+00 Component Mole fractions on stages: 21 to 22 1 0.303612761E-12 0.372068709E-13 2 0.566504222E-05 0.146653227E-05 3 0.156741444E-03 0.553449083E-04 4 0.999837594E+00 0.999943189E+00 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.631780808E-03 0.139899202E-03 0.936950747E-04 0.869056529E-04 0.969720964E-04 2 0.962231920E+00 0.904574485E+00 0.849184367E+00 0.779412758E+00 0.598056538E+00 3 0.371262992E-01 0.950412790E-01 0.148289599E+00 0.197621429E+00 0.238272317E+00 4 0.100000000E-04 0.244336757E-03 0.243233862E-02 0.228789079E-01 0.163574173E+00 Component Mole fractions on stages: 6 to 10 1 0.103736402E-03 0.872462392E-04 0.766760643E-04 0.725226501E-04 0.239575225E-04 2 0.344633316E+00 0.228124948E+00 0.189257414E+00 0.176578579E+00 0.105513512E+00 3 0.182948556E+00 0.909420655E-01 0.476360731E-01 0.331364796E-01 0.501529147E-01 4 0.472314392E+00 0.680845740E+00 0.763029837E+00 0.790212419E+00 0.844309616E+00 Component Mole fractions on stages: 11 to 15 1 0.557993885E-05 0.100872462E-05 0.155771195E-06 0.220914349E-07 0.300908399E-08 2 0.525756445E-01 0.222811453E-01 0.821686425E-02 0.275976152E-02 0.881371411E-03 3 0.475482830E-01 0.321911622E-01 0.176729085E-01 0.866649902E-02 0.402853437E-02 4 0.899870493E+00 0.945526684E+00 0.974110072E+00 0.988573717E+00 0.995090091E+00 Component Mole fractions on stages: 16 to 20 1 0.402763984E-09 0.535180925E-10 0.708972450E-11 0.937875150E-12 0.123865603E-12 2 0.274832515E-03 0.847694450E-04 0.260015742E-04 0.793627600E-05 0.239716212E-05 3 0.182857762E-02 0.820586845E-03 0.365295604E-03 0.160861507E-03 0.692939968E-04 4 0.997896589E+00 0.999094644E+00 0.999608703E+00 0.999831202E+00 0.999928309E+00 Component Mole fractions on stages: 21 to 22 1 0.162192928E-13 0.198751793E-14 2 0.700688630E-06 0.181366478E-06 3 0.283234067E-04 0.100000000E-04 4 0.999970976E+00 0.999989819E+00 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 21 to 22 1 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -2.093261902E+05 [Reboiler Heat Duty] 2.973464890E+05 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.418271727E+01 0.451597149E+01 0.484819995E+01 0.505170494E+01 0.453864220E+01 2 0.102149445E+01 0.106373984E+01 0.110861954E+01 0.118260158E+01 0.150140572E+01 3 0.389008274E+00 0.390633414E+00 0.391320705E+00 0.389373059E+00 0.392745001E+00 4 0.434533353E-01 0.409271210E-01 0.388827773E-01 0.383653470E-01 0.492382738E-01 Component K-values on stages: 6 to 10 1 0.438796554E+01 0.537395320E+01 0.607290037E+01 0.637106024E+01 0.905361455E+01 2 0.244313138E+01 0.338269505E+01 0.390082283E+01 0.411079965E+01 0.500518208E+01 3 0.565967377E+00 0.902976121E+00 0.112404761E+01 0.121738576E+01 0.197566443E+01 4 0.114367521E+00 0.214050681E+00 0.272242955E+00 0.295261007E+00 0.441287679E+00 Component K-values on stages: 11 to 15 1 0.122619530E+02 0.150235380E+02 0.169139030E+02 0.179348899E+02 0.183967625E+02 2 0.573152474E+01 0.640857610E+01 0.708251638E+01 0.757293506E+01 0.784598104E+01 3 0.301198111E+01 0.401102964E+01 0.475667776E+01 0.518502287E+01 0.538700263E+01 4 0.617175967E+00 0.770020281E+00 0.880533920E+00 0.944961511E+00 0.976175932E+00 Component K-values on stages: 16 to 20 1 0.185885379E+02 0.186663426E+02 0.186981065E+02 0.187112865E+02 0.187168508E+02 2 0.797809336E+01 0.803837381E+01 0.806531353E+01 0.807728382E+01 0.808260014E+01 3 0.547331139E+01 0.550908593E+01 0.552393651E+01 0.553017900E+01 0.553284068E+01 4 0.989881106E+00 0.995699369E+00 0.998162999E+00 0.999214970E+00 0.999668900E+00 Component K-values on stages: 21 to 22 1 0.187192354E+02 0.187202696E+02 2 0.808496381E+01 0.808601610E+01 3 0.553398980E+01 0.553449082E+01 4 0.999866613E+00 0.999953368E+00 [Molecular weights] 1 76.094 2 32.042 3 18.015 4 73.094 [Feed stream 1] 9 Stage Number 1.4758202112801E-02 Flow rate 3.7630294778600E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -3.3649030546563E+07 Enthalpy [J/kmol] -5.8200695971256E+04 Entropy [J/kmol/K] 1.9094512644828E-08 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.6000000007805E-04 Mole fraction of component 1 2.4368766911862E-01 Mole fraction of component 2 9.4097915146143E-03 Mole fraction of component 3 7.4674253936669E-01 Mole fraction of component 4 2.8180067685781E-10 Flow rate 7.8261222992459E-04 Mole fraction of component 1 8.2953547038103E-01 Mole fraction of component 2 7.9760409052651E-03 Mole fraction of component 3 1.6170587648378E-01 Mole fraction of component 4 1.4758201831001E-02 Flow rate 1.5999998818957E-04 Mole fraction of component 1 2.4368765793214E-01 Mole fraction of component 2 9.4097915419911E-03 Mole fraction of component 3 7.4674255053768E-01 Mole fraction of component 4 3.8602913714252E+01 Molar mass 1.2501565341782E+00 Density 1.1443627923368E-05 Viscosity 2.1916801343626E-02 Thermal conductivity 6.0113402114409E+04 Heat capacity 6.2572185566306E+01 Molar mass 8.5888091726330E+02 Density 3.4951583755931E-04 Viscosity 1.7197218488075E-01 Thermal conductivity 1.6245225788848E+05 Heat capacity 2.3750651471928E-02 Surface tension [Reflashed Feed stream 1] 9 Stage Number 1.4758202112801E-02 Flow rate 3.7630294881073E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -3.3649030546563E+07 Enthalpy [J/kmol] -5.8200695132424E+04 Entropy [J/kmol/K] 1.4297017125742E-08 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.6000000007805E-04 Mole fraction of component 1 2.4368766911862E-01 Mole fraction of component 2 9.4097915146143E-03 Mole fraction of component 3 7.4674253936669E-01 Mole fraction of component 4 2.1099826835188E-10 Flow rate 7.8261227576593E-04 Mole fraction of component 1 8.2953546242006E-01 Mole fraction of component 2 7.9760412670963E-03 Mole fraction of component 3 1.6170588403708E-01 Mole fraction of component 4 1.4758201901803E-02 Flow rate 1.5999999117655E-04 Mole fraction of component 1 2.4368766074274E-01 Mole fraction of component 2 9.4097915351127E-03 Mole fraction of component 3 7.4674254773097E-01 Mole fraction of component 4 3.8602914021273E+01 Molar mass 1.2501565407166E+00 Density 1.1443627916159E-05 Viscosity 2.1916801395349E-02 Thermal conductivity 6.0113402689386E+04 Heat capacity 6.2572185451314E+01 Molar mass 8.5888091596617E+02 Density 3.4951583450643E-04 Viscosity 1.7197218469594E-01 Thermal conductivity 1.6245225818830E+05 Heat capacity 2.3750651333831E-02 Surface tension [Top product] 1 Stage Number 3.7375499690000E-03 Flow rate 3.3832606030000E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -3.3783466028353E+07 Enthalpy [J/kmol] -9.8031485331982E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 6.3178080800000E-04 Mole fraction of component 1 9.6223192000000E-01 Mole fraction of component 2 3.7126299200000E-02 Mole fraction of component 3 1.0000000000000E-05 Mole fraction of component 4 3.7375499690000E-03 Flow rate 6.3178080800000E-04 Mole fraction of component 1 9.6223192000000E-01 Mole fraction of component 2 3.7126299200000E-02 Mole fraction of component 3 1.0000000000000E-05 Mole fraction of component 4 3.1549471180480E+01 Molar mass 7.5610388762768E+02 Density 3.4441314423540E-04 Viscosity 2.0852356802401E-01 Thermal conductivity 1.1259591760120E+05 Heat capacity 2.0550328540859E-02 Surface tension [Bottom product] 22 Stage Number 1.1020652160000E-02 Flow rate 4.2556492370000E+02 Temperature [K] 1.0132500000000E+05 Pressure [Pa] -2.5616587756297E+07 Enthalpy [J/kmol] -5.4595950912738E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.9875179300000E-15 Mole fraction of component 1 1.8136647800000E-07 Mole fraction of component 2 1.0000000000000E-05 Mole fraction of component 3 9.9998981900000E-01 Mole fraction of component 4 1.1020652160000E-02 Flow rate 1.9875179300000E-15 Mole fraction of component 1 1.8136647800000E-07 Mole fraction of component 2 1.0000000000000E-05 Mole fraction of component 3 9.9998981900000E-01 Mole fraction of component 4 7.3093245199088E+01 Molar mass 8.2243864475187E+02 Density 2.9670233966670E-04 Viscosity 1.5431080909476E-01 Thermal conductivity 1.9209543730577E+05 Heat capacity 2.0940347646474E-02 Surface tension [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stagebP7%u@ >s4u@E}7Bu@${)Wu@[u@<:Nv@;w@Mw@8q(2x@_@x@__Fy@Ձa)y@HLz@傎vz@$9~z@%z@#WR@ԷBR@4ؙDR@Ӈ.oER@nER@.Vapour Density profile:Vapour Density at each stageYOj?ǵ!?[u?+2?n?!?9?q ?Eɨ2L?()?H?Xm>?9 {/?j#?M@Up@N@ݒ@[d@x@w @׻?@MT@2Vapour Viscosity profile>Vapour Viscosity at each stage \Y3)>9?D>@Z]>~>XIz>\,n>o׉\>SK>b#>a6>t^)6>Ov>L4>!r>R> :d>x[sI>^">>jֲ9>pp#7>π 6>(K6>6>:Vapour Heat capacity profileFVapour Heat capacity at each stagea+G@PpG@9̗SG@ŏ1CG@tׂG@oUI@<L@ xO@nSCP@c*R@9dU@^)?Y@z6>[@&S]@n{j^@*^@v^@[B>_@JY _@_@&S_@-_@HVapour Thermal conductivity profileTVapour Thermal conductivity at each stage/B?P}Г?)?g?6 V?@_a^ӕ?D?]+ז?`h?f8?LjlȖ?-?'cca?aP* ?ި6?c왔?ڥ.??qO̢?aę?^]T?M(?4Liquid Moleweight profile@Liquid Moleweight at each stage"?@u>@&">@҇6>@KA@CRoH@NE*-\M@:fYO@+HP@P@gCQ@x Q@Q@3 R@O|5R@8>R@bhBR@FB[ΥDR@%jjER@2ER@NER@ER@.Liquid Density profile:Liquid Density at each stageoԠ@ꕲ @3ı.ч@=,Ԛf'@S@&䃞Š@JYˊ@ڊe@X9H@\mk@!u*@vq `@9EGry։@$tÉ@1f@p@N@%u@гY@@:pΈ@4@@2Liquid Viscosity profile>Liquid Viscosity at each stageGX5K6?T2#6?# 6?6?t*(V7?p]7?) &g6?C4%6?$O56?:4?C=4?$E3?ѳ23?h^3?b{3?ku3?eQxs3?<(Ãr3?"NJr3?»q3?.q3?֬q3?:Liquid Heat capacity profileFLiquid Heat capacity at each stage9#&\@#[@K7A`[@=R!F[@r -\@|гY#a@Clc@9d@ktd@Pke@ŏ1w-{f@^)g@Dlg@}8gg@ѳYg@#~jg@8gDiog@^)h@JY8h@)Ǻh@w-!h@;M h@:Liquid Thermal cond. profileFLiquid Thermal cond. at each stage8?=8g"?nn?'eRC?ѩr(?؇P ?}6`Fg?r[C?Cȝ4?Ոc?0S f??Tu%? ?z+Ya?66 ?@'Λ?vTF?2:=?3?=ˈ? `?Yt?0Surface tension profile<Surface tension at each stage.M% ?F?lz/?v?>K?)Þ?6X8?&㔐z?WD '?9Gݘ?^#?_"(?a[?o?TQ?؄0?=+O{?; R[u?902s?k`PKr?f̚q?˪cq? 1 Converged 0 Iterations ChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_4_6~1.SEP Cape Open unit name: C2 Cape-Open unit id: CS_4_68C_1CCE46C_EE515410 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties enabled Reading configuration Reading component property libraries Reading thermodynamic property options Reading specifications Reading reaction data Checking Component Data 109-87-5 Dimethoxymethane * No class * Missing L-density 67-56-1 Methanol 7732-18-5 Water * No class 68-12-2 N,n-dimethylformamide Determining feed conditions Run level: Initialization Reading initial temperature profiles Reading initial composition profiles Init 47 milliseconds Run level: Complete model Iteration log(Err/Tol) 0 -2.3585 Run level: Report Convergence obtained in 0 iterations Time 187 milliseconds FixMem driver done run time: 0.33 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe Using CAPE-OPEN version 1.1 thermodynamics CAPE-OPEN thermo-properties were enabled CAPE-OPEN diffusion coefficients were disabled CAPE-OPEN supplied derivatives were enabled CAPE-OPEN supplied molar derivatives were enabled Inlet re-flash: <none> Outlet flash: Auto Flash used for TopProduct: PVF Flash used for BottomProduct: PVF CAPE-OPEN supplied d H / d T have been used CAPE-OPEN supplied d H / d x have been used CAPE-OPEN supplied d K / d T have been used CAPE-OPEN supplied d K / d x and d K / d y have been used Relative perturbation of pressure: 0.001 Relative perturbation of temperature: 0.001 Perturbation of composition: 0.001@ N, not all ports are connectedFeed1{split}_stage9 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@@3@message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 338.33 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 339.28 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 340.19 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 341.47 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 346.25 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 361.39 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 376.11 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 382.71 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 385.06 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 397.14 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 408.10 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 415.89 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 420.80 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 423.43 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 424.66 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 338.33 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 338.33 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 339.28 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 339.28 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 340.19 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 340.19 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 341.47 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 341.47 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 346.25 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 346.25 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 361.39 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 361.39 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 376.11 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 376.11 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 382.71 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 382.71 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 382.71 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 385.06 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 385.06 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 385.06 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 397.14 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 397.14 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 397.14 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 408.10 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 408.10 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 408.10 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 415.89 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 415.89 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 415.89 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 420.80 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 420.80 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 420.80 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 423.43 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 423.43 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 423.43 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 424.66 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 424.66 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 424.66 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.18 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.18 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.18 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.18 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.18 K, range = [250.00 - 425.15] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.40 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.40 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.40 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.40 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.40 K, range = [250.00 - 425.15] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.50 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.50 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.50 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.50 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.50 K, range = [250.00 - 425.15] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.54 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.54 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.54 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.54 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.54 K, range = [250.00 - 425.15] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.55 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.55 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.55 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.55 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.55 K, range = [250.00 - 425.15] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.56 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.56 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.56 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.56 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.56 K, range = [250.00 - 425.15] K) #(last 5 messages repeated 1 time) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 376.30 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 376.30 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 376.30 K, range = [168.35 - 315.00] K) #(last 3 messages repeated 1 time) message: Warning: temperature out of range for vapor thermal conductivity correlation for compound N,n-dimethylformamide (T = 338.33 K, range = [425.15 - 1000.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 338.33 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 338.33 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methylal (T = 425.56 K, range = [168.35 - 378.50] K) message: Warning: temperature out of range for liquid viscosity correlation for compound Methanol (T = 425.56 K, range = [175.47 - 337.85] K) message: Warning: temperature out of range for liquid viscosity correlation for compound N,n-dimethylformamide (T = 425.56 K, range = [240.00 - 425.15] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound Methylal (T = 425.56 K, range = [168.35 - 315.00] K) message: Warning: temperature out of range for liquid thermal conductivity correlation for compound N,n-dimethylformamide (T = 425.56 K, range = [250.00 - 425.15] K) M17MakeUpMixer - mixer for determining a make-up flow rate/!TLCcCOUSCOUS0002Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Outlet flowTarget flow at recycle outlet?=S &@ _BNet flowResulting net make up flow? _B Flow basisBasis for target and net flowmol/smol/smol/skg/sTarget compound&Compound for outlet flow specification Total flow Total flow Total flowDimethoxymethaneMethanolWaterN,n-dimethylformamideLast run+++ specifications +++ Flow basis: mol/s Outlet flow: 11.020846 mol/s +++ run results ++ Net flow: 1.9384449274007E-04 mol/s  $not all material ports are connectedMake up excess flow Recycle inletMake up surplus flowRecycle outlet 0?@@?@@@@ @HeaterCooler_4MHeaterCooler - heat or cool stream specifying heat duty or outlet temperaturez,wKJEKBCOUSCOUS0002TypeType of heat duty specification Temperature Heat duty Heat duty Temperature Energy inletOutlet temperature!Temperature of the product stream?r@r@ _B Heat duty Heat duty@?@$7d @x@xD Pressure dropPressure drop along the unit?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Heat duty: -232579.027127355 W Pressure drop: 0 Pa +++ optional parameters +++ Outlet temperature: 300 K "& $not all material ports are connectedInletOutlet VvR{'1 +{{Ж3 {3VvR{'1 +{{Ж3 {3VvR{'1 +{{Ж3 {3VvR{'1 +{{Ж3 {3@@ ɿ@????@@@@@ɿ@@@MS Sans/C6?/C6?h㈵>/C6?@A@UUUUUA@;@UUUUUA@;@A@UUUUUA@UUUUUA@ @ @@A@*4@;@*4@;@A@*4@*4@ @ @@R@*9@P@*9@P@R@*9@*9@ @ @{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 42\b0 \par } ;@;@y=@j@@XUUUU?@QA@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 1 atm\b0 \par } K@;@y7@:8s=@%@LDDDDD+@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs24 300 K\b0 \par } I@9@y;@<@@@UUUUUDDDDD?{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 roman;}{\f1\fnil\fcharset0 Roman;}{\f2\fnil MS Sans Serif;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 0.999 Methylal \par \b0 RR=2.5 \par \f1 2575 kg/h\b\f2\fs21 \par } ``@@Q@@@@XUUUU1@&""""4@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 21\b0 \par } ;@;@yyP@VUUUUQ@@@QB@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 9\b0 \par } 1@;@yyP@VUUUUQ@XUUUU6@&""""9@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 2\b0 \par } 1@;@yyP@VUUUUQ@-@&""""1@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\b\f0\fs27 2\b0 \par } 1@;@y>@@@-@&""""1@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\f0\fs27 3000 kg/h \par 0.858 Methylal \par 0.139 Methanol \par 0.003 Water \par } ``@V@yg@ 4@A@ywwwwwF@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\f0\fs27 2900 kg/h DMF \par \par } @`@H@@<ϳ/@ =@UUUUU?@{\rtf1\ansi\ansicpg1252\deff0\deflang1033\deflangfe1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\sl240\slmult1\f0\fs27 0.07 kg/h DMF \par \par } @_@H@yg@ 4@XUUUU7@;@ׁ?ׁ?ׁ?ׁ??\BBv