FSD100MbP?h㈵>dg g0dr@м@Harry Kooijman and Ross TaylorButyl_Acetate_iecr50p1247tځChemSepAdapted from Luyben et al., Ind. Eng. Chem. Res. (2011) 50 pp. 1247-1263 Process to synthesize Butyl Acetate from Methyl Acetate and Butanol. Note that the temperature of the last column has been increased to 4.4 atm to match the bottom temperature of the Butyl Acetate column. Also realize that the Methyl Acetate recycle rate is a strong function of the chosen thermodynamic models and their interaction parameters.x temperaturepressure compositionflowButyl Acetate ProcessAUwNA\t//Butyl Acetate Processư>MbP?MbP?MbP?K.C:\Program Files\ChemSepL6v90\pcd\chemsep1.pcdqMethyl acetate CH3COOCH3C3H6O279-20-9CC(=O)OC 8̬@QA/?@A?pt@e@e@@E?`R@s?@?=@@7e9ǥ?T1A`@RA4g^A 8EY2@h 8 8 8׃Q@e@Fw??­@ HP? 8e@@i[@`fh+w>@e@@e@·AW? Mg^?te@@j`@ 8 8 8 8r@`f@`fB@@ƚ?@K)i@`fVw@`c@`fh-(@U4 ?`4vr@p@`п? bA: \l̬o@@3@hp=&@QY-2 ͡@@o@z@e 0>kC? \@@ 8@o@@f`/ҿ/;@9?K?ozľe@`f"x@@ ?ƿcA`40 8@3Oq@@@ftCݓ@ !K۳e@̨@8@Q]@ 7? :t>r@@@d 8 8 8 8 8 8 8 \o5@`f@"KF 8 8 s@ c|@ 9#oB`> 8 8@o@z@ ;pΈ^1@LmHLP÷w-!@H8>@`ff@ף@ף@ /?`@s? 8 8?@?? ?H?qR@s?@1(@ z@ a?@A?s?gMethanolCH3OHCH4O67-56-1COM@:^A?5?@?@ u@@ e@@ e@ {?@`@@ڤ?z?`T=@9`%;?VA3Y@H ALHA 8`•>@W 8 8 8dd@̔e@6??@? 8@ e@q@i`f^@@3.`U>@@ e@@e(A?-??@ e@@3 @j@3Ɍ@o2w?>9@@3c@d@̘@_?@@ e@y@ @3s-@ 1&@@qO?@הY@p@L0hC@?W@R`fq@p@h|@@ @vо@@ e@u@e Q> bJ?כi@M8@ 8n@@@f @O*@ڊ2`_b@z@K> C? [@@ 8q@b@f2@@@@qP?¾q@`fr@@#@@ M]h?58`U!>I@@@d 8 8 8 8 8 8 8Z7@ƫ@ ݔB 8 8`f>s@|@ @*? 8 8@ e@u@ 㥛 u@ X4?#~jL|sj1@G?G?Q?@?@֤?@?ۿ`?6?!S? k??@?@ڤ?D @z@)Տ?@?֤? 1-butanol CH3(CH2)3OHC4H10O71-36-3CCCCOQ`f@VPA?ף?nx@@3f@Qg@4?@߇R@?x?z)=@T9@,Ԫ?@A@^ A,aA 8wL@33,@[C> 8 8 8Qg@Q@h@@a?/?`f@#? 8Qg@@i %@@g@Ծ@Qg@@eWAC?w @ @`9Qg@@j̪@ 5qw l?4@Gg@d@@@ `6? Qg@lx@ @@,)@$?pb@p@?@T"Kh@q@p@h`XF@3@р@`ؾ@g@lx@e`>.?R@@3h@ 8Qg@@@fߓ? 3`ffQXQg@lx@J-?`?@p 8@3+w@ G@f n"Q@1 ]?I*Ѿ`fq@`fy@"@= a@`S? sfJ``>I@@@d 8 8 8 8 8 8 8`x5@@z4[ 8 8@3/u@s@ (@ ? 8 8g@lx@ eX@@ffffgI-LN]m{?#\>@h @j@(? ?L@???7?.?ِ?7 ?`?3W@?k p@q@]Jz?`B>?X?N-butyl acetateCH3COO(CH2)3CH3C6H12O2123-86-4 CC(=O)OCCCC#@(GAPk?&1?x@h@h@?= ]@?I ?ti=A@-"93? @h@@3@e,A 0?@пƿS?h@@3@jSA 8 8 8 8@pA`f3 @7|?) >`fVi@@3|@@ \ф /*@Ep>`fr@@:?@ p.P@r@$@h@ 1`fԖ@?` ~>@@o@)x@eL'|>1?"+J@'@ 8h@@@fZ?i_ ڿJxE>h@`f|@$9>@@ #y`@ 8q@@f1"1@RE mȾh@@3@G7@`K&? 8`fr@@ 8 8 8 8 8 8 895@`fT@6P 8 8zu@` @ @@/j 8 8 8@o@)x@K7g@&WMa? rh<~8>@BO@@@@@I ?A@?s?I ?N?`?@S?`ǜ?@`@?W@`p@lE?ӿ?&1?? activityCoefficientactivityCoefficientDdensitydensity enthalpyenthalpy enthalpyF enthalpyFentropyentropy: excessEnthalpyexcessEnthalpyfugacityCoefficientfugacityCoefficient heatOfVaporizationheatOfVaporizationO logFugacityCoefficientlogFugacityCoefficient vaporPressure vaporPressureN volumevolumeVapor Vapor phaseLiquid Liquid phase . `"?MethylAcetate/Methanol p86 1/2cimported from NRTL.IPD`"?MethylAcetate/Methanol p86 1/2cimported from NRTL.IPDc]K?Methanol/1-Butanol p127 1/2cimported from NRTL.IPDc]K?Methanol/1-Butanol p127 1/2cimported from NRTL.IPDT 333333?Methyl acetate/methyl acetateimported from HAYDENO.IPD?Methyl acetate/methanolimported from HAYDENO.IPD?n-butanol/methyl acetateimported from HAYDENO.IPD?Methyl acetate/methanolimported from HAYDENO.IPDGz?Methanol/methanolimported from HAYDENO.IPD?n-butanol/methanolimported from HAYDENO.IPD?n-butanol/methyl acetateimported from HAYDENO.IPD?n-butanol/methanolimported from HAYDENO.IPD@n-butanol/n-butanolimported from HAYDENO.IPD:X?MethylAcetate/Methanol p82 1/2cimported from VANLAAR.IPD;On?MethylAcetate/Methanol p82 1/2cimported from VANLAAR.IPD ?Methanol/1-Butanol p127 1/2cimported from VANLAAR.IPD2U0*?Methanol/1-Butanol p127 1/2cimported from VANLAAR.IPD:?MethylAcetate/Methanol p82 1/2imported from MARGULES.IPDY8m?MethylAcetate/Methanol p82 1/2imported from MARGULES.IPDB?Methanol/1-Butanol p127 1/2imported from MARGULES.IPD0' ?Methanol/1-Butanol p127 1/2imported from MARGULES.IPD6{_j/MethylAcetate/Methanol p86 1/2cimported from WILSON.IPDYpuy@MethylAcetate/Methanol p86 1/2cimported from WILSON.IPD|bwY@Methanol/1-Butanol p127 1/2cimported from WILSON.IPD=H@Methanol/1-Butanol p127 1/2cimported from WILSON.IPD.leh@MethylAcetate/Methanol p86 1/2cimported from NRTL.IPDJe@MethylAcetate/Methanol p86 1/2cimported from NRTL.IPD2vtx@Methanol/1-Butanol p127 1/2cimported from NRTL.IPDpnMethanol/1-Butanol p127 1/2cimported from NRTL.IPD: j*˱?b@$?>ّ5?W@ŗ`?I5?35 ?oq0?=rB*?p}K?^.n?ڊe?W?e?s?hh1?<,Ԛ?_\;?H}8g?q?t@Aml^_@xΊ @1 MeOH+MeACy"yy"yy"" default`@t@Ro:Q@&( @b7⻴ ?(#|?vHz?_*?ư>k#>$"P ??‹??¢j{O>7XZH>cW\>?b7⻴ ?(#|?vHz?_*?ư>k#>$"P ?? BuOH recycle4NhN444N defaultмA@/D{@˽@@^{ @N }X>:A)W>< >>j?٭SA?f??b}?L ~>OiE#}>E;>@a|>M?C֧?{*_?b??N }X>:A)W>< >>j?٭SA?f??b}?QBuAcUUUUUUU )defaultluAr|@y~0@&%?wK;t;n,2i;Ks;u:ΫU;jv?I?+$?٢?P`P?q_? ?jHpM??jv?I?+$?٢?X24J:933J9J339:9 default17Ad-UM{@˽@@^{ @N }X>:A)W>< >>j?٭SA?f??b}??N }X>:A)W>< >>j?٭SA?f??b}?2 MeAc RecycleG Z G  G default6@Pt@'E@N@{Gz? 2? ףp= ?c4Sd ?iI61i?? [??{Gz? 2? ףp= ?c4Sd ?PMeOH:VU:V:VV  (defaultA :ou@'Z&;@X3ص?v?@bQ;@?"usr?' A ?3Oj$>\^z >xS藔 ?R,2=?I?zn?>?nJ?&NXV?xj8_>o xaI>Z ?y} i&??v?@bQ;@?"usr?' A ?3Oj$>\^z >xS藔 ?R,2=?^ MeAc Feed!#9#!#!#9#!#9# `&5@5default17As@VUUUUD@@333333?Dd"z??n:u??333333?Dd"z??n:u?333333?Dd"z??n:u?s@17AVUUUUD@@ BuOH+BuAcy@@@y@@y@@ *defaultD A4|y@J H@ @2i fP>""J>wư>Ϳ;>ol?38l ?[Tx&?exz? v>֡Vs>M_>g?B> /fô?0& @?_qZ? Ka~??2i fP>""J>wư>Ϳ;>ol?38l ?[Tx&?exz?910@!C*A&@!C*@!A!A*C* default17Ae t@Q@!u_hQ@j-U?]%^c?*TA?js?y$<):Slj*<(Რm<&IA`|}<?k-U?]%^c?,TA?js?215X,[,Y,X,[,X,[, defaultAu@]@r`@Dr_6?ta??db'? ?R7/?)? ٤Y?NG.n??Dr_6?ta??db'? ?R7/?)? ٤Y?NG.n?218A7C.B3A.C7A7B7B.C. default17Ad-UM{@I@o@-4fP>ƬO>Vư>j Q>h?Hk?}ҧ$?RGk??-4fP>ƬO>Vư>j Q>h?Hk?}ҧ$?RGk?221I,K,J,I,K,I,K, default17A[h4m=x@^@@QXM?!?w\ ?twr:??d2? m?(Ӷd??QXM?!?w\ ?twr:??d2? m?(Ӷd?222C 988 CC 8 89 default17Ae t@'E@N@{Gz? 2? ףp= ?c4Sd ?iI61""J>wư>Ϳ;>ol?38l ?[Tx&?exz??2i fP>""J>wư>Ϳ;>ol?38l ?[Tx&?exz?2Butanol 5:5 5 5:5 5:5 @55default17As@rq;@rqx@???????s@17Arq;@rqx@28N,P,O,N,P,N,P, defaultA*h4m=x@^@@QXM?!?w\ ?twr:??d2? m?(Ӷd??QXM?!?w\ ?twr:??d2? m?(Ӷd?230;493;393;4;4;393 o undefault17As@4}lrh&@Z薵??????231:$8%:%8$:%:$:%8% default17As@+@V2u?333333?Dd"z??n:u??333333?Dd"z??n:u?2 C1ChemSep Unit OperationqeWCXcCSUOt[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_2E_~1.sep Title=ChemSep CO Unit Operation "C1" in COFE Flowsheet User=Harry Date=2012-02-01 Time=23:47:04 [Cape-Open] unitname=C1 CO_ID=CS_31_1244_1CCE133_72CA3D20 4 components Methyl acetate 79-20-9 74.0790023804 Mw Methanol 67-56-1 32.0419998169 Mw 1-butanol 71-36-3 74.1230010986 Mw N-butyl acetate 123-86-4 116.157997131 Mw 1 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=TRUE WilsonEstimate=TRUE Status= 1 Converged, 2 Iterations 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=K Flow=kmol/h Mass flow=kg/s Pressure=atm Heat=J/s Enthalpy=J/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=rad Velocity=m/s Surface tension=N/m Density=kg/m3 Molar density=kmol/m3 Viscosity=N/m2.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=m2/s Interaction parameter=J/mol Time=s [Components] 4 64 1312 Library Offset, Index DT=2012-01-31,09:17:24 CHK=52947 CAS=79-20-9 CID=Methyl acetate Name=Methyl acetate Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 1101 Library Offset, Index DT=2012-01-31,09:17:24 CHK=37880 CAS=67-56-1 CID=Methanol Name=Methanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 94 1105 Library Offset, Index DT=2012-01-31,09:17:24 CHK=53304 CAS=71-36-3 CID=1-butanol Name=1-butanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 1 1315 Library Offset, Index DT=2010-11-11,13:28:14 CHK=61714 CAS=123-86-4 CID=N-butyl acetate Name=N-butyl acetate Lib=h:\chemsep\documents\case_stories\flowsheets\butyl acetate\butylacetate.pcd [Operation] 2 Operation Column 1 Operation kind Simple Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 37 Stages 1 Feed stages 0 Sidestream stages F=20 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 4 K model DECHEMA 6 1 Activity coefficient NRTL * Wilson model * * UNIQUAC model * * Equation of State * * Cubic EOS * * Virial EOS * 3 Vapour pressure T correlation 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 1 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [NRTL Data] i j Aij Aji aij Component Component 1 2 1596.011 1449.907 0.2965 Methyl acetate/Methanol 1 3 * * * Methyl acetate/1-butanol 1 4 * * * Methyl acetate/N-butyl acetate 2 3 3321.332 -2034.804 0.2483 Methanol/1-butanol 2 4 1373.256 1895.359 0.2961 Methanol/N-butyl acetate 3 4 * * * 1-butanol/N-butyl acetate [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 36 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 1 Column pressure Constant pressure 121590 Condenser pressure 156040.5 Top pressure * Pressure Drop * Bottom pressure [Feeds] 1 Number 1 Feed state T & p 20 Stage Feed1{split} 349.958672198 Temperature 141855 Pressure 0.000226581514303 Vapour fraction 4 componentflows 0.0273866145746 Component 1 flow 0.0426134194951 Component 2 flow 0.0303492029185 Component 3 flow 0.0196507630117 Component 4 flow [Condenser] 7 Type Mole fraction of a component 0.000001 Value Qcondenser 3 1st comp. * Type * * Initialization guess [Reboiler] 7 Type Mole fraction of a component 0.000001 Value Qreboiler 2 1st comp. * Type * * Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 300 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data Temperature profile On Vertical Black set label "ChemSep" at 405.6088,1.88 right On Off StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 Temperature (K) 320.4187 405.6088 20 0 Off Off Off y1 Stage 45 1 10 0 Off Off Off x2 0 Off Off Off y2 0 Off Off Off StringGrid=StringGrid3 2 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage 1 T T S x1 y1 K Red Diamond Normal Solid 1 45 CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 1 ComboBox=ComboBox23 2 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Methanol - 1-butanol Xlabel X Methanol/(Methanol+1-butanol) Ylabel Y Methanol/(Methanol+1-butanol) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 1 ComboBox=ComboBox76 3 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 0 Edit=Edit1 1.20000 Edit=Edit2 21 Edit=Edit3 Title ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 20 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 5 7 Identifier L# File Loc. CAS SMILES Name Methyl acetate 1312 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 64 79-20-9 CC(=O)OC Methyl acetate Methanol 1101 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 67-56-1 CO Methanol 1-butanol 1105 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 94 71-36-3 CCCCO 1-butanol N-butyl acetate 1315 h:\chemsep\documents\case_stories\flowsheets\butyl acetate\butylacetate.pcd 1 123-86-4 N-butyl acetate 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 2 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 332.6624704 1.215900000E+05 7.000356666E-02 2.304618730E-02 -3.125595528E+06 2 341.4359193 1.560405000E+05 9.304975396E-02 2.298044650E-02 0.000000000E+00 3 342.2074174 1.560405000E+05 9.298401316E-02 2.282023025E-02 0.000000000E+00 4 342.4054872 1.560405000E+05 9.282379691E-02 2.278453581E-02 0.000000000E+00 5 342.4599108 1.560405000E+05 9.278810248E-02 2.277400025E-02 0.000000000E+00 6 342.4877277 1.560405000E+05 9.277756691E-02 2.276724522E-02 0.000000000E+00 7 342.5170167 1.560405000E+05 9.277081188E-02 2.275894938E-02 0.000000000E+00 8 342.5572859 1.560405000E+05 9.276251604E-02 2.274656398E-02 0.000000000E+00 9 342.6162449 1.560405000E+05 9.275013064E-02 2.272709642E-02 0.000000000E+00 10 342.7048536 1.560405000E+05 9.273066308E-02 2.269565564E-02 0.000000000E+00 11 342.8409427 1.560405000E+05 9.269922230E-02 2.264379808E-02 0.000000000E+00 12 343.0542840 1.560405000E+05 9.264736474E-02 2.255699474E-02 0.000000000E+00 13 343.3944094 1.560405000E+05 9.256056140E-02 2.241110614E-02 0.000000000E+00 14 343.9409182 1.560405000E+05 9.241467280E-02 2.216955899E-02 0.000000000E+00 15 344.8096657 1.560405000E+05 9.217312565E-02 2.178864215E-02 0.000000000E+00 16 346.1296376 1.560405000E+05 9.179220881E-02 2.124684743E-02 0.000000000E+00 17 347.9440336 1.560405000E+05 9.125041409E-02 2.059794057E-02 0.000000000E+00 18 350.0573487 1.560405000E+05 9.060150724E-02 1.997592743E-02 0.000000000E+00 19 352.0525695 1.560405000E+05 8.997949410E-02 1.949577243E-02 0.000000000E+00 20 353.5850173 1.560405000E+05 8.949933909E-02 1.403118931E-01 0.000000000E+00 21 354.8008332 1.560405000E+05 9.031545976E-02 1.395968902E-01 0.000000000E+00 22 356.0821891 1.560405000E+05 8.960045691E-02 1.391136582E-01 0.000000000E+00 23 357.2223559 1.560405000E+05 8.911722486E-02 1.388336129E-01 0.000000000E+00 24 358.1371193 1.560405000E+05 8.883717952E-02 1.386412462E-01 0.000000000E+00 25 358.9738204 1.560405000E+05 8.864481288E-02 1.383114008E-01 0.000000000E+00 26 360.3798838 1.560405000E+05 8.831496750E-02 1.372440588E-01 0.000000000E+00 27 364.3972669 1.560405000E+05 8.724762545E-02 1.343090146E-01 0.000000000E+00 28 374.6146025 1.560405000E+05 8.431258130E-02 1.313881783E-01 0.000000000E+00 29 388.6025279 1.560405000E+05 8.139174499E-02 1.340305295E-01 0.000000000E+00 30 397.3315917 1.560405000E+05 8.403409613E-02 1.382208799E-01 0.000000000E+00 31 400.3718788 1.560405000E+05 8.822444659E-02 1.400730374E-01 0.000000000E+00 32 401.1863369 1.560405000E+05 9.007660401E-02 1.406078888E-01 0.000000000E+00 33 401.3888052 1.560405000E+05 9.061145549E-02 1.407557643E-01 0.000000000E+00 34 401.4412506 1.560405000E+05 9.075933100E-02 1.408246811E-01 0.000000000E+00 35 401.4627103 1.560405000E+05 9.082824774E-02 1.409207932E-01 0.000000000E+00 36 401.4914958 1.560405000E+05 9.092435981E-02 1.411341006E-01 0.000000000E+00 37 401.5690804 1.560405000E+05 9.113766731E-02 4.999643334E-02 3.610421859E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.3085918E+08 -0.3085918E+08 -0.9414844E+05 -0.9414844E+05 2 0.2731405E+07 -0.3106878E+08 0.1052563E+05 -0.9595390E+05 3 0.2703351E+07 -0.3133032E+08 0.1025617E+05 -0.9704173E+05 4 0.2697345E+07 -0.3138366E+08 0.1018987E+05 -0.9724395E+05 5 0.2697338E+07 -0.3139195E+08 0.1018584E+05 -0.9723384E+05 6 0.2699172E+07 -0.3138988E+08 0.1019970E+05 -0.9715969E+05 7 0.2702164E+07 -0.3138450E+08 0.1022288E+05 -0.9704536E+05 8 0.2706532E+07 -0.3137711E+08 0.1025599E+05 -0.9688440E+05 9 0.2712896E+07 -0.3136795E+08 0.1030283E+05 -0.9665849E+05 10 0.2722299E+07 -0.3135736E+08 0.1036983E+05 -0.9633826E+05 11 0.2736454E+07 -0.3134653E+08 0.1046719E+05 -0.9587929E+05 12 0.2758183E+07 -0.3133841E+08 0.1061091E+05 -0.9521563E+05 13 0.2792147E+07 -0.3133915E+08 0.1082588E+05 -0.9425344E+05 14 0.2845846E+07 -0.3135999E+08 0.1114939E+05 -0.9287241E+05 15 0.2930418E+07 -0.3141738E+08 0.1163204E+05 -0.9095656E+05 16 0.3059092E+07 -0.3152533E+08 0.1232591E+05 -0.8849008E+05 17 0.3238660E+07 -0.3167481E+08 0.1324227E+05 -0.8570239E+05 18 0.3453664E+07 -0.3182520E+08 0.1428722E+05 -0.8307385E+05 19 0.3663113E+07 -0.3194469E+08 0.1526604E+05 -0.8105287E+05 20 0.3827476E+07 -0.3204352E+08 0.1601223E+05 -0.7978729E+05 21 0.3762682E+07 -0.3226806E+08 0.1551915E+05 -0.8075441E+05 22 0.3698589E+07 -0.3242937E+08 0.1480567E+05 -0.8165442E+05 23 0.3641799E+07 -0.3252728E+08 0.1395679E+05 -0.8239178E+05 24 0.3602498E+07 -0.3257837E+08 0.1314184E+05 -0.8289200E+05 25 0.3600999E+07 -0.3259556E+08 0.1257170E+05 -0.8299218E+05 26 0.3709204E+07 -0.3256465E+08 0.1264999E+05 -0.8208184E+05 27 0.4201963E+07 -0.3231473E+08 0.1461753E+05 -0.7846076E+05 28 0.5879973E+07 -0.3098717E+08 0.2132496E+05 -0.7071775E+05 29 0.9393678E+07 -0.2817613E+08 0.3284752E+05 -0.6238820E+05 30 0.1260742E+08 -0.2607270E+08 0.4069511E+05 -0.5795705E+05 31 0.1396579E+08 -0.2529363E+08 0.4287942E+05 -0.5659442E+05 32 0.1435400E+08 -0.2507850E+08 0.4317749E+05 -0.5627016E+05 33 0.1445381E+08 -0.2501762E+08 0.4317774E+05 -0.5618192E+05 34 0.1448382E+08 -0.2498455E+08 0.4317948E+05 -0.5611313E+05 35 0.1450512E+08 -0.2493207E+08 0.4322847E+05 -0.5597488E+05 36 0.1454471E+08 -0.2481066E+08 0.4336858E+05 -0.5564458E+05 37 0.1464033E+08 -0.2451162E+08 0.4371675E+05 -0.5483993E+05 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.5391143E+02 0.2370090E+01 0.9775826E-05 0.7055139E+05 0.1657390E-01 2 0.4849187E+02 0.2665551E+01 0.1030745E-04 0.6565258E+05 0.1801834E-01 3 0.4680328E+02 0.2566931E+01 0.1041385E-04 0.6384946E+05 0.1828029E-01 4 0.4640327E+02 0.2543520E+01 0.1043972E-04 0.6342513E+05 0.1834430E-01 5 0.4632652E+02 0.2538910E+01 0.1044515E-04 0.6334860E+05 0.1835856E-01 6 0.4632376E+02 0.2538552E+01 0.1044607E-04 0.6335362E+05 0.1836217E-01 7 0.4634188E+02 0.2539328E+01 0.1044595E-04 0.6338429E+05 0.1836385E-01 8 0.4637190E+02 0.2540674E+01 0.1044552E-04 0.6343252E+05 0.1836562E-01 9 0.4641526E+02 0.2542612E+01 0.1044491E-04 0.6350222E+05 0.1836824E-01 10 0.4647728E+02 0.2545351E+01 0.1044414E-04 0.6360281E+05 0.1837245E-01 11 0.4656674E+02 0.2549239E+01 0.1044324E-04 0.6374972E+05 0.1837939E-01 12 0.4669734E+02 0.2554798E+01 0.1044227E-04 0.6396747E+05 0.1839110E-01 13 0.4689019E+02 0.2562808E+01 0.1044144E-04 0.6429480E+05 0.1841109E-01 14 0.4717681E+02 0.2574376E+01 0.1044119E-04 0.6479128E+05 0.1844523E-01 15 0.4760014E+02 0.2590933E+01 0.1044224E-04 0.6554118E+05 0.1850247E-01 16 0.4820505E+02 0.2613852E+01 0.1044540E-04 0.6663874E+05 0.1859336E-01 17 0.4900260E+02 0.2643243E+01 0.1045071E-04 0.6812240E+05 0.1872293E-01 18 0.4991183E+02 0.2676034E+01 0.1045659E-04 0.6985800E+05 0.1887875E-01 19 0.5075728E+02 0.2705940E+01 0.1046127E-04 0.7151771E+05 0.1903083E-01 20 0.5138344E+02 0.2727449E+01 0.1046471E-04 0.7279056E+05 0.1915268E-01 21 0.4870778E+02 0.2576564E+01 0.1062376E-04 0.7005221E+05 0.1961224E-01 22 0.4606599E+02 0.2428049E+01 0.1078561E-04 0.6736515E+05 0.2008147E-01 23 0.4380471E+02 0.2301492E+01 0.1092718E-04 0.6507400E+05 0.2049360E-01 24 0.4213678E+02 0.2208205E+01 0.1103414E-04 0.6340995E+05 0.2081109E-01 25 0.4114976E+02 0.2151453E+01 0.1110344E-04 0.6254320E+05 0.2104280E-01 26 0.4110640E+02 0.2140801E+01 0.1113193E-04 0.6306646E+05 0.2125150E-01 27 0.4326633E+02 0.2228446E+01 0.1108430E-04 0.6748603E+05 0.2160128E-01 28 0.5125861E+02 0.2568085E+01 0.1080223E-04 0.8304352E+05 0.2231797E-01 29 0.6705843E+02 0.3238733E+01 0.1014594E-04 0.1144495E+06 0.2307584E-01 30 0.8047345E+02 0.3801254E+01 0.9603040E-05 0.1417801E+06 0.2337555E-01 31 0.8590853E+02 0.4027171E+01 0.9395763E-05 0.1529985E+06 0.2343978E-01 32 0.8744232E+02 0.4090749E+01 0.9338846E-05 0.1561741E+06 0.2345256E-01 33 0.8784264E+02 0.4107404E+01 0.9324332E-05 0.1569932E+06 0.2345418E-01 34 0.8798082E+02 0.4113328E+01 0.9319872E-05 0.1572511E+06 0.2345147E-01 35 0.8811362E+02 0.4119316E+01 0.9316517E-05 0.1574565E+06 0.2344337E-01 36 0.8838675E+02 0.4131789E+01 0.9310237E-05 0.1578541E+06 0.2342362E-01 37 0.8903977E+02 0.4161511E+01 0.9295748E-05 0.1588019E+06 0.2337687E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.4849187E+02 0.8436915E+03 0.3180048E-03 0.1140016E+06 0.1727740E+00 0.1970212E-01 2 0.4165947E+02 0.8063722E+03 0.3077707E-03 0.1060520E+06 0.1783761E+00 0.1870055E-01 3 0.3999624E+02 0.7975808E+03 0.3095172E-03 0.1037650E+06 0.1802378E+00 0.1860008E-01 4 0.3967365E+02 0.7956966E+03 0.3098276E-03 0.1033466E+06 0.1806023E+00 0.1857636E-01 5 0.3965933E+02 0.7955038E+03 0.3098881E-03 0.1033587E+06 0.1806307E+00 0.1857124E-01 6 0.3973119E+02 0.7957512E+03 0.3099040E-03 0.1035017E+06 0.1805691E+00 0.1857013E-01 7 0.3985114E+02 0.7961978E+03 0.3099226E-03 0.1037303E+06 0.1804610E+00 0.1856986E-01 8 0.4002439E+02 0.7968324E+03 0.3099678E-03 0.1040624E+06 0.1803028E+00 0.1856975E-01 9 0.4027197E+02 0.7977067E+03 0.3100715E-03 0.1045438E+06 0.1800745E+00 0.1856966E-01 10 0.4062878E+02 0.7989033E+03 0.3102922E-03 0.1052508E+06 0.1797415E+00 0.1856953E-01 11 0.4114955E+02 0.8005313E+03 0.3107395E-03 0.1063061E+06 0.1792489E+00 0.1856932E-01 12 0.4191952E+02 0.8027197E+03 0.3116141E-03 0.1079071E+06 0.1785094E+00 0.1856891E-01 13 0.4306907E+02 0.8055853E+03 0.3132704E-03 0.1103666E+06 0.1773874E+00 0.1856794E-01 14 0.4478438E+02 0.8091381E+03 0.3162880E-03 0.1141511E+06 0.1756861E+00 0.1856542E-01 15 0.4728354E+02 0.8130748E+03 0.3214718E-03 0.1198501E+06 0.1731700E+00 0.1855861E-01 16 0.5068535E+02 0.8165331E+03 0.3295259E-03 0.1278971E+06 0.1696970E+00 0.1854126E-01 17 0.5473766E+02 0.8182755E+03 0.3401551E-03 0.1379064E+06 0.1654987E+00 0.1850379E-01 18 0.5869618E+02 0.8177104E+03 0.3514225E-03 0.1482231E+06 0.1613180E+00 0.1844242E-01 19 0.6176622E+02 0.8155473E+03 0.3610640E-03 0.1568054E+06 0.1579765E+00 0.1837035E-01 20 0.6364978E+02 0.8129007E+03 0.3683706E-03 0.1626654E+06 0.1558071E+00 0.1830860E-01 21 0.6203067E+02 0.8084612E+03 0.3702943E-03 0.1610792E+06 0.1577693E+00 0.1818852E-01 22 0.6063754E+02 0.8040805E+03 0.3710030E-03 0.1598382E+06 0.1594138E+00 0.1806534E-01 23 0.5960422E+02 0.8004043E+03 0.3708969E-03 0.1590340E+06 0.1606066E+00 0.1795836E-01 24 0.5899736E+02 0.7977312E+03 0.3706293E-03 0.1587825E+06 0.1613032E+00 0.1787662E-01 25 0.5901224E+02 0.7960284E+03 0.3710464E-03 0.1596968E+06 0.1613233E+00 0.1781465E-01 26 0.6052459E+02 0.7949653E+03 0.3741019E-03 0.1643314E+06 0.1597512E+00 0.1774571E-01 27 0.6591889E+02 0.7921969E+03 0.3828137E-03 0.1799199E+06 0.1539322E+00 0.1757010E-01 28 0.7603240E+02 0.7798752E+03 0.3843189E-03 0.2117680E+06 0.1422916E+00 0.1699395E-01 29 0.8426639E+02 0.7603925E+03 0.3582239E-03 0.2425545E+06 0.1315969E+00 0.1600611E-01 30 0.8762054E+02 0.7483204E+03 0.3355854E-03 0.2573491E+06 0.1266184E+00 0.1532695E-01 31 0.8858423E+02 0.7441673E+03 0.3273286E-03 0.2619324E+06 0.1250826E+00 0.1508316E-01 32 0.8883787E+02 0.7430793E+03 0.3250711E-03 0.2631168E+06 0.1246805E+00 0.1501701E-01 33 0.8892592E+02 0.7428608E+03 0.3244246E-03 0.2634098E+06 0.1245683E+00 0.1499971E-01 34 0.8901111E+02 0.7429284E+03 0.3240524E-03 0.2634890E+06 0.1245076E+00 0.1499326E-01 35 0.8918673E+02 0.7432352E+03 0.3234388E-03 0.2635288E+06 0.1244114E+00 0.1498618E-01 36 0.8960721E+02 0.7440086E+03 0.3220108E-03 0.2635901E+06 0.1241890E+00 0.1497079E-01 37 0.9064158E+02 0.7458680E+03 0.3184952E-03 0.2637392E+06 0.1236406E+00 0.1493215E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.520231201E+00 0.391217407E+00 0.350914733E+00 0.341224386E+00 0.339163742E+00 2 0.479763101E+00 0.608731405E+00 0.648966415E+00 0.658567922E+00 0.660508076E+00 3 0.105612552E-06 0.100000000E-05 0.276920186E-05 0.606569219E-05 0.122439878E-04 4 0.559215814E-05 0.501881221E-04 0.116082691E-03 0.201626583E-03 0.315938561E-03 Component Mole fractions on stages: 6 to 10 1 0.338774691E+00 0.338755856E+00 0.338839194E+00 0.338978626E+00 0.339179268E+00 2 0.660729699E+00 0.660512749E+00 0.660093543E+00 0.659469494E+00 0.658559019E+00 3 0.238772766E-04 0.457991489E-04 0.870822981E-04 0.164717422E-03 0.310384722E-03 4 0.471733316E-03 0.685595168E-03 0.980180686E-03 0.138716209E-02 0.195132743E-02 Component Mole fractions on stages: 11 to 15 1 0.339463723E+00 0.339867787E+00 0.340441948E+00 0.341249398E+00 0.342345286E+00 2 0.657217056E+00 0.655209350E+00 0.652164131E+00 0.647511420E+00 0.640456838E+00 3 0.582717385E-03 0.108885523E-02 0.202013591E-02 0.370377852E-02 0.665267334E-02 4 0.273650357E-02 0.383400793E-02 0.537378541E-02 0.753540428E-02 0.105452028E-01 Component Mole fractions on stages: 16 to 20 1 0.343706266E+00 0.345095861E+00 0.346022474E+00 0.346100592E+00 0.345482923E+00 2 0.630147411E+00 0.616322148E+00 0.600369598E+00 0.585345856E+00 0.573907940E+00 3 0.115298197E-01 0.188308463E-01 0.281956121E-01 0.380683000E-01 0.466787912E-01 4 0.146165034E-01 0.197511447E-01 0.254123160E-01 0.304852517E-01 0.339303453E-01 Component Mole fractions on stages: 21 to 25 1 0.271162347E+00 0.196687665E+00 0.132117660E+00 0.832514984E-01 0.500707840E-01 2 0.641719099E+00 0.709001556E+00 0.766843424E+00 0.809889084E+00 0.836659183E+00 3 0.490338899E-01 0.517953190E-01 0.544809182E-01 0.569393543E-01 0.600663763E-01 4 0.380846642E-01 0.425154600E-01 0.465579974E-01 0.499200628E-01 0.532036569E-01 Component Mole fractions on stages: 26 to 30 1 0.291844808E-01 0.166082184E-01 0.901148416E-02 0.410557084E-02 0.138553736E-02 2 0.843608724E+00 0.809570892E+00 0.669241016E+00 0.383546145E+00 0.137625474E+00 3 0.680993206E-01 0.974176819E-01 0.195701559E+00 0.396442024E+00 0.572136115E+00 4 0.591074744E-01 0.764032074E-01 0.126045941E+00 0.215906260E+00 0.288852874E+00 Component Mole fractions on stages: 31 to 35 1 0.383502186E-03 0.990229562E-04 0.250948905E-04 0.632675651E-05 0.158852904E-05 2 0.374737530E-01 0.929216198E-02 0.224687469E-02 0.539339309E-03 0.128715988E-03 3 0.644253324E+00 0.664443791E+00 0.669092653E+00 0.669240972E+00 0.666908222E+00 4 0.317889421E+00 0.326165024E+00 0.328635377E+00 0.330213362E+00 0.332961473E+00 Component Mole fractions on stages: 36 to 37 1 0.393377964E-06 0.916566814E-07 2 0.302089621E-04 0.662284295E-05 3 0.660608746E+00 0.645121240E+00 4 0.339360651E+00 0.354872045E+00 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.391217407E+00 0.228143798E+00 0.187865294E+00 0.179233241E+00 0.177574326E+00 2 0.608731405E+00 0.771531231E+00 0.811446920E+00 0.819587534E+00 0.820563981E+00 3 0.100000000E-05 0.815858540E-05 0.216052602E-04 0.467901930E-04 0.941982979E-04 4 0.501881221E-04 0.316812247E-03 0.666180721E-03 0.113243440E-02 0.176749457E-02 Component Mole fractions on stages: 6 to 10 1 0.177449752E+00 0.177730629E+00 0.178211446E+00 0.178892392E+00 0.179832184E+00 2 0.819727390E+00 0.818076794E+00 0.815618230E+00 0.812037082E+00 0.806768518E+00 3 0.183545291E-03 0.351860245E-03 0.668565099E-03 0.126334561E-02 0.237699433E-02 4 0.263931241E-02 0.384071679E-02 0.550175918E-02 0.780718029E-02 0.110223035E-01 Component Mole fractions on stages: 11 to 15 1 0.181119836E+00 0.182864963E+00 0.185168799E+00 0.188024545E+00 0.191060254E+00 2 0.798896461E+00 0.786953616E+00 0.768645081E+00 0.740634449E+00 0.698953755E+00 3 0.445197240E-02 0.828633921E-02 0.152698164E-01 0.276562873E-01 0.485701497E-01 4 0.155317311E-01 0.218950819E-01 0.309163041E-01 0.436847188E-01 0.614158410E-01 Component Mole fractions on stages: 16 to 20 1 0.193135777E+00 0.192424280E+00 0.187993392E+00 0.181263888E+00 0.174540819E+00 2 0.641331934E+00 0.571951400E+00 0.503393625E+00 0.448867152E+00 0.413059821E+00 3 0.808709396E-01 0.124017007E+00 0.171471206E+00 0.214284967E+00 0.247859611E+00 4 0.846613500E-01 0.111607312E+00 0.137141776E+00 0.155583994E+00 0.164539749E+00 Component Mole fractions on stages: 21 to 25 1 0.126244255E+00 0.846355430E-01 0.532711706E-01 0.320143981E-01 0.186349586E-01 2 0.455073987E+00 0.491245854E+00 0.518234097E+00 0.534945759E+00 0.538663672E+00 3 0.250650406E+00 0.253061573E+00 0.255035246E+00 0.257309470E+00 0.262909073E+00 4 0.168031353E+00 0.171057030E+00 0.173459487E+00 0.175730373E+00 0.179792296E+00 Component Mole fractions on stages: 26 to 30 1 0.105580409E-01 0.565697140E-02 0.254330597E-02 0.868706139E-03 0.244789585E-03 2 0.514653885E+00 0.420116905E+00 0.237597784E+00 0.862884178E-01 0.239193320E-01 3 0.283062121E+00 0.348816769E+00 0.476574391E+00 0.585150820E+00 0.630787663E+00 4 0.191725954E+00 0.225409355E+00 0.283284519E+00 0.327692056E+00 0.345048215E+00 Component Mole fractions on stages: 31 to 35 1 0.636840286E-04 0.161772449E-04 0.408491896E-05 0.102998288E-05 0.259233155E-06 2 0.597585665E-02 0.144830126E-02 0.348121241E-03 0.833734827E-04 0.198460917E-04 3 0.643949577E+00 0.647023384E+00 0.647142206E+00 0.645648458E+00 0.641598434E+00 4 0.350010882E+00 0.351512137E+00 0.352505588E+00 0.354267139E+00 0.358381460E+00 Component Mole fractions on stages: 36 to 37 1 0.645986927E-07 0.152751347E-07 2 0.463096366E-05 0.100000000E-05 3 0.631626074E+00 0.607025959E+00 4 0.368369231E+00 0.392973025E+00 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 21 to 25 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 26 to 30 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 31 to 35 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 36 to 37 1 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -3.125595528E+06 [Reboiler Heat Duty] 3.610421859E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.132977519E+01 0.171478432E+01 0.186790612E+01 0.190380079E+01 0.190998186E+01 2 0.788135944E+00 0.788991269E+00 0.799764469E+00 0.803535796E+00 0.804944027E+00 3 0.105612552E+00 0.122570268E+00 0.128172576E+00 0.129635973E+00 0.129980988E+00 4 0.111423937E+00 0.158415978E+00 0.174251051E+00 0.178047032E+00 0.178749382E+00 Component K-values on stages: 6 to 10 1 0.190913026E+01 0.190600719E+01 0.190133239E+01 0.189487446E+01 0.188608769E+01 2 0.806035893E+00 0.807397000E+00 0.809316808E+00 0.812117462E+00 0.816292412E+00 3 0.130089290E+00 0.130162897E+00 0.130252534E+00 0.130381916E+00 0.130578655E+00 4 0.178733414E+00 0.178507087E+00 0.178157686E+00 0.177677732E+00 0.177034449E+00 Component K-values on stages: 11 to 15 1 0.187424929E+01 0.185857247E+01 0.183854921E+01 0.181491941E+01 0.179181844E+01 2 0.822656112E+00 0.832589542E+00 0.848459383E+00 0.874265869E+00 0.916307887E+00 3 0.130889712E+00 0.131403652E+00 0.132296018E+00 0.133921755E+00 0.136970411E+00 4 0.176187931E+00 0.175108180E+00 0.173817200E+00 0.172495199E+00 0.171701675E+00 Component K-values on stages: 16 to 20 1 0.177960952E+01 0.179341121E+01 0.184060977E+01 0.190937421E+01 0.197938181E+01 2 0.982560478E+00 0.107757783E+01 0.119264442E+01 0.130405144E+01 0.138940635E+01 3 0.142570616E+00 0.151840837E+00 0.164433509E+00 0.177652686E+00 0.188327542E+00 4 0.172646708E+00 0.176969988E+00 0.185299598E+00 0.195940797E+00 0.206213669E+00 Component K-values on stages: 21 to 25 1 0.214791831E+01 0.232393694E+01 0.248009681E+01 0.260043929E+01 0.268692757E+01 2 0.141014235E+01 0.144327235E+01 0.147972399E+01 0.151396487E+01 0.155321256E+01 3 0.195626613E+00 0.204674769E+00 0.213621133E+00 0.221287441E+00 0.228468252E+00 4 0.226652131E+00 0.248545529E+00 0.268408481E+00 0.284071911E+00 0.295917334E+00 Component K-values on stages: 26 to 30 1 0.276419472E+01 0.293588516E+01 0.354321669E+01 0.472607555E+01 0.566011567E+01 2 0.163917683E+01 0.192701337E+01 0.281669721E+01 0.444493194E+01 0.575373402E+01 3 0.240580832E+00 0.279280386E+00 0.410642206E+00 0.677504005E+00 0.907018555E+00 4 0.308291461E+00 0.338953135E+00 0.444944684E+00 0.658869375E+00 0.837137713E+00 Component K-values on stages: 31 to 35 1 0.602195235E+01 0.612112612E+01 0.614330191E+01 0.614258413E+01 0.612780042E+01 2 0.627085876E+01 0.641590409E+01 0.645428784E+01 0.646895502E+01 0.648570966E+01 3 0.100047169E+01 0.102692392E+01 0.103391905E+01 0.103654080E+01 0.103944802E+01 4 0.908227250E+00 0.927891216E+00 0.932284163E+00 0.932102716E+00 0.929070027E+00 Component K-values on stages: 36 to 37 1 0.608956540E+01 0.600038448E+01 2 0.652325615E+01 0.662284295E+01 3 0.104588581E+01 0.106275725E+01 4 0.921251351E+00 0.903044286E+00 [Molecular weights] 1 74.079 2 32.042 3 74.123 4 116.158 [Feed stream 1] 20 Stage Number 1.1999999999990E-01 Flow rate 3.5008251616319E+02 Temperature [K] 1.4185500000000E+05 Pressure [Pa] -3.2254772308607E+07 Enthalpy [J/kmol] -6.2775719272445E+04 Entropy [J/kmol/K] 2.2658151430300E-04 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2822178812186E-01 Mole fraction of component 1 3.5511182912613E-01 Mole fraction of component 2 2.5291002432104E-01 Mole fraction of component 3 1.6375635843097E-01 Mole fraction of component 4 2.7189781716337E-05 Flow rate 4.2528742614841E-01 Mole fraction of component 1 4.9781441903682E-01 Mole fraction of component 2 4.6160115669106E-02 Mole fraction of component 3 3.0738039145659E-02 Mole fraction of component 4 1.1997281021818E-01 Flow rate 2.2817712657502E-01 Mole fraction of component 1 3.5507948803173E-01 Mole fraction of component 2 2.5295688064171E-01 Mole fraction of component 3 1.6378650475154E-01 Mole fraction of component 4 5.4447833144974E+01 Molar mass 2.6536571213760E+00 Density 1.0216490361870E-05 Viscosity 1.8427694777293E-02 Thermal conductivity 7.5711337514598E+04 Heat capacity 6.6055626283988E+01 Molar mass 8.2025478616404E+02 Density 3.7859394726864E-04 Viscosity 1.5371779391422E-01 Thermal conductivity 1.6500488800473E+05 Heat capacity 1.8682015538660E-02 Surface tension [Reflashed Feed stream 1] 20 Stage Number 1.1999999999990E-01 Flow rate 3.5012418623527E+02 Temperature [K] 1.5604050000000E+05 Pressure [Pa] -3.2254772308607E+07 Enthalpy [J/kmol] -7.9486191383182E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2822178812186E-01 Mole fraction of component 1 3.5511182912613E-01 Mole fraction of component 2 2.5291002432104E-01 Mole fraction of component 3 1.6375635843097E-01 Mole fraction of component 4 1.1999999999990E-01 Flow rate 2.2822178812186E-01 Mole fraction of component 1 3.5511182912613E-01 Mole fraction of component 2 2.5291002432104E-01 Mole fraction of component 3 1.6375635843097E-01 Mole fraction of component 4 6.6052996172837E+01 Molar mass 8.2021356976595E+02 Density 3.7838843632291E-04 Viscosity 1.5370714414012E-01 Thermal conductivity 1.6501568840879E+05 Heat capacity 1.8677763504534E-02 Surface tension [Top product] 1 Stage Number 7.0003566660683E-02 Flow rate 3.3266247041876E+02 Temperature [K] 1.2159000000000E+05 Pressure [Pa] -3.0859178672058E+07 Enthalpy [J/kmol] -9.4148444578905E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 3.9121740673078E-01 Mole fraction of component 1 6.0873140514711E-01 Mole fraction of component 2 1.0000000000000E-06 Mole fraction of component 3 5.0188122110006E-05 Mole fraction of component 4 7.0003566660683E-02 Flow rate 3.9121740673078E-01 Mole fraction of component 1 6.0873140514711E-01 Mole fraction of component 2 1.0000000000000E-06 Mole fraction of component 3 5.0188122110006E-05 Mole fraction of component 4 4.8491870651459E+01 Molar mass 8.4369147132370E+02 Density 3.1800478627043E-04 Viscosity 1.7277398438698E-01 Thermal conductivity 1.1400156326040E+05 Heat capacity 1.9702120811760E-02 Surface tension [Bottom product] 37 Stage Number 4.9996433339217E-02 Flow rate 4.0156908036388E+02 Temperature [K] 1.5604050000000E+05 Pressure [Pa] -2.4511624001207E+07 Enthalpy [J/kmol] -5.4839929515091E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.5275134735478E-08 Mole fraction of component 1 1.0000000000000E-06 Mole fraction of component 2 6.0702595941234E-01 Mole fraction of component 3 3.9297302531253E-01 Mole fraction of component 4 4.9996433339217E-02 Flow rate 1.5275134735478E-08 Mole fraction of component 1 1.0000000000000E-06 Mole fraction of component 2 6.0702595941234E-01 Mole fraction of component 3 3.9297302531253E-01 Mole fraction of component 4 9.0641578576935E+01 Molar mass 7.4586798713453E+02 Density 3.1849519521031E-04 Viscosity 1.2364060973480E-01 Thermal conductivity 2.6373918348071E+05 Heat capacity 1.4932153862653E-02 Surface tension [Estimated NRTL Data] i j Aij Aji `ij 1 2 1.59601E+03 1.44991E+03 2.96500E-01 1 3 2.73191E+03 -3.46751E+02 2.00000E-01 1 4 2.71547E+03 -2.13639E+03 2.00000E-01 2 3 3.32133E+03 -2.03480E+03 2.48300E-01 2 4 1.37326E+03 1.89536E+03 2.96100E-01 3 4 1.58281E+03 9.08908E+02 2.00000E-01 [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stage%zt@ Vu@YQcu@%o%|fu@u@cdu@PEu@4u@}oxu@FSv@;\v@8y6,v@gPAv@*iŎSv@h1bv@"Ĕov@| v@t4[v@Xniiw@זKIx@23Nx@6A/7y@f<y@<(͋8y@r\y@\`Bgy@1*y@ y@"Pressure profile.Pressure at each stage%`@D AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD AD A(Vapour Flow profile4Vapour Flow at each stage%o:Q@;+/CW@'BU>W@4W@_bEp2W@91W@YT1W@n0W@á#0W@?/.W@,W@ln)W@<#W@W@R6} W@eV@|V@9V@~V@J+_V@"~0V@mfV@GV@hY5V@=D)V@bqm(V@ZjU@5TU@YYT@Jш.U@:U]V@RlV@ 5"V@ ᘰV@MV@k (V@iV@(Liquid Flow profile4Liquid Flow at each stage%N 7@I6@6@}V6@`$6@.j6@ckJ6@x&6@M"6@|6@rϤ6@X56@|@>i6@7h+6@Cs5@d1?5@4@Ka3@%~3@# =a@ zsa@}ca@Za@5Ta@X~Ia@fT'a@r`@kl`@`@[rGa@PRVa@Ys6sa@8/a@#Dca@" M#wa@kWJa@ H@Duties profile*Duties at each stage%íGF횋KA4Vapour Moleweight profile@Vapour Moleweight at each stage%KJ@>H@fG@Y3G@Hh)G@ap)G@M+G@Pk/G@"[='5G@wӂ=G@㪲HG@oBYG@qG@ǵG@4cG@?H@|a2UH@nضH@`I@7ُI@aZH@x=\rG@aE@_E@U+D@%䃞D@E@5!I@.QP@:MT@[[%zU@xNU@KRU@?U@ ҌEV@nV@*WxBV@.Vapour Density profile:Vapour Density at each stage%@g S@g@~ƅ!Y@ O@*YN@e2P@JaLS@TVDW@(.\@jd@9p@j{@ۼqR@q;@m<+@$ \%@]߇h@å@0@Uh ͜@@l@ @ti@bg@x ,6@QF\ @T7@&p@ @@Pnh@5@-LN\@mPm@eVA t@7-z@@ƻ#c@2Vapour Viscosity profile>Vapour Viscosity at each stage%xuK[>G$ŝ>F>c0>j|>0>o >aWV>4>i'>>!&>:>ә">x7>;>!W>3Z>q2>tG>Oqz>k/|>0p#>m,I>2/hX>YS>>q/g>&`G>y?ė#>RsO>EW8>[n>sDt>.Xĉ>:e>-y~>:Vapour Heat capacity profileFVapour Heat capacity at each stage%UHIQ@iP@MO@4FjO@[재O@kCO@+j0O@n\O@ղHO@(O@0O@:O@P@~T2P@OpbP@jP@AfQ@xvQ@)"Q@a2R@hWQ@^P@~jDP@b=yO@ݓEO@>O@P@4.T@T㥛Ĝ\@sFa@ˡEc@z):c@d]Kȟc@ c@S㥛c@pTc@2U0*c@HVapour Thermal conductivity profileTVapour Thermal conductivity at each stage%bޙ?Tfs?'x~?&E"Ȓ?4̒?m̈^͒?͒?CoΒ?Wϒ??:В?A Ғ?b]&Ւ?+U[ڒ?xnN?rN.O?_}D# ?$$,?0[wT?a|?Jœ?/%;?V?•?pa\?zl ږ?L˂h1?? ? uԨ?#7`_?ł?+?mj\?"0?4Liquid Moleweight profile@Liquid Moleweight at each stage%>H@XQiD@{ʄC@y):C@ƢdC@ĔHC@('C@,&6D@"D@0{PD@St$D@KԲD@?'I׈E@xWfdF@΍ KG@$(~WI@ȓk^K@mYM@C8N@%̴+O@{O@($QN@h˹WM@V+~M@ُM@%CN@ƧzP@sS@~ U@wgU@9d%V@+~5V@EB;V@&@V@bbKV@wTfV@"qV@.Liquid Density profile:Liquid Density at each stage%y&1]@\C2@"lxz@&S݈@]K܈@ F%uވ@1*@T@`TR@гY9@6@@s@2ı,@<,I@ 0h@C@bX94@1殍@Έ`|@34g@R'C@/ݤ @/n<@b@y):@4׈@N@@h_@q= #Ç@ -b@aVA@ h8@-C6@ڬ\m7@'9@u@@mN@2Liquid Viscosity profile>Liquid Viscosity at each stage%wI7<4?V+4?&e@H4?Qh N4?hBAO4?~SO4? inO4? VeP4?_#"R4?U4?uW]4?H6T^l4?M#p·4?'ܹn4?!f5?5?ȂJ6?%7?j_7?;$8?D8?apeP8?AN8?h J8?>' Q8?mc8?"lR9?R/9?Key7?oiQ05?L͡s5?MM5?(] B5?=u<5?Ryg25?hq5?twv4?:Liquid Heat capacity profileFLiquid Heat capacity at each stage%6\@SZ@)\Y@2ı.Y@DY@QY@46U\@ h]@wOj_@:=a@w#b@Y8řc@EJUd@:pΈ"d@?p <?xNz?zS?P ۑ?fBQϒ?2X}?4%@?Tq?N&#c?T ?N? >?9`p+?s?6`f?c?gc?\w?m [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data Liquid phase composition profiles On Vertical Black set label "ChemSep" at 1,1.98 right On Off StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 Liquid mole fraction 0 1 0.2 0 Off Off Off y1 Stage 50 1 10 0 Off Off Off x2 0 Off Off Off y2 0 Off Off Off StringGrid=StringGrid3 5 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage 1 Methyl acetate X1 S x1 y1 _ Red Diamond Normal Solid 1 50 2 Methanol X2 S x1 y1 _ Green + Normal Solid 1 50 3 1-butanol X3 S x1 y1 _ Blue Square Normal Solid 1 50 4 N-butyl acetate X4 S x1 y1 _ Magenta x Normal Solid 1 50 CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 2 ComboBox=ComboBox23 3 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram 1-butanol - N-butyl acetate Xlabel X 1-butanol/(1-butanol+N-butyl acetate) Ylabel Y 1-butanol/(1-butanol+N-butyl acetate) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 2 ComboBox=ComboBox76 3 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 0 Edit=Edit1 1000000 Edit=Edit2 21 Edit=Edit3 1-butanol + N-butyl acetate @ p=1000000 (N/m2) ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 27 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 5 7 Identifier L# File Loc. CAS SMILES Name Methyl acetate 1312 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 64 79-20-9 CC(=O)OC Methyl acetate Methanol 1101 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 67-56-1 CO Methanol 1-butanol 1105 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 94 71-36-3 CCCCO 1-butanol N-butyl acetate 1315 h:\chemsep\documents\case_stories\flowsheets\butyl acetate\butylacetate.pcd 1 123-86-4 N-butyl acetate 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 1 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 437.9869371 4.053000000E+05 3.348278471E-02 6.862843555E-02 -3.763916325E+06 2 438.3541165 4.053000000E+05 1.021112203E-01 6.890002455E-02 0.000000000E+00 3 438.7884464 4.062907333E+05 1.023828093E-01 6.919206732E-02 0.000000000E+00 4 439.1946558 4.072814667E+05 1.026748520E-01 6.945483542E-02 0.000000000E+00 5 439.5733659 4.082722000E+05 1.029376201E-01 6.969065340E-02 0.000000000E+00 6 439.9254053 4.092629333E+05 1.031734381E-01 6.990165341E-02 0.000000000E+00 7 440.2518591 4.102536667E+05 1.033844381E-01 7.008986558E-02 0.000000000E+00 8 440.5540601 4.112444000E+05 1.035726503E-01 7.025725748E-02 0.000000000E+00 9 440.8335482 4.122351333E+05 1.037400422E-01 7.040574364E-02 0.000000000E+00 10 441.0920127 4.132258667E+05 1.038885284E-01 7.053717819E-02 0.000000000E+00 11 441.3312291 4.142166000E+05 1.040199629E-01 7.065333918E-02 0.000000000E+00 12 441.5529991 4.152073333E+05 1.041361239E-01 7.075591124E-02 0.000000000E+00 13 441.7590980 4.161980667E+05 1.042386960E-01 7.084647007E-02 0.000000000E+00 14 441.9512334 4.171888000E+05 1.043292548E-01 7.092647125E-02 0.000000000E+00 15 442.1310138 4.181795333E+05 1.044092560E-01 7.099724365E-02 0.000000000E+00 16 442.2999295 4.191702667E+05 1.044800284E-01 7.105998775E-02 0.000000000E+00 17 442.4593412 4.201610000E+05 1.045427725E-01 7.111577795E-02 0.000000000E+00 18 442.6104758 4.211517333E+05 1.045985627E-01 7.116556733E-02 0.000000000E+00 19 442.7544291 4.221424667E+05 1.046483520E-01 7.121019529E-02 0.000000000E+00 20 442.8921707 4.231332000E+05 1.046929800E-01 7.125039664E-02 0.000000000E+00 21 443.0245526 4.241239333E+05 1.047331814E-01 7.128681091E-02 0.000000000E+00 22 443.1523187 4.251146667E+05 1.047695956E-01 7.131999209E-02 0.000000000E+00 23 443.2761153 4.261054000E+05 1.048027768E-01 7.135041770E-02 0.000000000E+00 24 443.3965012 4.270961333E+05 1.048332024E-01 7.137849896E-02 0.000000000E+00 25 443.5139579 4.280868667E+05 1.048612837E-01 7.140458756E-02 0.000000000E+00 26 443.6288989 4.290776000E+05 1.048873723E-01 7.142898458E-02 0.000000000E+00 27 443.7416786 4.300683333E+05 1.049117693E-01 1.382917329E-01 0.000000000E+00 28 443.8884216 4.310590667E+05 1.217780843E-01 1.384189369E-01 0.000000000E+00 29 444.0577762 4.320498000E+05 1.219052883E-01 1.385762533E-01 0.000000000E+00 30 444.2589178 4.330405333E+05 1.220626047E-01 1.387753806E-01 0.000000000E+00 31 444.5044911 4.340312667E+05 1.222617320E-01 1.390320713E-01 0.000000000E+00 32 444.8116991 4.350220000E+05 1.225184226E-01 1.393670869E-01 0.000000000E+00 33 445.2034509 4.360127333E+05 1.228534383E-01 1.398069393E-01 0.000000000E+00 34 445.7091975 4.370034667E+05 1.232932907E-01 1.403839108E-01 0.000000000E+00 35 446.3645922 4.379942000E+05 1.238702622E-01 1.411345415E-01 0.000000000E+00 36 447.2083083 4.389849333E+05 1.246208929E-01 1.420954510E-01 0.000000000E+00 37 448.2735479 4.399756667E+05 1.255818024E-01 1.432953259E-01 0.000000000E+00 38 449.5723244 4.409664000E+05 1.267816773E-01 1.447424059E-01 0.000000000E+00 39 451.0751349 4.419571333E+05 1.282287573E-01 1.464085677E-01 0.000000000E+00 40 452.6978534 4.429478667E+05 1.298949190E-01 1.482158892E-01 0.000000000E+00 41 454.3130000 4.439386000E+05 1.317022406E-01 1.500389705E-01 0.000000000E+00 42 455.7891383 4.449293333E+05 1.335253219E-01 1.517347536E-01 0.000000000E+00 43 457.0354990 4.459200667E+05 1.352211050E-01 1.531894529E-01 0.000000000E+00 44 458.0219744 4.469108000E+05 1.366758043E-01 1.543510572E-01 0.000000000E+00 45 458.7683587 4.479015333E+05 1.378374086E-01 1.552282695E-01 0.000000000E+00 46 459.3198162 4.488922667E+05 1.387146209E-01 1.558665734E-01 0.000000000E+00 47 459.7260038 4.498830000E+05 1.393529248E-01 1.651364862E-02 4.381765351E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.1810868E+08 -0.1810868E+08 -0.5051910E+05 -0.5051910E+05 2 0.1875227E+08 -0.1760660E+08 0.4221590E+05 -0.4868018E+05 3 0.1899237E+08 -0.1712761E+08 0.4320896E+05 -0.4706100E+05 4 0.1921106E+08 -0.1669576E+08 0.4407032E+05 -0.4565514E+05 5 0.1940967E+08 -0.1630741E+08 0.4482095E+05 -0.4443015E+05 6 0.1958948E+08 -0.1595912E+08 0.4547642E+05 -0.4336119E+05 7 0.1975170E+08 -0.1564759E+08 0.4604906E+05 -0.4242798E+05 8 0.1989762E+08 -0.1536961E+08 0.4654916E+05 -0.4161339E+05 9 0.2002853E+08 -0.1512200E+08 0.4698561E+05 -0.4090248E+05 10 0.2014574E+08 -0.1490174E+08 0.4736621E+05 -0.4028214E+05 11 0.2025054E+08 -0.1470589E+08 0.4769789E+05 -0.3974071E+05 12 0.2034421E+08 -0.1453172E+08 0.4798686E+05 -0.3926787E+05 13 0.2042794E+08 -0.1437666E+08 0.4823863E+05 -0.3885445E+05 14 0.2050289E+08 -0.1423837E+08 0.4845812E+05 -0.3849237E+05 15 0.2057011E+08 -0.1411469E+08 0.4864971E+05 -0.3817452E+05 16 0.2063058E+08 -0.1400372E+08 0.4881723E+05 -0.3789468E+05 17 0.2068515E+08 -0.1390373E+08 0.4896405E+05 -0.3764741E+05 18 0.2073463E+08 -0.1381322E+08 0.4909311E+05 -0.3742801E+05 19 0.2077971E+08 -0.1373084E+08 0.4920699E+05 -0.3723239E+05 20 0.2082099E+08 -0.1365545E+08 0.4930790E+05 -0.3705705E+05 21 0.2085902E+08 -0.1358602E+08 0.4939775E+05 -0.3689897E+05 22 0.2089426E+08 -0.1352170E+08 0.4947818E+05 -0.3675557E+05 23 0.2092712E+08 -0.1346172E+08 0.4955061E+05 -0.3662463E+05 24 0.2095794E+08 -0.1340545E+08 0.4961624E+05 -0.3650427E+05 25 0.2098703E+08 -0.1335233E+08 0.4967610E+05 -0.3639288E+05 26 0.2101464E+08 -0.1330188E+08 0.4973108E+05 -0.3628910E+05 27 0.2104099E+08 -0.1325372E+08 0.4978191E+05 -0.3619177E+05 28 0.2108828E+08 -0.1316825E+08 0.4990127E+05 -0.3598956E+05 29 0.2114950E+08 -0.1305820E+08 0.5006563E+05 -0.3571900E+05 30 0.2123020E+08 -0.1291400E+08 0.5029219E+05 -0.3535432E+05 31 0.2133803E+08 -0.1272274E+08 0.5060395E+05 -0.3486159E+05 32 0.2148332E+08 -0.1246738E+08 0.5103078E+05 -0.3419762E+05 33 0.2167972E+08 -0.1212630E+08 0.5160994E+05 -0.3331033E+05 34 0.2194466E+08 -0.1167355E+08 0.5238500E+05 -0.3214212E+05 35 0.2229907E+08 -0.1108091E+08 0.5340161E+05 -0.3063904E+05 36 0.2276562E+08 -0.1032314E+08 0.5469787E+05 -0.2876803E+05 37 0.2336405E+08 -0.9387608E+07 0.5628754E+05 -0.2654214E+05 38 0.2410261E+08 -0.8287329E+07 0.5813753E+05 -0.2404638E+05 39 0.2496665E+08 -0.7071909E+07 0.6014829E+05 -0.2144598E+05 40 0.2591004E+08 -0.5826233E+07 0.6215561E+05 -0.1895737E+05 41 0.2685930E+08 -0.4650235E+07 0.6396964E+05 -0.1678339E+05 42 0.2773447E+08 -0.3627375E+07 0.6544040E+05 -0.1504794E+05 43 0.2847611E+08 -0.2801204E+07 0.6650808E+05 -0.1377148E+05 44 0.2906041E+08 -0.2172932E+07 0.6720419E+05 -0.1289463E+05 45 0.2949545E+08 -0.1715486E+07 0.6761292E+05 -0.1232261E+05 46 0.2980708E+08 -0.1390999E+07 0.6782775E+05 -0.1196158E+05 47 0.3002563E+08 -0.1162971E+07 0.6792569E+05 -0.1173638E+05 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.7726538E+02 0.8599840E+01 0.1051208E-04 0.1524220E+06 0.2838777E-01 2 0.7832644E+02 0.8710636E+01 0.1048786E-04 0.1541360E+06 0.2834271E-01 3 0.7927651E+02 0.8829096E+01 0.1046888E-04 0.1557019E+06 0.2831476E-01 4 0.8012652E+02 0.8937249E+01 0.1045238E-04 0.1571097E+06 0.2829183E-01 5 0.8088489E+02 0.9035991E+01 0.1043810E-04 0.1583718E+06 0.2827332E-01 6 0.8155913E+02 0.9126115E+01 0.1042581E-04 0.1594995E+06 0.2825868E-01 7 0.8215626E+02 0.9208352E+01 0.1041530E-04 0.1605035E+06 0.2824746E-01 8 0.8268301E+02 0.9283400E+01 0.1040639E-04 0.1613941E+06 0.2823925E-01 9 0.8314590E+02 0.9351929E+01 0.1039891E-04 0.1621813E+06 0.2823369E-01 10 0.8355121E+02 0.9414582E+01 0.1039269E-04 0.1628752E+06 0.2823047E-01 11 0.8390495E+02 0.9471972E+01 0.1038760E-04 0.1634853E+06 0.2822927E-01 12 0.8421283E+02 0.9524680E+01 0.1038349E-04 0.1640205E+06 0.2822984E-01 13 0.8448016E+02 0.9573247E+01 0.1038025E-04 0.1644895E+06 0.2823195E-01 14 0.8471186E+02 0.9618171E+01 0.1037776E-04 0.1649002E+06 0.2823538E-01 15 0.8491243E+02 0.9659909E+01 0.1037593E-04 0.1652598E+06 0.2823995E-01 16 0.8508592E+02 0.9698873E+01 0.1037466E-04 0.1655749E+06 0.2824549E-01 17 0.8523595E+02 0.9735430E+01 0.1037388E-04 0.1658515E+06 0.2825188E-01 18 0.8536575E+02 0.9769909E+01 0.1037352E-04 0.1660948E+06 0.2825897E-01 19 0.8547814E+02 0.9802598E+01 0.1037352E-04 0.1663094E+06 0.2826667E-01 20 0.8557562E+02 0.9833749E+01 0.1037382E-04 0.1664994E+06 0.2827488E-01 21 0.8566033E+02 0.9863583E+01 0.1037438E-04 0.1666684E+06 0.2828352E-01 22 0.8573415E+02 0.9892291E+01 0.1037516E-04 0.1668193E+06 0.2829253E-01 23 0.8579869E+02 0.9920039E+01 0.1037613E-04 0.1669548E+06 0.2830185E-01 24 0.8585534E+02 0.9946967E+01 0.1037726E-04 0.1670773E+06 0.2831142E-01 25 0.8590529E+02 0.9973199E+01 0.1037852E-04 0.1671887E+06 0.2832121E-01 26 0.8594954E+02 0.9998838E+01 0.1037989E-04 0.1672906E+06 0.2833118E-01 27 0.8598897E+02 0.1002397E+02 0.1038136E-04 0.1673845E+06 0.2834129E-01 28 0.8610858E+02 0.1005772E+02 0.1038119E-04 0.1676115E+06 0.2834876E-01 29 0.8628108E+02 0.1009718E+02 0.1037994E-04 0.1679265E+06 0.2835452E-01 30 0.8652727E+02 0.1014461E+02 0.1037719E-04 0.1683641E+06 0.2835791E-01 31 0.8687538E+02 0.1020309E+02 0.1037240E-04 0.1689717E+06 0.2835810E-01 32 0.8736310E+02 0.1027668E+02 0.1036481E-04 0.1698127E+06 0.2835399E-01 33 0.8803931E+02 0.1037068E+02 0.1035352E-04 0.1709696E+06 0.2834424E-01 34 0.8896473E+02 0.1049159E+02 0.1033740E-04 0.1725457E+06 0.2832732E-01 35 0.9020949E+02 0.1064684E+02 0.1031523E-04 0.1746615E+06 0.2830166E-01 36 0.9184476E+02 0.1084387E+02 0.1028587E-04 0.1774417E+06 0.2826600E-01 37 0.9392458E+02 0.1108804E+02 0.1024866E-04 0.1809846E+06 0.2821992E-01 38 0.9645633E+02 0.1137959E+02 0.1020387E-04 0.1853119E+06 0.2816440E-01 39 0.9936619E+02 0.1171008E+02 0.1015326E-04 0.1903075E+06 0.2810228E-01 40 0.1024805E+03 0.1206078E+02 0.1010017E-04 0.1956807E+06 0.2803814E-01 41 0.1055501E+03 0.1240556E+02 0.1004896E-04 0.2010042E+06 0.2797745E-01 42 0.1083234E+03 0.1271860E+02 0.1000371E-04 0.2058383E+06 0.2792522E-01 43 0.1106278E+03 0.1298259E+02 0.9966997E-05 0.2098753E+06 0.2788463E-01 44 0.1124070E+03 0.1319222E+02 0.9939445E-05 0.2130091E+06 0.2785647E-01 45 0.1137018E+03 0.1335201E+02 0.9920136E-05 0.2153044E+06 0.2783957E-01 46 0.1146031E+03 0.1347142E+02 0.9907424E-05 0.2169158E+06 0.2783176E-01 47 0.1152107E+03 0.1356074E+02 0.9899590E-05 0.2180156E+06 0.2783069E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.7832644E+02 0.6716302E+03 0.2326192E-03 0.2817052E+06 0.1226413E+00 0.1186662E-01 2 0.7973821E+02 0.6745993E+03 0.2303007E-03 0.2817750E+06 0.1217551E+00 0.1178753E-01 3 0.8099760E+02 0.6770004E+03 0.2280226E-03 0.2818725E+06 0.1209414E+00 0.1170681E-01 4 0.8211827E+02 0.6790313E+03 0.2259990E-03 0.2819653E+06 0.1202117E+00 0.1163317E-01 5 0.8311227E+02 0.6807470E+03 0.2242025E-03 0.2820534E+06 0.1195594E+00 0.1156614E-01 6 0.8399073E+02 0.6821930E+03 0.2226085E-03 0.2821367E+06 0.1189781E+00 0.1150529E-01 7 0.8476420E+02 0.6834082E+03 0.2211950E-03 0.2822153E+06 0.1184620E+00 0.1145018E-01 8 0.8544273E+02 0.6844255E+03 0.2199417E-03 0.2822892E+06 0.1180051E+00 0.1140036E-01 9 0.8603595E+02 0.6852736E+03 0.2188301E-03 0.2823587E+06 0.1176019E+00 0.1135538E-01 10 0.8655298E+02 0.6859770E+03 0.2178432E-03 0.2824239E+06 0.1172468E+00 0.1131478E-01 11 0.8700240E+02 0.6865567E+03 0.2169656E-03 0.2824852E+06 0.1169347E+00 0.1127811E-01 12 0.8739220E+02 0.6870311E+03 0.2161834E-03 0.2825429E+06 0.1166606E+00 0.1124497E-01 13 0.8772968E+02 0.6874159E+03 0.2154841E-03 0.2825972E+06 0.1164200E+00 0.1121495E-01 14 0.8802153E+02 0.6877245E+03 0.2148565E-03 0.2826484E+06 0.1162088E+00 0.1118767E-01 15 0.8827373E+02 0.6879685E+03 0.2142908E-03 0.2826970E+06 0.1160231E+00 0.1116280E-01 16 0.8849164E+02 0.6881577E+03 0.2137782E-03 0.2827431E+06 0.1158597E+00 0.1114003E-01 17 0.8868000E+02 0.6883005E+03 0.2133113E-03 0.2827871E+06 0.1157154E+00 0.1111907E-01 18 0.8884296E+02 0.6884041E+03 0.2128835E-03 0.2828292E+06 0.1155876E+00 0.1109969E-01 19 0.8898416E+02 0.6884745E+03 0.2124890E-03 0.2828696E+06 0.1154740E+00 0.1108167E-01 20 0.8910676E+02 0.6885170E+03 0.2121231E-03 0.2829086E+06 0.1153726E+00 0.1106481E-01 21 0.8921349E+02 0.6885358E+03 0.2117814E-03 0.2829463E+06 0.1152815E+00 0.1104895E-01 22 0.8930671E+02 0.6885347E+03 0.2114604E-03 0.2829828E+06 0.1151993E+00 0.1103394E-01 23 0.8938845E+02 0.6885169E+03 0.2111571E-03 0.2830184E+06 0.1151246E+00 0.1101967E-01 24 0.8946043E+02 0.6884849E+03 0.2108687E-03 0.2830532E+06 0.1150563E+00 0.1100602E-01 25 0.8952414E+02 0.6884410E+03 0.2105932E-03 0.2830872E+06 0.1149935E+00 0.1099291E-01 26 0.8958083E+02 0.6883871E+03 0.2103286E-03 0.2831205E+06 0.1149353E+00 0.1098025E-01 27 0.8963158E+02 0.6883248E+03 0.2100732E-03 0.2831533E+06 0.1148811E+00 0.1096798E-01 28 0.8978026E+02 0.6883993E+03 0.2096827E-03 0.2831938E+06 0.1147620E+00 0.1094949E-01 29 0.8999314E+02 0.6885611E+03 0.2092052E-03 0.2832394E+06 0.1146003E+00 0.1092689E-01 30 0.9029485E+02 0.6888412E+03 0.2086081E-03 0.2832924E+06 0.1143794E+00 0.1089857E-01 31 0.9071833E+02 0.6892785E+03 0.2078484E-03 0.2833559E+06 0.1140770E+00 0.1086232E-01 32 0.9130635E+02 0.6899193E+03 0.2068714E-03 0.2834344E+06 0.1136639E+00 0.1081523E-01 33 0.9211218E+02 0.6908125E+03 0.2056111E-03 0.2835340E+06 0.1131033E+00 0.1075353E-01 34 0.9319759E+02 0.6919998E+03 0.2039949E-03 0.2836633E+06 0.1123513E+00 0.1067262E-01 35 0.9462563E+02 0.6934965E+03 0.2019553E-03 0.2838338E+06 0.1113612E+00 0.1056731E-01 36 0.9644493E+02 0.6952642E+03 0.1994530E-03 0.2840601E+06 0.1100928E+00 0.1043266E-01 37 0.9866381E+02 0.6971842E+03 0.1965094E-03 0.2843587E+06 0.1085299E+00 0.1026558E-01 38 0.1012196E+03 0.6990534E+03 0.1932387E-03 0.2847437E+06 0.1067020E+00 0.1006725E-01 39 0.1039615E+03 0.7006310E+03 0.1898543E-03 0.2852196E+06 0.1047009E+00 0.9845411E-02 40 0.1066711E+03 0.7017307E+03 0.1866252E-03 0.2857706E+06 0.1026744E+00 0.9614802E-02 41 0.1091256E+03 0.7023040E+03 0.1837915E-03 0.2863578E+06 0.1007880E+00 0.9393923E-02 42 0.1111702E+03 0.7024437E+03 0.1814897E-03 0.2869279E+06 0.9917197E-01 0.9199165E-02 43 0.1127524E+03 0.7023107E+03 0.1797356E-03 0.2874334E+06 0.9788663E-01 0.9039858E-02 44 0.1139062E+03 0.7020521E+03 0.1784593E-03 0.2878482E+06 0.9692447E-01 0.8917220E-02 45 0.1147104E+03 0.7017620E+03 0.1775564E-03 0.2881694E+06 0.9623580E-01 0.8826743E-02 46 0.1152532E+03 0.7014853E+03 0.1769243E-03 0.2884096E+06 0.9575711E-01 0.8761545E-02 47 0.1156115E+03 0.7012358E+03 0.1764793E-03 0.2885869E+06 0.9542934E-01 0.8714795E-02 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.141163093E-06 0.228088230E-07 0.997304235E-08 0.855228055E-08 0.838595282E-08 2 0.772030448E-05 0.149319940E-05 0.680892102E-06 0.574129932E-06 0.558730054E-06 3 0.925228209E+00 0.899998484E+00 0.877398243E+00 0.857176931E+00 0.839135595E+00 4 0.747639290E-01 0.100000000E+00 0.122601066E+00 0.142822486E+00 0.160863837E+00 Component Mole fractions on stages: 6 to 10 1 0.836000271E-08 0.835050807E-08 0.834349894E-08 0.833736097E-08 0.833185058E-08 2 0.555225216E-06 0.553397989E-06 0.551933983E-06 0.550654955E-06 0.549524759E-06 3 0.823095684E+00 0.808890139E+00 0.796358809E+00 0.785346809E+00 0.775704638E+00 4 0.176903752E+00 0.191109299E+00 0.203640631E+00 0.214652632E+00 0.224294804E+00 Component Mole fractions on stages: 11 to 15 1 0.832695797E-08 0.832261025E-08 0.831875120E-08 0.831534921E-08 0.831237247E-08 2 0.548530282E-06 0.547656110E-06 0.546888652E-06 0.546216634E-06 0.545629568E-06 3 0.767289170E+00 0.759964915E+00 0.753605195E+00 0.748093014E+00 0.743321570E+00 4 0.232710273E+00 0.240034529E+00 0.246394250E+00 0.251906432E+00 0.256677876E+00 Component Mole fractions on stages: 16 to 20 1 0.830978670E-08 0.830750106E-08 0.830550149E-08 0.830375183E-08 0.830224228E-08 2 0.545117652E-06 0.544668344E-06 0.544274734E-06 0.543929234E-06 0.543626538E-06 3 0.739194397E+00 0.735625187E+00 0.732537369E+00 0.729863510E+00 0.727544600E+00 4 0.260805050E+00 0.264374260E+00 0.267462078E+00 0.270135938E+00 0.272454848E+00 Component Mole fractions on stages: 21 to 25 1 0.830088472E-08 0.829971834E-08 0.829868897E-08 0.829775723E-08 0.829694349E-08 2 0.543357127E-06 0.543119946E-06 0.542908615E-06 0.542718061E-06 0.542547364E-06 3 0.725529288E+00 0.723773096E+00 0.722237661E+00 0.720890007E+00 0.719701874E+00 4 0.274470161E+00 0.276226352E+00 0.277761787E+00 0.279109442E+00 0.280297575E+00 Component Mole fractions on stages: 26 to 30 1 0.829621734E-08 0.829557429E-08 0.169648137E-08 0.347439142E-09 0.712834152E-10 2 0.542392717E-06 0.542252232E-06 0.109533852E-06 0.220962339E-07 0.444850297E-08 3 0.718649106E+00 0.717711099E+00 0.714866477E+00 0.710762800E+00 0.704906124E+00 4 0.281350344E+00 0.282288351E+00 0.285133412E+00 0.289237177E+00 0.295093872E+00 Component Mole fractions on stages: 31 to 35 1 0.146583159E-10 0.302302060E-11 0.625756714E-12 0.130135966E-12 0.272195624E-13 2 0.892929833E-09 0.178463329E-09 0.354485083E-10 0.697993430E-11 0.135769528E-11 3 0.696624715E+00 0.685022120E+00 0.668935214E+00 0.646919740E+00 0.617307163E+00 4 0.303375284E+00 0.314977880E+00 0.331064786E+00 0.353080260E+00 0.382692837E+00 Component Mole fractions on stages: 36 to 40 1 0.573184650E-14 0.121595731E-14 0.259826315E-15 0.558451595E-16 0.120413222E-16 2 0.259696600E-12 0.485675458E-13 0.882099334E-14 0.154505570E-14 0.259460761E-15 3 0.578404623E+00 0.528926334E+00 0.468696884E+00 0.399472044E+00 0.325384389E+00 4 0.421595377E+00 0.471073666E+00 0.531303117E+00 0.600527956E+00 0.674615611E+00 Component Mole fractions on stages: 41 to 45 1 0.259572612E-17 0.557458753E-18 0.118263776E-18 0.247256696E-19 0.477002017E-20 2 0.416441044E-16 0.639392831E-17 0.943363087E-18 0.134397531E-18 0.188993277E-19 3 0.252358916E+00 0.186382350E+00 0.131562387E+00 0.892351119E-01 0.584312413E-01 4 0.747641084E+00 0.813617650E+00 0.868437613E+00 0.910764888E+00 0.941568759E+00 Component Mole fractions on stages: 46 to 47 1 0.115697753E-20 0.287274392E-21 2 0.273472309E-20 0.433394641E-21 3 0.369905270E-01 0.225347801E-01 4 0.963009473E+00 0.977465220E+00 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.228087999E-07 0.373551633E-08 0.165357416E-08 0.143317370E-08 0.141828922E-08 2 0.149319796E-05 0.286152249E-06 0.129393875E-06 0.108253316E-06 0.104589332E-06 3 0.899998484E+00 0.866415388E+00 0.836455122E+00 0.809794816E+00 0.786147833E+00 4 0.100000000E+00 0.133584322E+00 0.163544747E+00 0.190205074E+00 0.213852061E+00 Component Mole fractions on stages: 6 to 10 1 0.142519998E-08 0.143342927E-08 0.144081326E-08 0.144724777E-08 0.145284260E-08 2 0.103247108E-06 0.102291911E-06 0.101473604E-06 0.100754552E-06 0.100123073E-06 3 0.765249382E+00 0.746848871E+00 0.730706797E+00 0.716594346E+00 0.704294342E+00 4 0.234750513E+00 0.253151025E+00 0.269293100E+00 0.283405552E+00 0.295705557E+00 Component Mole fractions on stages: 11 to 15 1 0.145772915E-08 0.146201265E-08 0.146578481E-08 0.146912854E-08 0.147211331E-08 2 0.995714186E-07 0.990914279E-07 0.986752914E-07 0.983158789E-07 0.980064691E-07 3 0.693602675E+00 0.684329640E+00 0.676300895E+00 0.669357939E+00 0.663358091E+00 4 0.306397224E+00 0.315670259E+00 0.323699004E+00 0.330641962E+00 0.336641809E+00 Component Mole fractions on stages: 16 to 20 1 0.147479871E-08 0.147722549E-08 0.147943820E-08 0.148147053E-08 0.148335552E-08 2 0.977408999E-07 0.975130584E-07 0.973180908E-07 0.971513966E-07 0.970092923E-07 3 0.658174065E+00 0.653693199E+00 0.649816474E+00 0.646457387E+00 0.643540768E+00 4 0.341825836E+00 0.346306702E+00 0.350183427E+00 0.353542514E+00 0.356459134E+00 Component Mole fractions on stages: 21 to 25 1 0.148510716E-08 0.148675750E-08 0.148831577E-08 0.148979578E-08 0.149121323E-08 2 0.968876767E-07 0.967842739E-07 0.966959364E-07 0.966204250E-07 0.965560024E-07 3 0.641001589E+00 0.638783819E+00 0.636839335E+00 0.635126930E+00 0.633611401E+00 4 0.358998312E+00 0.361216083E+00 0.363160567E+00 0.364872972E+00 0.366388501E+00 Component Mole fractions on stages: 26 to 30 1 0.149257631E-08 0.149389640E-08 0.305987112E-09 0.627884303E-10 0.129139980E-10 2 0.965009050E-07 0.964539063E-07 0.194599974E-07 0.391836729E-08 0.786672631E-09 3 0.632262742E+00 0.631055419E+00 0.627518339E+00 0.622454084E+00 0.615276435E+00 4 0.367737160E+00 0.368944483E+00 0.372481641E+00 0.377545912E+00 0.384723564E+00 Component Mole fractions on stages: 31 to 35 1 0.266394254E-11 0.551607236E-12 0.114763934E-12 0.240175244E-13 0.506116620E-14 2 0.157265284E-09 0.312480218E-10 0.615544630E-11 0.119797991E-11 0.229309676E-12 3 0.605202139E+00 0.591213249E+00 0.572042713E+00 0.546221265E+00 0.512248647E+00 4 0.394797861E+00 0.408786751E+00 0.427957287E+00 0.453778735E+00 0.487751353E+00 Component Mole fractions on stages: 36 to 40 1 0.107464107E-14 0.229882974E-15 0.494740024E-16 0.106831295E-16 0.230659864E-17 2 0.429231200E-13 0.780441892E-14 0.136877606E-14 0.230194508E-15 0.370040348E-16 3 0.468967861E+00 0.416181435E+00 0.355379482E+00 0.290150070E+00 0.225690459E+00 4 0.531032139E+00 0.583818565E+00 0.644620518E+00 0.709849930E+00 0.774309541E+00 Component Mole fractions on stages: 41 to 45 1 0.496511069E-18 0.105990797E-18 0.224331852E-19 0.460193438E-20 0.122715273E-20 2 0.569012869E-17 0.840699926E-18 0.119816732E-18 0.169997622E-19 0.233522219E-20 3 0.167299473E+00 0.118658965E+00 0.810170536E-01 0.535706620E-01 0.344383428E-01 4 0.832700527E+00 0.881341035E+00 0.918982946E+00 0.946429338E+00 0.965561657E+00 Component Mole fractions on stages: 46 to 47 1 0.445377720E-21 0.264744750E-21 2 0.141880352E-21 0.258716000E-21 3 0.215245956E-01 0.130000000E-01 4 0.978475405E+00 0.987000000E+00 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 21 to 25 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 26 to 30 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 31 to 35 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 36 to 40 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 41 to 45 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 46 to 47 1 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -3.763916325E+06 [Reboiler Heat Duty] 4.381765351E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.618897225E+01 0.610593592E+01 0.603120186E+01 0.596737257E+01 0.591272734E+01 2 0.517031299E+01 0.521819970E+01 0.526216435E+01 0.530357636E+01 0.534213059E+01 3 0.102803308E+01 0.103876096E+01 0.104894838E+01 0.105851126E+01 0.106740178E+01 4 0.747639290E+00 0.748590841E+00 0.749648450E+00 0.750886834E+00 0.752220187E+00 Component K-values on stages: 6 to 10 1 0.586584817E+01 0.582554978E+01 0.579083189E+01 0.576084573E+01 0.573486924E+01 2 0.537763026E+01 0.540998128E+01 0.543918092E+01 0.546530333E+01 0.548848328E+01 3 0.107559144E+01 0.108307071E+01 0.108984727E+01 0.109594335E+01 0.110139269E+01 4 0.753581962E+00 0.754922080E+00 0.756204413E+00 0.757404470E+00 0.758507234E+00 Component K-values on stages: 11 to 15 1 0.571228787E+01 0.569257880E+01 0.567529785E+01 0.566006817E+01 0.564657048E+01 2 0.550889985E+01 0.552676108E+01 0.554229076E+01 0.555571741E+01 0.556726592E+01 3 0.110623733E+01 0.111052462E+01 0.111430459E+01 0.111762776E+01 0.112054346E+01 4 0.759505162E+00 0.760396399E+00 0.761183217E+00 0.761870726E+00 0.762465827E+00 Component K-values on stages: 16 to 20 1 0.563453467E+01 0.562373249E+01 0.561397126E+01 0.560508844E+01 0.559694705E+01 2 0.557715140E+01 0.558557509E+01 0.559272198E+01 0.559875967E+01 0.560383824E+01 3 0.112309864E+01 0.112533706E+01 0.112729886E+01 0.112902029E+01 0.113053381E+01 4 0.762976411E+00 0.763410753E+00 0.763777087E+00 0.764083318E+00 0.764336839E+00 Component K-values on stages: 21 to 25 1 0.558943168E+01 0.558244517E+01 0.557590571E+01 0.556974447E+01 0.556390353E+01 2 0.560809076E+01 0.561163430E+01 0.561457115E+01 0.561699016E+01 0.561896818E+01 3 0.113186815E+01 0.113304857E+01 0.113409712E+01 0.113503297E+01 0.113587267E+01 4 0.764544430E+00 0.764712218E+00 0.764845669E+00 0.764949619E+00 0.765028307E+00 Component K-values on stages: 26 to 30 1 0.555833416E+01 0.555299540E+01 0.554430525E+01 0.553350629E+01 0.551987112E+01 2 0.562057140E+01 0.562185663E+01 0.562864226E+01 0.563912012E+01 0.565480826E+01 3 0.113663048E+01 0.113731865E+01 0.113919615E+01 0.114187185E+01 0.114567385E+01 4 0.765085430E+00 0.765124194E+00 0.765496549E+00 0.766098023E+00 0.767028325E+00 Component K-values on stages: 31 to 35 1 0.550250614E+01 0.548039944E+01 0.545256966E+01 0.541838701E+01 0.537812967E+01 2 0.567783444E+01 0.571116126E+01 0.575886007E+01 0.582639238E+01 0.592076526E+01 3 0.115106122E+01 0.115867180E+01 0.116937983E+01 0.118435473E+01 0.120509281E+01 4 0.768431935E+00 0.770518806E+00 0.773593055E+00 0.778089039E+00 0.784606407E+00 Component K-values on stages: 36 to 40 1 0.533373966E+01 0.528947424E+01 0.525175546E+01 0.522744315E+01 0.522073192E+01 2 0.605024476E+01 0.622305560E+01 0.644440980E+01 0.671193870E+01 0.701167419E+01 3 0.123335663E+01 0.127090324E+01 0.131886309E+01 0.137677735E+01 0.144172859E+01 4 0.793916874E+00 0.806883668E+00 0.824210679E+00 0.845992835E+00 0.871247963E+00 Component K-values on stages: 41 to 45 1 0.523065770E+01 0.525153478E+01 0.527612251E+01 0.529881878E+01 0.531685418E+01 2 0.731866911E+01 0.760439434E+01 0.784693352E+01 0.803689278E+01 0.817632127E+01 3 0.150842625E+01 0.157073973E+01 0.162388511E+01 0.166574593E+01 0.169669144E+01 4 0.897851098E+00 0.923158706E+00 0.944998616E+00 0.962316838E+00 0.975151355E+00 Component K-values on stages: 46 to 47 1 0.532973374E+01 0.533815090E+01 2 0.827374265E+01 0.833940124E+01 3 0.171852367E+01 0.173344463E+01 4 0.984193848E+00 0.990339635E+00 [Molecular weights] 1 74.079 2 32.042 3 74.123 4 116.158 [Feed stream 1] 27 Stage Number 4.9996433339136E-02 Flow rate 4.0195054426600E+02 Temperature [K] 4.3569750000000E+05 Pressure [Pa] -2.4869433183572E+07 Enthalpy [J/kmol] -5.4617774734964E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.5275134735505E-08 Mole fraction of component 1 1.0000000000013E-06 Mole fraction of component 2 6.0702595941266E-01 Mole fraction of component 3 3.9297302531220E-01 Mole fraction of component 4 4.9996433339136E-02 Flow rate 1.5275134735505E-08 Mole fraction of component 1 1.0000000000013E-06 Mole fraction of component 2 6.0702595941266E-01 Mole fraction of component 3 3.9297302531220E-01 Mole fraction of component 4 9.0641578576922E+01 Molar mass 7.4572633438561E+02 Density 3.1716767376148E-04 Viscosity 1.2355514852650E-01 Thermal conductivity 2.6396319040945E+05 Heat capacity 1.4896162026694E-02 Surface tension [Reflashed Feed stream 1] 27 Stage Number 4.9996433339136E-02 Flow rate 4.0195054426600E+02 Temperature [K] 4.3006833333333E+05 Pressure [Pa] -2.4869433183572E+07 Enthalpy [J/kmol] -5.4617774734964E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.5275134735505E-08 Mole fraction of component 1 1.0000000000013E-06 Mole fraction of component 2 6.0702595941266E-01 Mole fraction of component 3 3.9297302531220E-01 Mole fraction of component 4 4.9996433339136E-02 Flow rate 1.5275134735505E-08 Mole fraction of component 1 1.0000000000013E-06 Mole fraction of component 2 6.0702595941266E-01 Mole fraction of component 3 3.9297302531220E-01 Mole fraction of component 4 9.0641578576922E+01 Molar mass 7.4571957611954E+02 Density 3.1716767376148E-04 Viscosity 1.2355514852650E-01 Thermal conductivity 2.6396319040945E+05 Heat capacity 1.4896162026694E-02 Surface tension [Top product] 1 Stage Number 3.3482784714995E-02 Flow rate 4.3798693714202E+02 Temperature [K] 4.0530000000000E+05 Pressure [Pa] -1.8108680353385E+07 Enthalpy [J/kmol] -5.0519099350131E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.2808799855404E-08 Mole fraction of component 1 1.4931979602645E-06 Mole fraction of component 2 8.9999848397585E-01 Mole fraction of component 3 9.9999999998067E-02 Mole fraction of component 4 3.3482784714995E-02 Flow rate 2.2808799855404E-08 Mole fraction of component 1 1.4931979602645E-06 Mole fraction of component 2 8.9999848397585E-01 Mole fraction of component 3 9.9999999998067E-02 Mole fraction of component 4 7.8326437864122E+01 Molar mass 6.7163018074013E+02 Density 2.3261916302114E-04 Viscosity 1.2264128339823E-01 Thermal conductivity 2.8170519887418E+05 Heat capacity 1.1866624751454E-02 Surface tension [Bottom product] 47 Stage Number 1.6513648624140E-02 Flow rate 4.5972600378873E+02 Temperature [K] 4.4988300000000E+05 Pressure [Pa] -1.1629705947995E+06 Enthalpy [J/kmol] -1.1736383055290E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 2.6474475000000E-22 Mole fraction of component 1 2.5871600000000E-22 Mole fraction of component 2 1.3000000000510E-02 Mole fraction of component 3 9.8700000003868E-01 Mole fraction of component 4 1.6513648624140E-02 Flow rate 2.6474475000000E-22 Mole fraction of component 1 2.5871600000000E-22 Mole fraction of component 2 1.3000000000510E-02 Mole fraction of component 3 9.8700000003868E-01 Mole fraction of component 4 1.1561154218745E+02 Molar mass 7.0123580503742E+02 Density 1.7647927619214E-04 Viscosity 9.5429344059216E-02 Thermal conductivity 2.8858691146835E+05 Heat capacity 8.7147949971811E-03 Surface tension [Estimated NRTL Data] i j Aij Aji `ij 1 2 3.81456E+02 3.46536E+02 2.96500E-01 1 3 2.73191E+03 -3.46751E+02 2.00000E-01 1 4 2.71547E+03 -2.13639E+03 2.00000E-01 2 3 7.93817E+02 -4.86330E+02 2.48300E-01 2 4 3.28216E+02 4.53002E+02 2.96100E-01 3 4 6.61349E+02 -2.37641E+02 3.05600E-01 [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stage/X{~_{@'ve{@byl{@ofOs{@DҸ,y{@u~{@3[h{@Ln݈{@<*6V{@Ox{@L{@{٘{@XC%{@}@8{@2%{@̤{@I{(vY{@Eĩ{@iz?${@1TF{@`Dd{@o{@vj{@2mX{@U@+9{@J{@J2aݻ{@P6{@˗{@${@yBe{@ 2{@xUA{@{NzX{@v^{@;U{@;Fs`|@?K=(|@$31|@pSh*K|@^I e|@Vh{O||@@fg|@Z|@~2K|@{|@Y)|@"Pressure profile.Pressure at each stage/мAмA1JAԚA@AAg6 AA,)An4w8Affff"HA_LUWA;MDgA3333vA,e"AAA1~AԚAtAAgjAA`An4w AffffV0A_LU?A;MDLOA3333^A,e"BnA}A8A1AԚ-ĄA#AgAAAn4w AffffA_LU(A;MD7A3333FA,e"vVAeAluA(Vapour Flow profile4Vapour Flow at each stage/:˽@@ɿ;Y@Y@hq0Y@dY@XY@BY@ڢqMY@;\Y@M8Y@xGZ@AZ@kFZ@CZ@F@1Z@ ɸZ@*ȼ"Z@FN&Z@c~)Z@2Y,Z@F­q.Z@PI A1Z@4`3Z@(0S5Z@E7Z@/8Z@?mZ:Z@"q^@|V>y^@$^@D7^@w -^@鬻^@$.[F^@{9`^@d'_@."@(Kka@(Liquid Flow profile4Liquid Flow at each stage/4I8(Q@79Q@JLQ@}]Q@wQ3lQ@yQ@ȏ[Q@vQ@ ,Q@* aQ@"OЩQ@`Q@W̐,Q@NKQ@2ҿQ@HQ@D6hQ@趧Q@sQ@Q@%[Q@azQ@"\\>mQ@HS9Q@a8Q@e{tQ@Z-U@x@e:U@EU@p_OU@ rhWU@4ؙ^U@DdU@UBjU@HPnU@isU@{vU@UwEyU@kC|U@hHKU@?U@6U@]ʾU@9U@^K=U@V@"=V@HhV@>?V@IQ,{W@4X@Ӈ.oX@nY@a4cZ@镲[@q -[@5^I \@MJl\@ 0\@Q|\@.Vapour Density profile:Vapour Density at each stage/P}:3!@sV{k!@$}ZE!@j!@im"@1%@"@j"@p_"@) 0"@BD"@cAaP"@aۢ #@k{%#@֫<#@Q#@ee#@Gx#@/1#@ #@9% &#@] '#@]#@Z#@P#@#G#@ g#@+E $@vy$@1$@`YiR J$@Jig$@!>$@ɽ$@:$@A}˜.K%@&%@z1-&@מY&@]k'@s`(@!q(@Vo)@V )@5Fjb*@ܺ:*@S\U]*@:3P+@2Vapour Viscosity profile>Vapour Viscosity at each stage/%F >ӧ>Eo>E"+>uL>9^jP>c>KY>`N>o>+>M>r`>Iy>>>0i>5o>p =>p =>4f>]f>!>|r>@?>Pi>!K8>2As>S[>A8>AN2"6> ͣ>0>*>p٭>_{j>\V5/>5~>Vy6)f>1mJ>p|.> 쾋>n>g><2>!2>3u>=J>:Vapour Heat capacity profileFVapour Heat capacity at each stage//$ c@1ZDc@!uvc@ c@c@Dlc@'1d@Qkw,d@yX5Ed@.n\d@ݓod@-燎d@ld@:pΜd@HPd@ Oed@i|?d@%ud@=,Ԛd@sd@ecd@37d@Ǻd@b=yd@+ d@_Ld@Md@!rhd@Sd@( e@0*e@.n:e@tF_e@_ve@I +e@ h".f@ׁf@s)g@p= g@d]Kuh@ h" i@ZӺi@ F%uS@V?T@DUT@n/T@JhT@0U@Q5U\U@:MU@9dU@`TR'U@p_U@"U@x]`V@{ʄV@YwV@Q+V@5V@9z>V@W!'FV@yѩMV@"SV@fc]XV@:dw]V@aV@IQ,eV@3khV@ qV@]V@pΈޒV@odV@K=V@-W@PLW@`YiR W@yX@0{X@( NY@K7Y@jMZ@+ H[@q[@`TR'0\@H.y\@ŏ1w\@9m4\@B`"\@.Liquid Density profile:Liquid Density at each stage//L @c]@Y(@6@8@"E@CQ@ё\C[@Clgc@|a2U0j@A`o@w-!tt@?W[?x@@aS{@}@h|@7B@Clg@ǘ;@˃@B`"@QI@_)G@kw"@N@Ⴥ@J +@A@ 0@X21@I.!}@)Ǻ@}?5^:@YZ@@Tt$@@Ӽ@c=yɅ@ڬ\m؅@5^I @=y@On@镲@HP|@gj@jt@e@-C@2Liquid Viscosity profile>Liquid Viscosity at each stage/"|g}.?C/.?18+-?ZCD-?sb-?)0bt--?,?xg*,?Y.>,?I&֚,?P(p,?uDU,?Sr>,?!DHc),?g,?}T4,?Q=_+?w*9W/+?+?+?_4+?s:o+?NyA+?;+W+?UBU+?v+t+?+ +?DA{+? k+?N2W+?:)<>+?3s+?)*?i/*?/H~x*?c9$*?و)?1,T)?t(?8>Bv(?;(?r'?&@ '?޶d'?E'?&,*0'?dҤ!'?:Liquid Heat capacity profileFLiquid Heat capacity at each stage/:Hq@gffffq@)\q@Ciqq@Yڠq@V/q@Ciqq@ -q@46ٰq@a+eq@rhq@gsq@p_q@*Գq@Uq@X2ıq@jMq@Cq@uq@z6>Wq@j+q@46B?!&?JΉ=?տ?}uU?}?Gx?@eTt?Ҩ6p?CZfl?mh?N a?1qV? VG?9x&4?U^<?W֑~V?)ü? *?j /?]#Ȼ?kjP?\ͺ?"H?I >͹?sԏUc?ΐ"? и?YS袸?9Ϸ?F`n?0Surface tension profile<Surface tension at each stage/1ƆM?E~$?Pp?(!Ӈ?S?z??%1s?jY?1M}A?}4,?L?4'S?_i? %?Mt܆?06І?;qPņ?],o?gi?%?=Ԡ?5v[?{?HR?€gs?r75|?9[av?|l?3oY`? MQ?D>?0K&?U]?tΆۅ?BVP?]??l#?)?.찃?u=?ׂۣ?3}?^~+1C?d?B橒?!y!ف?Number of stagesNSi Feed1 stageF1Ni Reflux ratioRRoCondenser duty QCo?@@J/sReflux liquid flowrate RLo?kmol/hReboiler duty QRo?@@J/s 1 Converged 1 Iterations ChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_2F_~1.SEP Cape Open unit name: C3 Cape-Open unit id: CS_2F_10F8_1CCE133_6717B390 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties disabled Reading configuration Reading component property libraries Reading thermodynamic property options Reading physical property options Reading thermodynamic property data Warning! Estimating thermodynamic model parameters Ignoring all warnings User choice: Ignore Reading specifications Reading reaction data Checking Component Data 79-20-9 Methyl acetate 67-56-1 Methanol 71-36-3 1-butanol 123-86-4 N-butyl acetate * No class * Missing STboil * Missing Cp gas 1 Determining feed conditions Solving TP flash Possible trivial solution Run level: Initialization Reading initial temperature profiles Reading initial composition profiles Init 79 milliseconds Run level: Complete model Iteration log(Err/Tol) 0 0.9284 1 -1.9057 Run level: Report Convergence obtained in 1 iterations Time 46 milliseconds FixMem driver done run time: 0.2 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe CAPE-OPEN thermo-properties were disabled. All calculation methods have been determined by ChemSep. See output report or graphical user interface for more information. ,W not all ports are connectedFeed1{split}_stage27 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@@*@C2ChemSep Unit OperationqeWCXcCSUOŽ[ChemSep] Version=6.90 Compiled=2012-1-31 20:40 41769b34bc6e Name=C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_30_~1.sep Title=ChemSep CO Unit Operation "Column" in COFE Flowsheet User=Harry Date=2012-02-01 Time=23:47:14 [Cape-Open] unitname=Column CO_ID=CS_33_1244_1CCE133_7498BB90 4 components Methyl acetate 79-20-9 74.0790023804 Mw Methanol 67-56-1 32.0419998169 Mw 1-butanol 71-36-3 74.1230010986 Mw N-butyl acetate 123-86-4 116.157997131 Mw 1 thermo exe=C:\Program Files\ChemSepL6v90\bin\co-col2.exe mode=COFE NoWarnings=TRUE WilsonEstimate=TRUE Status= 1 Converged, 1 Iterations 0 only K-values and ethalpies 0 use only perturbed derivative 0 use only perturbed mole derivative 0.001 relative T perturbation 0.001 relative P perturbation 0.001 X perturbation 0 write all values to log 1 use initial guess 0 inlet reflash 0 outlet reflash 0 expose energy ports 0 clear log 0 update icon CO Thermo Version=Auto 2 number of run levels normal simplified 1 current run level [Paths] Device drivers path=c:\program files\chemsepl6v90\bin\ Help and Info path=c:\program files\chemsepl6v90\help\ Component data path=c:\program files\chemsepl6v90\pcd\ Property data path=c:\program files\chemsepl6v90\ipd\ Section data path=c:\program files\chemsepl6v90\ild\ Executables path=C:\Program Files\ChemSepL6v90\bin\ Temporary path=C:\DOCUME~1\Harry\LOCALS~1\Temp\ Scripts path=c:\program files\chemsepl6v90\bin\ [Units] Temperature=K Flow=mol/s Mass flow=kg/s Pressure=atm Heat=MW Enthalpy=kJ/kmol Entropy=J/kmol/K Fraction=_ Length=m 1/Length=1/m Area=m2 Volume=m3 Mass=kg Angle=deg Velocity=m/s Surface tension=dyn/cm Density=kg/m3 Molar density=kmol/m3 Viscosity=Pa.s Molecular weight=kg/kmol Heat capacity=J/kmol/K Thermal conductivity=J/s/m/K Diffusivity=1e-8 m2/s Interaction parameter=J/mol Time=s [Components] 4 64 1312 Library Offset, Index DT=2012-01-31,09:17:24 CHK=52947 CAS=79-20-9 CID=Methyl acetate Name=Methyl acetate Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 1101 Library Offset, Index DT=2012-01-31,09:17:24 CHK=37880 CAS=67-56-1 CID=Methanol Name=Methanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 94 1105 Library Offset, Index DT=2012-01-31,09:17:24 CHK=53304 CAS=71-36-3 CID=1-butanol Name=1-butanol Lib=c:\program files\chemsepl6v90\pcd\chemsep1.pcd 1 1315 Library Offset, Index DT=2010-11-11,13:28:14 CHK=61714 CAS=123-86-4 CID=N-butyl acetate Name=N-butyl acetate Lib=h:\chemsep\documents\case_stories\flowsheets\butyl acetate\butylacetate.pcd [Operation] 2 Operation Column 1 Operation kind Simple Distillation 1 Condenser Total (Liquid product) 1 Reboiler Partial (Liquid product) 27 Stages 1 Feed stages 0 Sidestream stages F=18 S= 0 Pumparound stages P= [Properties] 350 BIP estimation temperature [Thermodynamics] 4 K model DECHEMA 6 1 Activity coefficient NRTL * Wilson model * * UNIQUAC model * * Equation of State * * Cubic EOS * * Virial EOS * 3 Vapour pressure T correlation 0 Henry's law * Henry's default * [Enthalpy] 3 Enthalpy Excess 1 Enthalpy reference state Vapour 298.15 Enthalpy reference temperature 1 Formation enthalpies Excluded 298.15 Exergy surroundings temperature [Physical property models] 0 No Check T range * Cubic EOS * * Virial EOS * * Vapour model * * Liquid mixture density * * Liquid component density * * Vapour mixture viscosity * * Vapour mixture viscosity pressure correction * * Vapour component viscosity * * Liquid mixture viscosity * * Liquid component viscosity * Vapour mixture Cp * Vapour component Cp * Liquid mixture Cp * Liquid component Cp * Vapour mixture conductivity * * Vapour component conductivity * * Liquid mixture conductivity * * Liquid component conductivity * Mixture surface tension * * Component surface tension * * Vignes MS D-model * * D mixture model * * Vapour Diffusion Coefficients * [Property Data] [NRTL Data] i j Aij Aji aij Component Component 1 2 1596.011 1449.907 0.2965 Methyl acetate/Methanol 1 3 * * * Methyl acetate/1-butanol 1 4 * * * Methyl acetate/N-butyl acetate 2 3 3321.332 -2034.804 0.2483 Methanol/1-butanol 2 4 1373.256 1895.359 0.2961 Methanol/N-butyl acetate 3 4 * * * 1-butanol/N-butyl acetate [Reaction data] 0 Number of reactions [Specifications] Top Bottom [Heaters/Coolers] 0 Number 0 Column duty Qcolumn 2 First stage 26 Last stage 0 Qcolumn lost to surroundings [Efficiencies] 1 Default efficiency 0 Number [Pressures] 2 Column pressure Bottom & top pressures 111457.5 Condenser pressure 111457.5 Top pressure * Pressure Drop 135775.5 Bottom pressure [Feeds] 1 Number 1 Feed state T & p 18 Stage Feed1{split} 333.094963055 Temperature 121590 Pressure 0 Vapour fraction 4 componentflows 0.0273866138109 Component 1 flow 0.0426133694987 Component 2 flow 7.00035666607e-008 Component 3 flow 3.5133475517e-006 Component 4 flow [Condenser] 7 Type Mole fraction of a component 0.64 Value Qcondenser 1 1st comp. * Type * * Initialization guess [Reboiler] 7 Type Mole fraction of a component 0.013 Value Qreboiler 1 1st comp. * Type * * Initialization guess [Monitored Variables] * [Solve options] 3 Initialization Old Results 1 Method Newton's method 0.5 Flow Step limit 10 Temperature Step limit 1 Composition Step limit 1 Flux Step limit 0.000001 Accuracy 30 Maximum iterations 1 Iteration count & function vector 0 T/V/L profiles 0 X/Y profiles 0 Variable and function vectors 0 Jacobian 1 History Screen History file= 1 Feeds type Stage below 1 Interactive 0 Log thermodynamics 0 Log enthalpy/entropy 0 Log physical properties 0 Log timing 0 CO numeric differencing 0 Log from iteration 0 CS K-value 0 CS enthalpy 0 CS entropy 0 CS flash 0 CS activity coefficient 0 CS vapor pressuure 0 CS density 0 CS viscosity 0 CS thermal conductivity 0 CS heat capacity 0 CS surface tension 0 CS diffusivity [Programs] Temporary file=SCRATCH.TMP User program= 8 DOS extender NT 1 Show windows Hidden [FlowSheet] [CoCo] [Settings] ComboBox=ComboBox14 -1 ComboBox=ComboBox20 -1 ComboBox=ComboBox21 -1 CheckBox=CheckBox3 0 Show settings CheckBox=CheckBox1 1 Auto colors CheckBox=CheckBox2 1 Auto points Edit=Edit9 0.2 StringGrid=StringGrid5 2 8 Title Labels Stages Axis color Commands Box Labels box Import data Liquid phase composition profiles On Vertical Black set label "ChemSep" at 1,1.58 right On Off StringGrid=StringGrid4 5 9 Title Start End Tic interval Small tics Grid Logarithmic Scientific notation x1 Liquid mole fraction 0 1 0.2 0 Off Off Off y1 Stage 30 1 5 0 Off Off Off x2 0 Off Off Off y2 0 Off Off Off StringGrid=StringGrid3 5 14 Label Plot X Plot Y X axis Y axis Units X Units Y Color Points Thickness Style 1st stage Last stage 1 Methyl acetate X1 S x1 y1 _ Red Diamond Normal Solid 1 30 2 Methanol X2 S x1 y1 _ Green + Normal Solid 1 30 3 1-butanol X3 S x1 y1 _ Blue Square Normal Solid 1 30 4 N-butyl acetate X4 S x1 y1 _ Magenta x Normal Solid 1 30 CheckBox=CheckBox10 0 Show settings ComboBox=ComboBox22 0 ComboBox=ComboBox23 1 StringGrid=StringGrid7 16 2 Title McCabe-Thiele diagram Methyl acetate - Methanol Xlabel X Methyl acetate/(Methyl acetate+Methanol) Ylabel Y Methyl acetate/(Methyl acetate+Methanol) X interval 0.2 Y interval 0.2 X min 0 X max 1 Y min 0 Y max 1 X tics 0 Y tics 0 Axis color Black Grid Off y Fractions Vertical Commands set label "ChemSep" at 1,0.02 right Stage numbers On StringGrid=StringGrid11 5 3 CheckBox=CheckBox45 0 Lumped ComboBox=ComboBox75 1 ComboBox=ComboBox76 2 ComboBox=ComboBox77 0 Edit=Edit55 0.95 Edit=Edit56 0.95 Edit=Edit57 1.2 Edit=Edit1 1 CheckBox=CheckBox2 0 Use old results CheckBox=CheckBox3 1 Automatic CheckBox=CheckBox1 0 Keep sep-files CheckBox=CheckBox4 1 Restore original StringGrid=StringGrid1 1 6 Name Variable Units Value Start/Valuelist End StringGrid=StringGrid2 4 1 Name Variable Units Current Value StringGrid=StringGrid3 1 1 None ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Title ComboBox=ComboBox4 0 ComboBox=ComboBox15 0 Edit=Edit17 Plot font CheckBox=CheckBox2 1 Color=Edit18 1241641 SpinEdit=SpinEdit1 1 CheckBox=CheckBox2 1 Color=Edit19 1241641 Edit=Edit5 StringGrid=StringGrid2 7 2 StringGrid=StringGrid3 7 2 StringGrid=StringGrid4 7 2 Color=BVLEbplineColor 1241641 SpinEdit=SpinEdit2 1 ComboBox=ComboBox13 0 Color=BVLEdplineColor 1241641 SpinEdit=SpinEdit3 1 ComboBox=ComboBox14 0 RadioButton=RadioButton3 TRUE DrawSetColors=BVLEcolors 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ComboBox=ComboBox7 -1 ComboBox=ComboBox11 -1 ComboBox=ComboBox6 -1 Memo=Memo1 Memo1, ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox4 0 Edit=Edit1 Edit=Edit2 21 Edit=Edit3 Ternary Phase Diagram Edit=Edit4 18 Edit=Edit6 Edit=Edit7 chemsep1.pcd Edit=Edit8 Edit=Edit5 StringGrid=StringGrid1 5 7 Identifier L# File Loc. CAS SMILES Name Methyl acetate 1312 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 64 79-20-9 CC(=O)OC Methyl acetate Methanol 1101 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 32 67-56-1 CO Methanol 1-butanol 1105 c:\program files\chemsepl6v90\pcd\chemsep1.pcd 94 71-36-3 CCCCO 1-butanol N-butyl acetate 1315 h:\chemsep\documents\case_stories\flowsheets\butyl acetate\butylacetate.pcd 1 123-86-4 N-butyl acetate 0 0 ComboBox=ComboBox1 -1 ComboBox=ComboBox2 -1 ComboBox=ComboBox3 -1 Edit=Edit1 Edit=Edit2 Edit=Edit3 21 Edit=Edit4 Binary Property Diagram Memo=Memo1 StringGrid=StringGrid1 13 4 Axis Left Right X/Y Property -click to select- -click to select- x Title x Units - Minimum 0 Maximum 1 Interval 0.2 Grid Off Off Off Log Off Off Off Color Blue Red Black Line Normal Normal Style Solid Solid Point None None Edit=Edit5 ComboBox=ComboBox7 -1 ComboBox=ComboBox6 -1 [End Settings] [End of Input] [Results] 1 Converged 1 Iterations [Profiles] Stage Temperature Pressure Vapour Flow Liquid Flow Duties 1 329.3526846 1.114575000E+05 4.222738030E-02 4.736074942E-02 -2.856982681E+06 2 329.3699546 1.114575000E+05 8.958812972E-02 4.717040328E-02 0.000000000E+00 3 329.6307614 1.124302200E+05 8.939778357E-02 4.702524302E-02 0.000000000E+00 4 329.9003013 1.134029400E+05 8.925262332E-02 4.687429147E-02 0.000000000E+00 5 330.1797046 1.143756600E+05 8.910167176E-02 4.671588339E-02 0.000000000E+00 6 330.4703678 1.153483800E+05 8.894326368E-02 4.654907975E-02 0.000000000E+00 7 330.7736403 1.163211000E+05 8.877646005E-02 4.637401022E-02 0.000000000E+00 8 331.0903556 1.172938200E+05 8.860139051E-02 4.619227301E-02 0.000000000E+00 9 331.4202134 1.182665400E+05 8.841965331E-02 4.600722774E-02 0.000000000E+00 10 331.7611492 1.192392600E+05 8.823460803E-02 4.582394538E-02 0.000000000E+00 11 332.1089802 1.202119800E+05 8.805132567E-02 4.564861666E-02 0.000000000E+00 12 332.4576543 1.211847000E+05 8.787599695E-02 4.548746836E-02 0.000000000E+00 13 332.8002173 1.221574200E+05 8.771484866E-02 4.534553956E-02 0.000000000E+00 14 333.1302022 1.231301400E+05 8.757291985E-02 4.522580872E-02 0.000000000E+00 15 333.4428645 1.241028600E+05 8.745318902E-02 4.512897242E-02 0.000000000E+00 16 333.7357954 1.250755800E+05 8.735635271E-02 4.505381384E-02 0.000000000E+00 17 334.0088637 1.260483000E+05 8.728119414E-02 4.499783420E-02 0.000000000E+00 18 334.2652857 1.270210200E+05 6.416610134E-02 9.190593475E-02 0.000000000E+00 19 334.5252688 1.279937400E+05 6.412974838E-02 9.186233978E-02 0.000000000E+00 20 334.8447044 1.289664600E+05 6.408615341E-02 9.172252758E-02 0.000000000E+00 21 335.2976189 1.299391800E+05 6.394634121E-02 9.139523991E-02 0.000000000E+00 22 336.0374573 1.309119000E+05 6.361905355E-02 9.076520519E-02 0.000000000E+00 23 337.3125801 1.318846200E+05 6.298901883E-02 8.983153665E-02 0.000000000E+00 24 339.2652654 1.328573400E+05 6.205535029E-02 8.888720007E-02 0.000000000E+00 25 341.5111550 1.338300600E+05 6.111101370E-02 8.827418053E-02 0.000000000E+00 26 343.3649846 1.348027800E+05 6.049799417E-02 8.800522414E-02 0.000000000E+00 27 344.5669790 1.357755000E+05 6.022903777E-02 2.777618636E-02 2.098971483E+06 [Enthalpies/Entropies] Stage Vap.Enthalpy Liq.Enthalpy Vap.Entropy Liq.Entropy 1 -0.2960268E+08 -0.2960268E+08 -0.9006579E+05 -0.9006579E+05 2 0.2287512E+07 -0.2972082E+08 0.1193313E+05 -0.9039726E+05 3 0.2293078E+07 -0.2980846E+08 0.1192287E+05 -0.9065348E+05 4 0.2298969E+07 -0.2990030E+08 0.1191067E+05 -0.9092937E+05 5 0.2305049E+07 -0.2999769E+08 0.1189657E+05 -0.9122931E+05 6 0.2311255E+07 -0.3010139E+08 0.1188048E+05 -0.9155625E+05 7 0.2317586E+07 -0.3021133E+08 0.1186221E+05 -0.9191073E+05 8 0.2324100E+07 -0.3032633E+08 0.1184148E+05 -0.9228975E+05 9 0.2330896E+07 -0.3044386E+08 0.1181799E+05 -0.9268578E+05 10 0.2338101E+07 -0.3056010E+08 0.1179155E+05 -0.9308640E+05 11 0.2345846E+07 -0.3067033E+08 0.1176220E+05 -0.9347545E+05 12 0.2354235E+07 -0.3076978E+08 0.1173033E+05 -0.9383547E+05 13 0.2363335E+07 -0.3085450E+08 0.1169670E+05 -0.9415108E+05 14 0.2373166E+07 -0.3092209E+08 0.1166232E+05 -0.9441172E+05 15 0.2383704E+07 -0.3097189E+08 0.1162823E+05 -0.9461288E+05 16 0.2394898E+07 -0.3100473E+08 0.1159534E+05 -0.9475553E+05 17 0.2406679E+07 -0.3102239E+08 0.1156431E+05 -0.9484413E+05 18 0.2418940E+07 -0.3102813E+08 0.1153544E+05 -0.9488807E+05 19 0.2430841E+07 -0.3103718E+08 0.1150491E+05 -0.9494779E+05 20 0.2440640E+07 -0.3108427E+08 0.1146440E+05 -0.9514806E+05 21 0.2446291E+07 -0.3120567E+08 0.1139866E+05 -0.9562995E+05 22 0.2444386E+07 -0.3144956E+08 0.1126566E+05 -0.9660395E+05 23 0.2429522E+07 -0.3182728E+08 0.1095046E+05 -0.9820515E+05 24 0.2392469E+07 -0.3223468E+08 0.1021658E+05 -0.1001712E+06 25 0.2328684E+07 -0.3252229E+08 0.8893691E+04 -0.1019140E+06 26 0.2259256E+07 -0.3266177E+08 0.7274864E+04 -0.1031045E+06 27 0.2210763E+07 -0.3271102E+08 0.5873621E+04 -0.1037916E+06 [Vapour Properties] Stage Moleweight Density Viscosity Heat capacity Thermal conductivity 1 0.5936776E+02 0.2416511E+01 0.9437691E-05 0.7603685E+05 0.1568822E-01 2 0.5894568E+02 0.2399205E+01 0.9455772E-05 0.7558081E+05 0.1573449E-01 3 0.5851396E+02 0.2400517E+01 0.9481959E-05 0.7515006E+05 0.1580408E-01 4 0.5807940E+02 0.2401340E+01 0.9508648E-05 0.7471683E+05 0.1587485E-01 5 0.5763588E+02 0.2401409E+01 0.9536133E-05 0.7427461E+05 0.1594754E-01 6 0.5717911E+02 0.2400526E+01 0.9564651E-05 0.7381885E+05 0.1602276E-01 7 0.5670700E+02 0.2398580E+01 0.9594345E-05 0.7334738E+05 0.1610085E-01 8 0.5622037E+02 0.2395589E+01 0.9625219E-05 0.7286113E+05 0.1618182E-01 9 0.5572377E+02 0.2391737E+01 0.9657080E-05 0.7236493E+05 0.1626516E-01 10 0.5522593E+02 0.2387409E+01 0.9689493E-05 0.7186796E+05 0.1634979E-01 11 0.5473942E+02 0.2383182E+01 0.9721779E-05 0.7138335E+05 0.1643399E-01 12 0.5427908E+02 0.2379764E+01 0.9753083E-05 0.7092656E+05 0.1651562E-01 13 0.5385950E+02 0.2377872E+01 0.9782520E-05 0.7051272E+05 0.1659251E-01 14 0.5349214E+02 0.2378101E+01 0.9809345E-05 0.7015371E+05 0.1666281E-01 15 0.5318350E+02 0.2380824E+01 0.9833085E-05 0.6985621E+05 0.1672537E-01 16 0.5293459E+02 0.2386158E+01 0.9853582E-05 0.6962125E+05 0.1677983E-01 17 0.5274197E+02 0.2394007E+01 0.9870960E-05 0.6944521E+05 0.1682652E-01 18 0.5259522E+02 0.2403923E+01 0.9885769E-05 0.6931727E+05 0.1686683E-01 19 0.5243460E+02 0.2413058E+01 0.9901338E-05 0.6917420E+05 0.1690899E-01 20 0.5211487E+02 0.2414265E+01 0.9926033E-05 0.6886320E+05 0.1697384E-01 21 0.5145945E+02 0.2398639E+01 0.9970376E-05 0.6819821E+05 0.1708735E-01 22 0.5014304E+02 0.2349590E+01 0.1005473E-04 0.6683654E+05 0.1729937E-01 23 0.4771210E+02 0.2243779E+01 0.1021014E-04 0.6429686E+05 0.1768394E-01 24 0.4395908E+02 0.2070545E+01 0.1045599E-04 0.6033975E+05 0.1828203E-01 25 0.3961086E+02 0.1867037E+01 0.1074960E-04 0.5570176E+05 0.1898390E-01 26 0.3600826E+02 0.1700337E+01 0.1099950E-04 0.5181696E+05 0.1957444E-01 27 0.3376122E+02 0.1600132E+01 0.1115964E-04 0.4937898E+05 0.1995279E-01 [Liquid Properties] Stage Moleweight Density Viscosity Heat capacity Thermal cond. Surface tension 1 0.5894568E+02 0.8707235E+03 0.3024516E-03 0.1289556E+06 0.1613217E+00 0.2030761E-01 2 0.5812749E+02 0.8695045E+03 0.3043796E-03 0.1277206E+06 0.1622981E+00 0.2028446E-01 3 0.5730150E+02 0.8678447E+03 0.3056036E-03 0.1265390E+06 0.1631941E+00 0.2023479E-01 4 0.5645593E+02 0.8660510E+03 0.3068508E-03 0.1253299E+06 0.1641122E+00 0.2018405E-01 5 0.5558228E+02 0.8640967E+03 0.3081387E-03 0.1240809E+06 0.1650623E+00 0.2013192E-01 6 0.5467616E+02 0.8619574E+03 0.3094741E-03 0.1227856E+06 0.1660495E+00 0.2007820E-01 7 0.5373875E+02 0.8596173E+03 0.3108499E-03 0.1214462E+06 0.1670719E+00 0.2002281E-01 8 0.5277841E+02 0.8570763E+03 0.3122433E-03 0.1200756E+06 0.1681196E+00 0.1996592E-01 9 0.5181179E+02 0.8543595E+03 0.3136137E-03 0.1186990E+06 0.1691727E+00 0.1990803E-01 10 0.5086329E+02 0.8515235E+03 0.3149064E-03 0.1173528E+06 0.1702025E+00 0.1984995E-01 11 0.4996223E+02 0.8486567E+03 0.3160606E-03 0.1160803E+06 0.1711750E+00 0.1979283E-01 12 0.4913784E+02 0.8458679E+03 0.3170211E-03 0.1149244E+06 0.1720567E+00 0.1973792E-01 13 0.4841362E+02 0.8432668E+03 0.3177502E-03 0.1139187E+06 0.1728210E+00 0.1968640E-01 14 0.4780335E+02 0.8409420E+03 0.3182332E-03 0.1130824E+06 0.1734528E+00 0.1963914E-01 15 0.4730999E+02 0.8389468E+03 0.3184777E-03 0.1124187E+06 0.1739496E+00 0.1959658E-01 16 0.4692745E+02 0.8372969E+03 0.3185072E-03 0.1119178E+06 0.1743191E+00 0.1955870E-01 17 0.4664410E+02 0.8359775E+03 0.3183534E-03 0.1115620E+06 0.1745752E+00 0.1952516E-01 18 0.4643987E+02 0.8349320E+03 0.3180610E-03 0.1113223E+06 0.1747416E+00 0.1949512E-01 19 0.4621398E+02 0.8338010E+03 0.3178032E-03 0.1110501E+06 0.1749326E+00 0.1946434E-01 20 0.4574804E+02 0.8317391E+03 0.3179556E-03 0.1104303E+06 0.1753983E+00 0.1942261E-01 21 0.4481125E+02 0.8277216E+03 0.3188584E-03 0.1091335E+06 0.1763990E+00 0.1935803E-01 22 0.4308722E+02 0.8199574E+03 0.3208172E-03 0.1067228E+06 0.1782790E+00 0.1925000E-01 23 0.4044658E+02 0.8065034E+03 0.3233687E-03 0.1030726E+06 0.1811356E+00 0.1907487E-01 24 0.3741981E+02 0.7881406E+03 0.3246774E-03 0.9903271E+05 0.1843010E+00 0.1883471E-01 25 0.3493558E+02 0.7701621E+03 0.3234617E-03 0.9591060E+05 0.1867548E+00 0.1858510E-01 26 0.3339447E+02 0.7573771E+03 0.3210134E-03 0.9411702E+05 0.1881745E+00 0.1839222E-01 27 0.3259923E+02 0.7501292E+03 0.3188598E-03 0.9326980E+05 0.1888523E+00 0.1827190E-01 [Vapour phase compositions] Component Mole fractions on stages: 1 to 5 1 0.650040652E+00 0.640000000E+00 0.629730058E+00 0.619392378E+00 0.608841772E+00 2 0.349959348E+00 0.360000000E+00 0.370269942E+00 0.380607622E+00 0.391158228E+00 3 0.106035322E-18 0.933195024E-18 0.484705883E-17 0.235923351E-16 0.114264457E-15 4 0.177784032E-17 0.214398659E-16 0.144661613E-15 0.900787176E-15 0.544215114E-14 Component Mole fractions on stages: 6 to 10 1 0.597975858E+00 0.586744916E+00 0.575168741E+00 0.563355391E+00 0.551512520E+00 2 0.402024142E+00 0.413255084E+00 0.424831259E+00 0.436644609E+00 0.448487480E+00 3 0.556610663E-15 0.272971351E-14 0.134619794E-13 0.666417232E-13 0.330459273E-12 4 0.320887362E-13 0.184475949E-12 0.103175625E-11 0.560095514E-11 0.294538439E-10 Component Mole fractions on stages: 11 to 15 1 0.539939025E+00 0.528988309E+00 0.519006931E+00 0.510268143E+00 0.502925822E+00 2 0.460060974E+00 0.471011691E+00 0.480993066E+00 0.489731841E+00 0.497074104E+00 3 0.163783968E-11 0.809674675E-11 0.398567184E-10 0.195145587E-09 0.949872788E-09 4 0.149862557E-09 0.737688052E-09 0.351729134E-08 0.162849996E-07 0.734736580E-07 Component Mole fractions on stages: 16 to 20 1 0.497004135E+00 0.492419853E+00 0.488921294E+00 0.485100233E+00 0.477494130E+00 2 0.502995537E+00 0.507578718E+00 0.511073521E+00 0.514894511E+00 0.522500468E+00 3 0.459663883E-08 0.221244961E-07 0.891049670E-07 0.895590426E-07 0.904030722E-07 4 0.324344337E-06 0.140679395E-05 0.509590344E-05 0.516631258E-05 0.531143142E-05 Component Mole fractions on stages: 21 to 25 1 0.461902033E+00 0.430585191E+00 0.372753878E+00 0.283470583E+00 0.180026428E+00 2 0.538092254E+00 0.569408435E+00 0.627238448E+00 0.716519560E+00 0.819960570E+00 3 0.921906466E-07 0.962045773E-07 0.104758960E-06 0.119864903E-06 0.141513334E-06 4 0.562117150E-05 0.627704079E-05 0.756865489E-05 0.973683901E-05 0.128598231E-04 Component Mole fractions on stages: 26 to 27 1 0.943141516E-01 0.408202390E-01 2 0.905667030E+00 0.959140826E+00 3 0.187427924E-06 0.453218548E-06 4 0.186306926E-04 0.384814603E-04 [Liquid phase compositions] Component Mole fractions on stages: 1 to 5 1 0.640000000E+00 0.620536311E+00 0.600887298E+00 0.580772434E+00 0.559989432E+00 2 0.360000000E+00 0.379463689E+00 0.399112702E+00 0.419227566E+00 0.440010568E+00 3 0.933195024E-18 0.835071656E-17 0.439391194E-16 0.216358191E-15 0.105888655E-14 4 0.214398659E-16 0.254968785E-15 0.169040313E-14 0.103253771E-13 0.610743799E-13 Component Mole fractions on stages: 6 to 10 1 0.538434130E+00 0.516134505E+00 0.493289537E+00 0.470294966E+00 0.447731495E+00 2 0.461565870E+00 0.483865494E+00 0.506710463E+00 0.529705034E+00 0.552268505E+00 3 0.520509160E-14 0.257191000E-13 0.127561249E-12 0.633762333E-12 0.314710264E-11 4 0.351801894E-12 0.197121721E-11 0.107210461E-10 0.564873617E-10 0.287960644E-09 Component Mole fractions on stages: 11 to 15 1 0.426296634E+00 0.406685438E+00 0.389457220E+00 0.374939532E+00 0.363202267E+00 2 0.573703365E+00 0.593314556E+00 0.610542748E+00 0.625060324E+00 0.636797096E+00 3 0.155865073E-10 0.768562431E-10 0.376868354E-09 0.183675102E-08 0.889765708E-08 4 0.142007561E-08 0.678244598E-08 0.314498902E-07 0.142074771E-06 0.627829891E-06 Component Mole fractions on stages: 16 to 20 1 0.354098088E+00 0.347339515E+00 0.342420181E+00 0.337046205E+00 0.325961753E+00 2 0.645899143E+00 0.652648612E+00 0.657537154E+00 0.662911010E+00 0.673995188E+00 3 0.428605794E-07 0.205441271E-06 0.824357617E-06 0.825295323E-06 0.827661052E-06 4 0.272530805E-05 0.116671101E-04 0.418405791E-04 0.419592274E-04 0.422309903E-04 Component Mole fractions on stages: 21 to 25 1 0.303675698E+00 0.262661137E+00 0.199840254E+00 0.127832671E+00 0.687279965E-01 2 0.696280651E+00 0.737294051E+00 0.800113039E+00 0.872118069E+00 0.931218505E+00 3 0.833087919E-06 0.844138673E-06 0.862257025E-06 0.885025989E-06 0.921654760E-06 4 0.428185743E-04 0.439685072E-04 0.458444817E-04 0.483750155E-04 0.525764514E-04 Component Mole fractions on stages: 26 to 27 1 0.320396230E-01 0.130000000E-01 2 0.967893006E+00 0.986870981E+00 3 0.110578918E-05 0.252051668E-05 4 0.662649096E-04 0.126498741E-03 [Reaction rates] Component reaction rates on stages: 1 to 5 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 6 to 10 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 11 to 15 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 16 to 20 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 21 to 25 1 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 0.000000000E+00 Component reaction rates on stages: 26 to 27 1 0.000000000E+00 0.000000000E+00 2 0.000000000E+00 0.000000000E+00 3 0.000000000E+00 0.000000000E+00 4 0.000000000E+00 0.000000000E+00 [Condenser Heat Duty] -2.856982681E+06 [Reboiler Heat Duty] 2.098971483E+06 [UA Column] 0.000000000E+00 [K-values] Component K-values on stages: 1 to 5 1 0.101568852E+01 0.103136591E+01 0.104800028E+01 0.106649755E+01 0.108723797E+01 2 0.972109299E+00 0.948707374E+00 0.927732793E+00 0.907878328E+00 0.888974620E+00 3 0.113626038E+00 0.111750105E+00 0.110317054E+00 0.109039210E+00 0.107909737E+00 4 0.829221274E-01 0.840875589E-01 0.855782143E-01 0.872401237E-01 0.891068702E-01 Component K-values on stages: 6 to 10 1 0.111058312E+01 0.113680622E+01 0.116598609E+01 0.119787672E+01 0.123179299E+01 2 0.871000583E+00 0.854070166E+00 0.838410276E+00 0.824316516E+00 0.812082305E+00 3 0.106935822E+00 0.106135631E+00 0.105533523E+00 0.105152494E+00 0.105004402E+00 4 0.912122351E-01 0.935842674E-01 0.962359490E-01 0.991531569E-01 0.102283232E+00 Component K-values on stages: 11 to 15 1 0.126658055E+01 0.130073088E+01 0.133264170E+01 0.136093449E+01 0.138469901E+01 2 0.801914373E+00 0.793865051E+00 0.787812265E+00 0.783495323E+00 0.780584750E+00 3 0.105080870E+00 0.105349372E+00 0.105757593E+00 0.106244813E+00 0.106754993E+00 4 0.105530199E+00 0.108762746E+00 0.111836063E+00 0.114620538E+00 0.117025510E+00 Component K-values on stages: 16 to 20 1 0.140357757E+01 0.141769027E+01 0.142784019E+01 0.143926925E+01 0.146487779E+01 2 0.778752443E+00 0.777721288E+00 0.777254217E+00 0.776717398E+00 0.775228788E+00 3 0.107246036E+00 0.107693069E+00 0.108093150E+00 0.108520360E+00 0.109229930E+00 4 0.119009272E+00 0.120574402E+00 0.121787795E+00 0.123121473E+00 0.125765771E+00 Component K-values on stages: 21 to 25 1 0.152103721E+01 0.163931826E+01 0.186525925E+01 0.221751283E+01 0.261940462E+01 2 0.772809440E+00 0.772294910E+00 0.783937302E+00 0.821585516E+00 0.880524367E+00 3 0.110664329E+00 0.113970921E+00 0.121497271E+00 0.135441129E+00 0.153546407E+00 4 0.131274605E+00 0.142759230E+00 0.165092384E+00 0.201278005E+00 0.244589618E+00 Component K-values on stages: 26 to 27 1 0.294367241E+01 0.314001854E+01 2 0.935709878E+00 0.971900963E+00 3 0.169498793E+00 0.179810401E+00 4 0.281144034E+00 0.304173490E+00 [Molecular weights] 1 74.079 2 32.042 3 74.123 4 116.158 [Feed stream 1] 18 Stage Number 7.0003566660718E-02 Flow rate 3.3309496305500E+02 Temperature [K] 1.2159000000000E+05 Pressure [Pa] -2.0007833449096E+07 Enthalpy [J/kmol] -8.3641336332321E+04 Entropy [J/kmol/K] 3.3339410594012E-01 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 3.9121740673062E-01 Mole fraction of component 1 6.0873140514727E-01 Mole fraction of component 2 9.9999999999974E-07 Mole fraction of component 3 5.0188122109948E-05 Mole fraction of component 4 2.3338776519470E-02 Flow rate 4.9065513408377E-01 Mole fraction of component 1 5.0933612672752E-01 Mole fraction of component 2 1.5229443383557E-07 Mole fraction of component 3 8.5868942807076E-06 Mole fraction of component 4 4.6664790141248E-02 Flow rate 3.4148494486202E-01 Mole fraction of component 1 6.5844263674425E-01 Mole fraction of component 2 1.4239687075239E-06 Mole fraction of component 3 7.0994425027116E-05 Mole fraction of component 4 5.2668399650035E+01 Molar mass 2.3124369227357E+00 Density 9.8449700438547E-06 Viscosity 1.6746157109651E-02 Thermal conductivity 6.9245380545436E+04 Heat capacity 4.6403035008342E+01 Molar mass 8.3644157683026E+02 Density 3.2189318167762E-04 Viscosity 1.7517034256650E-01 Thermal conductivity 1.1095277057392E+05 Heat capacity 1.9610703855660E-02 Surface tension [Reflashed Feed stream 1] 18 Stage Number 7.0003566660718E-02 Flow rate 3.3426006719922E+02 Temperature [K] 1.2702102000000E+05 Pressure [Pa] -2.0007833449096E+07 Enthalpy [J/kmol] -8.3333304950347E+04 Entropy [J/kmol/K] 3.2939911858834E-01 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 3.9121740673062E-01 Mole fraction of component 1 6.0873140514727E-01 Mole fraction of component 2 9.9999999999974E-07 Mole fraction of component 3 5.0188122109948E-05 Mole fraction of component 4 2.3059113156080E-02 Flow rate 4.8930226481878E-01 Mole fraction of component 1 5.1068899073651E-01 Mole fraction of component 2 1.5303458339409E-07 Mole fraction of component 3 8.5914101265611E-06 Mole fraction of component 4 4.6944453504638E-02 Flow rate 3.4303812946334E-01 Mole fraction of component 1 6.5688983408239E-01 Mole fraction of component 2 1.4160293692400E-06 Mole fraction of component 3 7.0620424904872E-05 Mole fraction of component 4 5.2611529492276E+01 Molar mass 2.4047061112758E+00 Density 9.8848654946700E-06 Viscosity 1.6864604744756E-02 Thermal conductivity 6.9334649956225E+04 Heat capacity 4.6468294439920E+01 Molar mass 8.3503361485935E+02 Density 3.1801484428467E-04 Viscosity 1.7470972346869E-01 Thermal conductivity 1.1136468740248E+05 Heat capacity 1.9496259829202E-02 Surface tension [Top product] 1 Stage Number 4.2227380295957E-02 Flow rate 3.2935268462631E+02 Temperature [K] 1.1145750000000E+05 Pressure [Pa] -2.9602680447645E+07 Enthalpy [J/kmol] -9.0065793827288E+04 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 6.3999999996912E-01 Mole fraction of component 1 3.5999999998263E-01 Mole fraction of component 2 9.3319502433431E-19 Mole fraction of component 3 2.1439865921590E-17 Mole fraction of component 4 4.2227380295957E-02 Flow rate 6.3999999996912E-01 Mole fraction of component 1 3.5999999998263E-01 Mole fraction of component 2 9.3319502433431E-19 Mole fraction of component 3 2.1439865921590E-17 Mole fraction of component 4 5.8945681454675E+01 Molar mass 8.7072345315722E+02 Density 3.0245158471771E-04 Viscosity 1.6132171093400E-01 Thermal conductivity 1.2895560851331E+05 Heat capacity 2.0307609322839E-02 Surface tension [Bottom product] 27 Stage Number 2.7776186364761E-02 Flow rate 3.4456697896056E+02 Temperature [K] 1.3577550000000E+05 Pressure [Pa] -3.2711017110709E+07 Enthalpy [J/kmol] -1.0379164779356E+05 Entropy [J/kmol/K] 0.0000000000000E+00 Vapour fraction [-] 1.0000000000000E+00 Liquid phase split ratio [-] 1.3000000001508E-02 Mole fraction of component 1 9.8687098085696E-01 Mole fraction of component 2 2.5205166839471E-06 Mole fraction of component 3 1.2649874083441E-04 Mole fraction of component 4 2.7776186364761E-02 Flow rate 1.3000000001508E-02 Mole fraction of component 1 9.8687098085696E-01 Mole fraction of component 2 2.5205166839471E-06 Mole fraction of component 3 1.2649874083441E-04 Mole fraction of component 4 3.2599227487609E+01 Molar mass 7.5012919362100E+02 Density 3.1885977812579E-04 Viscosity 1.8885231752155E-01 Thermal conductivity 9.3269799634873E+04 Heat capacity 1.8271896755860E-02 Surface tension [Estimated NRTL Data] i j Aij Aji `ij 1 2 1.59601E+03 1.44991E+03 2.96500E-01 1 3 2.73191E+03 -3.46751E+02 2.00000E-01 1 4 2.71547E+03 -2.13639E+03 2.00000E-01 2 3 3.32133E+03 -2.03480E+03 2.48300E-01 2 4 1.37326E+03 1.89536E+03 2.96100E-01 3 4 1.58281E+03 9.08908E+02 2.00000E-01 [End of Results] GUIArguments /kpldUseCOSEThermo:UseCOSEDiffusionCoefficients8UsePerturbedDerivativesOnly"UsePerturbed_ddX"SuppressWarnings@RelativePerturbationTemperatureMbP?:RelativePerturbationPressureMbP?0PerturbationCompositionMbP?InletReflash<none>OutletFlash AutoDUseOnlyKValuesAndEnthalpyFromCOSE*RestartDataAvailable,OmitStageFromPortNameWilsonEstimate"LogPropertyCallsEnergyPorts UseInitialGuess(Temperature profile4Temperature at each stagelt@Ut@D Dt@Vgt@ ?t@wbt@ⵦ`t@+rt@u1t@Ȫ-t@bt@PRt@ӧt@Nt@t@et@YCN$t@7>t@Agt@t@" t@glu@Su@*>4u@ݰ-Xu@uu@MhXu@"Pressure profile.Pressure at each stage6@6@Rr@p= @(\z@HzF)@f@Qݢ@= ף@(t@z?Y@3333 @Q@ףp=@)\mL@{G9@@Q@q= כ?@(\g|@G2@ffff@\dAQ7AGz0VAףp=tAA(Vapour Flow profile4Vapour Flow at each stage 4E@*MeV@P8IuYV@f*PV@EʁFV@Fn^HFG@/G@?fG@EvG@)e wF@+F@s\eF@M:F@LF@5+F@o5_F@HF@V@H00V@Q=V@UKV@q0V@:K7uV@,j8V@2c~,V@ɜUV@!7&;@Duties profile*Duties at each stage +W Eҽ@A4Vapour Moleweight profile@Vapour Moleweight at each stagesczM@= yM@pAM@y) M@dL@{1L@"~ZL@5L@~K@4FK@P^K@{#K@tJ@׆qJ@sh|J@&wJ@{Nz^J@j@+0LJ@k 7J@QfJ@AϺI@}"OI@&G@)"E@70C@B@Ӈ.o@@.Vapour Density profile:Vapour Density at each stagedU@2d1@AB4@5@~6@┹F4@J0@>B͐**@G"@hi@Ss@͕A @ȗP@ޭ,Y@WA t @̵h@)[$&@RX;;@1JZM@+jP@Gߤi0@@؜gB@+y@Qv0b?+4?w$?2Vapour Viscosity profile>Vapour Viscosity at each stage_>foh>H>1K>#>>\m>҄/>a@>kR>!Wc>I%t>%}O>MmZ> k>~>in>sWa>^>n"p> >4>i>KR>4%>O>-#>Ig>:Vapour Heat capacity profileFVapour Heat capacity at each stage6[S@%̴+R@BR@R@I5R@ htR@5Ry;VR@7R@[[R@Q@:pΈQ@rPLQ@TgРQ@]wb։Q@ %vQ@(\gQ@vR~\Q@ &NTQ@&KQ@z6>7Q@_x Q@r߉P@eP@sh|+N@ ҌEK@1%I@GjH@HVapour Thermal conductivity profileTVapour Thermal conductivity at each stagenT?3࿳?a5.?P&A?KT?A8Eh?O|?PŽ?`iЧ?wb?_fԐ?.x?O;?X @?klt ?kTT.?l:?`̉E?;P? a?PX?̐??fC?%p?ЌnR ?qJn?4Liquid Moleweight profile@Liquid Moleweight at each stage= yM@HQM@;OL@ [:L@&K@n/iVK@(\J@pZcJ@$I@_{fInI@sFZ*H@R H@[| 4H@<,G@$ G@mV}vG@CiqRG@>M8G@VcG@ TƿF@p= gF@Pc*E@)9D@RDUB@VewA@f2}@@dL@@.Liquid Density profile:Liquid Density at each stage?5^5@K7 ,@s@ rh@0L @T@~:܊@z,CȊ@L7Aಊ@ 0@D@@!un@ h"Z@K7G@ 7@vq `*@@~jt@ rh@B@Y8݉@T@tF4@@tK@:M@%uq@2Liquid Viscosity profile>Liquid Viscosity at each stage K3?2um3?Pw-4?k&4?&14? r#H4?'2_4? Òv4?Ǖ4?Z v@4?'4?[IA4?iΠ4?/4?]VN+4?-4? q4?fח-4?kY4?Qh4?>if4?`ak5?t915?y.G5? JJl25? 5?i4?:Liquid Heat capacity profileFLiquid Heat capacity at each stage؁sF`@_vO_@"~_@ӼU_@ŏ1w-_@58EG^@jq\^@a^@~j]@؁sFV]@w#]@^)\@tz\@/L FE\@t\@46<[@[@ -[@a4[@ [@CH[@ cZBZ@#lxzY@$X@58EGW@>tA}W@~8gDQW@:Liquid Thermal cond. profileFLiquid Thermal cond. at each stageKр0?#/?<83U?C?& ? 2*A?PJb?gk?f!vs?E 2?EGr?*b5?$? '3?}C?BȘP?XzX?b]?@1d?T#ss?>?#H?Zs/?N_,?}/ϔ?w?#O,?0Surface tension profile<Surface tension at each stageW\=˔?DsŔ?l*m?r ?)Hv??s1a?~܀?I5q?*tGb?OS?_.VD?*sc-6?2(?@`H?8 ?Ժh#2?TNg?ǍS[?)u?K?Xgғ?ʡE?*CM\?'gI?ڄ? uhՒ?=s޵?Number of stagesNSi Feed1 stageF1Ni Reflux ratioRRoCondenser duty QCo?@@J/sReflux liquid flowrate RLo?kmol/sReboiler duty QRo?@@J/s 1 Converged 1 Iterations uChemSep (TM) - COL2 6.90 Copyright (c) 1988-2012 Harry Kooijman and Ross Taylor License: 2100- 6 LITE free license Build: 6494e2b69d23 Checking data file C:\DOCUME~1\Harry\LOCALS~1\Temp\CS_30_~1.SEP Cape Open unit name: C2 Cape-Open unit id: CS_30_10F8_1CCE133_6816D410 Cape-Open run level: normal Cape open Initialized Cape Open Thermodynamic-properties disabled Reading configuration Reading component property libraries Reading thermodynamic property options Reading physical property options Reading thermodynamic property data Warning! Estimating thermodynamic model parameters Ignoring all warnings User choice: Ignore Reading specifications Reading reaction data Checking Component Data 79-20-9 Methyl acetate 67-56-1 Methanol 71-36-3 1-butanol 123-86-4 N-butyl acetate * No class * Missing STboil * Missing Cp gas 1 Determining feed conditions Solving TP flash Warning! Enthalpy: adapted T range Cp parameters Ignoring all warnings User choice: Ignore Run level: Initialization Reading initial temperature profiles Reading initial composition profiles Init 78 milliseconds Run level: Complete model Iteration log(Err/Tol) Warning! Feed pressure < column pressure (Feed 1) Ignoring all warnings User choice: Ignore 0 1.6276 1 -1.3488 Run level: Report Warning! Feed pressure < column pressure (Feed 1) Convergence obtained in 1 iterations Time 47 milliseconds FixMem driver done run time: 0.2 seconds Using: C:\Program Files\ChemSepL6v90\bin\co-col2.exe CAPE-OPEN thermo-properties were disabled. All calculation methods have been determined by ChemSep. See output report or graphical user interface for more information. : not all ports are connectedFeed1{split}_stage18 TopProduct BottomProduct @ @0@@ @ @ @(@ @(@$@,@@@@@@@@$@@(@@(@ @(@ @ @ @,@$@@@$@@(@ @,@ @ @,@ @$@0@,@4@@0@@2@@2@$@2@(@0@(@(@(@(@ @(@$@4@,@0@@ 4@,@0@ 4@,@0@4@,@0@ 4@,@0@ 4@,@0@ ,@0@  ,@0@@E@CSTRdContinuously stirred tank reactor - single phase mixed reactor for equilibrium and kinetic reactionsBkwKLĪӌ2FCOUSCOUS0002 Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Pressure dropReactor pressure drop?? _BHeat duty typeType of heat duty specification Isothermal Isothermal Isothermal Heat duty Energy inlet TemperatureReactor temperature?u@r@ _B Heat dutyReactor heat duty@?@kiw() _ _B Enthalpy TypeEnthalpy calculation type Use EnthalpyF Use EnthalpyF Use EnthalpyF"Use Enthalpy (no heat of reaction)!Use Enthalpy and heat of reactionReactor volumeReactor volume@@@j@ Catalyst mass Catalyst mass?חACatalyst volumeCatalyst volume@@j@Catalyst densityCatalyst density@?$@j@Phase9Phase of reactor volume in which the reactions take placeLiquidLiquidVaporLiquid Tolerance*Relative termination tolerance on solution-C6?-C6?|=?Maximum iterations%Maximum iterations to obtain solutiondd RX01͞lc?Last run+++ specifications +++ Using enthalpyF in enthalpy calculations Temperature: 350 K Pressure drop: 0 Pa Reaction phase: Liquid Tolerance: 0.0001 Maximum iterations: 100 kinetic reaction "RX01": homogeneous Effective reactor volume: 4 m +++ solution +++ Solution converged in 2 iterations Extent of reaction "RX01": 16.3025 mol/s Reaction rate reaction "RX01": 4.07562 mol/s/m Conversion Methyl acetate: 37.3147 % Conversion 1-butanol: 34.9451 % +++ optional parameters +++ Heat duty: -824379.99299179 W P&X2 $not all material ports are connected Butyl AcetateInlet Outlet  @(@@ @(@@ @(@@ @(@@? @@#@?@@@$@@@"@@ @@#@@#@@ @@,@Valve_661Valve - generates power from pressure difference.tQGt HՐ'aTJCOUSCOUS0002Pressure spec. Pressure drop specification typePressurePressure differencePressure differencePressurePressure differencePressure drop along the valve??CA _BPressureValve outlet pressure?PAj@ _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runp+++ specifications +++ Pressure: 141855 Pa +++ optional parameters +++ Pressure difference: 364770 Pa B[+^- $not all material ports are connected InletOutlet0@@@@@?@Mixer_706Mixer - mix 2 or more inlet streams to a single outletk!^/E a-COUSCOUS0002Number of inletsNumber of inlet ports Pressure dropPressure drop along the mixer?? _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runD+++ specifications +++ Number of inlets: 2 Pressure drop: 0 Pa FC)I/ $not all material ports are connected Inlet 1 Inlet 2 Outlet0@@@@@@@ @Pump_84>Pump - unit increasing the pressure due to the work performed.F^KsHSѪ2RnCOUSCOUS0002Pressure spec.$Pressure increase specification typePressurePressure increasePressure increasePressure Energy spec. Energy demand specification type Efficiency Efficiency Energy demand EfficiencyEnergy specification streamPressure increasePressure increase??}5A _BPressureOutlet pressure?17Aj@ _B Energy demandEnergy consumed by the pump@?@r@@xDAdiabatic efficiencyPump adiabatic efficiency???Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Pressure: 1519875 Pa Adiabatic efficiency: 0.75 +++ optional parameters +++ Pressure increase: 1408417.5 Pa Energy demand: 5370.87001721998 W Adiabatic efficiency: 0.75 TC G $not all material ports are connectedInlet Outlet@@@K(^&?@@@:t= @@?:t= @@?:t= @@?:t= @@?:t= @@@Pump_98>Pump - unit increasing the pressure due to the work performed.F^KsHSѪ2RjCOUSCOUS0002Pressure spec.$Pressure increase specification typePressurePressure increasePressure increasePressure Energy spec. Energy demand specification type Efficiency Efficiency Energy demand EfficiencyEnergy specification streamPressure increasePressure increase??A _BPressureOutlet pressure?ƗAj@ _B Energy demandEnergy consumed by the pump@?@!幡@@xDAdiabatic efficiencyPump adiabatic efficiency???Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Pressure: 435697.5 Pa Adiabatic efficiency: 0.75 +++ optional parameters +++ Pressure increase: 279657 Pa Energy demand: 2268.94913583642 W Adiabatic efficiency: 0.75 b>B $not all material ports are connectedInletOutlet@@?K(^&?@@@@?:t= @@?:t= @@?:t= @@?:t= @@?:t= @@@Pump_99>Pump - unit increasing the pressure due to the work performed.F^KsHSѪ2RjCOUSCOUS0002Pressure spec.$Pressure increase specification typePressurePressure increasePressure increasePressure Energy spec. Energy demand specification type Efficiency Efficiency Energy demand EfficiencyEnergy specification streamPressure increasePressure increase??1A _BPressureOutlet pressure?17Aj@ _B Energy demandEnergy consumed by the pump@?@Oꑗ@@xDAdiabatic efficiencyPump adiabatic efficiency???Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last run+++ specifications +++ Pressure: 1519875 Pa Adiabatic efficiency: 0.75 +++ optional parameters +++ Pressure increase: 1114575 Pa Energy demand: 5783.56998590876 W Adiabatic efficiency: 0.75 cJN $not all material ports are connectedInletOutlet@@@K(^&?@@@:t= @@?:t= @@?:t= @@?:t= @@?:t= @@@ Valve_1001Valve - generates power from pressure difference.tQGt HՐ'aTbCOUSCOUS0002Pressure spec. Pressure drop specification typePressure differencePressure differencePressure differencePressurePressure differencePressure drop along the valve??.A _BPressureValve outlet pressure?Aj@ _BThermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1Last runq+++ specifications +++ Pressure difference: 1013250 Pa +++ optional parameters +++ Pressure: 506625 Pa dK+N- $not all material ports are connected InletOutlet0@@@@@?@MakeUpMixer_1017MakeUpMixer - mixer for determining a make-up flow rate/!TLCchCOUSCOUS0002Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Outlet flowTarget flow at recycle outlet?I@ _BNet flowResulting net make up flow? _B Flow basisBasis for target and net flowmol/smol/smol/skg/sTarget compound&Compound for outlet flow specification Total flow Total flow Total flowMethyl acetateMethanol 1-butanolN-butyl acetateLast run}+++ specifications +++ Flow basis: mol/s Outlet flow: 50 mol/s +++ run results ++ Net flow: 16.517215285652 mol/s e:4A: $not all material ports are connectedMake up excess flow Recycle inletMake up surplus flow Recycle outlet 0?@@?@@@ @ @MakeUpMixer_1027MakeUpMixer - mixer for determining a make-up flow rate/!TLCcjCOUSCOUS0002Thermo Version*Thermodynamics CAPE-OPEN Interface version1.11.01.01.1 Outlet flowTarget flow at recycle outlet?Q@ _BNet flowResulting net make up flow? _B Flow basisBasis for target and net flowmol/smol/smol/skg/sTarget compound&Compound for outlet flow specification Total flow Total flow Total flowMethyl acetateMethanol 1-butanolN-butyl acetateLast run~+++ specifications +++ Flow basis: mol/s Outlet flow: 70 mol/s +++ run results ++ Net flow: 27.7726197060805 mol/s f9@$ $not all material ports are connectedMake up excess flow Recycle inletMake up surplus flow Recycle outlet 0?@@?@@@ @ @MS Sans/C6?/C6?h㈵>/C6?$ b@e@@a@`b@@F{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 59.5 kmol/h\f1\fs29 \par } X@;@D@I@VUUUUI@{J@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 100 kmol/h\f1\fs29 \par } W@;@ D@I@*@@A@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\b\f0\fs27 4 m\super 3 \par \nosupersub\fs29 350 K \par 5 atm\b0 \par -824 kW\f1 \par } S@@W@T@W@@J@43333N@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 120.5 kmol/h; 0.90 BuOH; \b 0.10 BuAc\b0 ; 436.3 K\b\f1\fs29 \par } w@;@VUUUU[@EDDDDb@YUUUUU@@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 152 kmol/h; \b 0.64 MeAc\b0 ; 0.36 MeOH; 329.7 K\f1\fs29 \par } v@;@:X@`@YUUUUU'@,@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 305 K; 15 atm\f1\fs29 \par } ]@;@`C@53333SI@VUUUUJ@;L@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 305 K; 15 atm \par \fs29 0.60 MeAc \par 0.40 MeOH\f1 \par } ]@Q@C@53333I@A@YE@@\@E@Z@E@Z@\@E@E@ @ @@`@A@_@A@_@`@A@A@ @ @@]c@P@UUUUUab@P@UUUUUab@]c@P@P@ @ @~{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 2\b0 \par } 1@;@:[@ܶm۶E\@aa;@R.R.>@~{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 2\b0 \par } 1@;@AAi`@m۶m`@i۶m۶7@5::@~{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 2\b0 \par } 1@;@AAb@n۶m2c@m۶mH@AJ@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 36\b0 \par } ;@;@:r[@ܶm۶%\@m۶mK@AM@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 20\b0 \par } ;@;@S.R.}[@aa0\@_aD@~~,F@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 18\b0 \par } ;@;@~~c`@a`@0 0?@~~,A@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 26\b0 \par } ;@;@_`@`@XUUUUG@;I@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 27\b0 \par } ;@;@~b@a c@ 0 N@K+P@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 46\b0 \par } ;@;@AAb@n۶m"c@aa8S@KS@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 100 kmol/h \par \b 0.987 MeOH\b0 \par \fs29 344.7 K \par \b 1.34 atm\b0\f1 \par } [@W@`@za@S@43333U@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 59.4 kmol/h \par \b 0.987 BuAc\b0 \par \fs29 459.0 K \par \b 4.44 atm\b0\f1 \par } Z@W@8d@e@R@T@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 -3.1 MW\f1\fs29 \par } R@;@\@iffff^@UUUUUU3@*6@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 -2.9 MW\f1\fs29 \par } R@;@VUUUU a@b@.@VUUUU1@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 -3.8 MW\f1\fs29 \par } R@;@WUUUU]c@Pd@VUUUUD@F@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 +3.6 MW\f1\fs29 \par } T@;@WUUUU^@`@jM@UUUUUN@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 +2.1 MW\f1\fs29 \par } T@;@VUUUU=a@@b@G@H@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 +4.4 MW\f1\fs29 \par } T@;@bc@ed@U@UUUUUuV@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 RR = 1.03\f1\fs29 \par } @V@;@(a@Hb@:@=@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 RR = 0.33 \par \b\fs29 10\super -6\nosupersub BuOH \par \b0 332.7 K\f1 \par } X@Q@]@_@WUUUUUA@D@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\f0\fs27 RR = 2\f1\fs29 \par } P@;@c@d@WUUUUJ@L@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\b\f0\fs27 1.2 atm\b0 \par \f1\fs29 \par } Q@H@WUUUUeY@ [@]UUUU7@UUUUU9@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}} \viewkind4\uc1\pard\b\f0\fs27 1.1 atm \par } Q@;@^@P`@4@6@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\b\f0\fs27 4.0 atm\f1\fs29 \par } Q@;@VUUUUMb@0c@E@jffffF@{\rtf1\ansi\ansicpg1252\deff0\deflang1033{\fonttbl{\f0\fnil\fcharset0 Roman;}{\f1\fnil MS Sans;}} \viewkind4\uc1\pard\b\f0\fs27 1.54 atm \par \fs29 10\super -6\nosupersub MeOH \par \b0 401.6 K\f1 \par } @Y@Q@WUUUU^@`@XUUUUuP@%""""BR@ׁ?ׁ?ׁ?ׁ??e